Water transport through epoxy-based powder pipeline coatings

• Published in: Progress in organic coatings Vol. 168; p. 106874
• Main Authors: Zargarnezhad, Hossein, Asselin, Edouard, Wong, Dennis, Lam, C.N. Catherine
• Format: Journal Article
• Language: English
• Published: Lausanne Elsevier B.V 01.07.2022; Elsevier BV
• Subjects: Clustering; Epoxy coatings; Epoxy network; Fusion bonded epoxy; Penetration; Phase separation; Polymer hydration; Powder coating; Residual stress; Room temperature; Underground storage tanks; Vapor transport; Water chemistry; Water clustering; Vapor transport; Water clustering; Polymer hydration; Fusion bonded epoxy; Epoxy network
• ISSN: 0300-9440; 1873-331X
• DOI: 10.1016/j.porgcoat.2022.106874

We examined the water permeation kinetics of two common epoxy-based powder coating systems for pipelines across a range of industrially-relevant temperatures (from room temperature to 80 °C). We exclusively analyzed the nonlinear dependency of water transport on the vapor concentration at 65 °C. The vapor transport analysis of epoxy coatings demonstrated a turning point around this temperature, perhaps due to clustering of water molecules. At higher temperatures, break-up of water clusters and plasticization of the polymer expedited the transport. We also examined microstructural changes of the epoxy network due to water transport and found evidence for irreversible damage to epoxy coatings under hydrothermal exposures. It appears that the combination of thermal exposure and internal stresses in the glassy epoxy leads to a phase separation of filler particles from the epoxy matrix, as well as to a distinctive cavity formation in the coating membrane. Our results indicate that hydrothermal exposure is likely to increase aggregate porosity of the coating and a conservative implementation of standard coating procedures is therefore reasonable to avoid early degradation issues. Analysis of wet-state permeation is not only crucial for protection of transport pipelines, but it also is of high relevance to process equipment and underground storage tanks. [Display omitted] •Water can change the molecular structure of polymeric coatings over time and affect the mass transport of other permeants.•Service parameters such as temperature, humidity or gas pressure can alter sorption mechanisms in epoxy coatings.•Hydration of the epoxy network at elevated temperatures increases the aggregate porosity within the coating.•A conservative implementation of standard coating procedures is necessary to decrease early coating degradation issues.