Isolation of enantiomerically pure organometallic palladium compounds: synthesis of the triangles prepared from enantiopure [cis-Pd2(C6H4PPh2)2(NCCH3)4]2

• Published in: Dalton transactions : an international journal of inorganic chemistry no. 16; pp. 2993 - 2998
• Main Authors: Koshevoy, Igor O, Gutierrez-Puebla, Enrique, Lahuerta, Pascual, Monge, Angeles, Ubeda, M Angeles, Sanaú, Mercedes
• Format: Journal Article
• Language: English
• Published: England 28.04.2009

Reaction of the racemic [Pd(C(6)H(4)PPh(2))Br](4) () with the silver salt of 1R-(1alpha,2beta,3alpha)]-3-methyl-2-(nitromethyl)-5-oxocyclopentaneacetate, (R)-AgO(2)CR*, results in the formation of a mixture of diastereoisomers (RRR)- and (SRR)- of the formula Pd(2)(C(6)H(4)PPh(2))(2)(O(2)CR*)(2) tha...