Synthesis and properties of naphthylamine derivative functionalized spiro-[fluorene-9,9′-xanthene] for single-component white light-emitting diodes

• Published in: Journal of molecular structure Vol. 1317; p. 139122
• Main Authors: Luo, Yang, Shi, Mingkai, Dong, Linlin, Xie, Tianyou, Lartey, Patrick Osei, Zhao, Shijie, Guo, Kunpeng, Wang, Hua, Miao, Yanqin, Li, Jie
• Format: Journal Article
• Language: English
• Published: Elsevier B.V 05.12.2024
• Subjects: Blue luminophore; Color-purity; Naphthylamine; Spiro[fluorene-9,9′-xanthene]; White light-emitting diodes; Spiro[fluorene-9,9′-xanthene]; Naphthylamine; Color-purity; Blue luminophore; White light-emitting diodes
• DOI: 10.1016/j.molstruc.2024.139122
• ISSN: 0022-2860

•A newly spiro[fluorene-9,9′-xanthene]-centered, naphthylamine derivative functionalized molecule SFX-PNA was synthesized.•SFX-PNA exhibits good thermal ability and broad blue-emissive band in the solid state.•Incorporation with the intrinsic yellow luminescence of GaN LED chips, single-component white light-emitting diode based on SFX-PNA was realized.•SFX-PNA-based white light-emitting diodes showed high color-purity with CIE coordinates of (0.30, 0.33). White light-emitting diodes (LEDs) with high color purity and color-rendering index have elicited much interest in many fields. In this work, a spirotype molecule SFX-PNA was designed and synthesized by combining a spiro[fluorene-9,9′-xanthene] (SFX) core with naphthylamine derivative functionalized at the 2,3′,6′,7-positions. Studies revealed that the highly twisted configuration allowed SFX-PNA to exhibit good thermal stability and a broad blue-emissive band (λem = 466 nm) in the solid state. In combination with the intrinsic yellow luminescence (λem = 556 nm) of commercially available GaN ultraviolet LED chips, a white LED with SFX-PNA as the phosphor was successfully obtained, which showed high color purity with Commission Internationale de L’Éclairage coordinates of (0.30, 0.33) and a color-rendering index of 86. [Display omitted]