Effect of Support on Steam Reforming of Ethanol for H2 Production with Copper-Based Catalysts

Catalytic studies hydrogen production via steam reforming of ethanol (SRE) are essential for process optimization. Likewise, selecting the ideal support for the active phase can be critical to achieve high conversion rates during the catalytic steam reforming process. In this work, copper-based cata...

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Published inProcesses Vol. 12; no. 7; p. 1331
Main Authors Nippes, Ramiro Picoli, Macruz, Paula Derksen, Domingues Gomes, Aline, de Souza, Marcos, Ferreira, Bruna Rodrigues, Rizzo-Domingues, Roberta Carolina Pelissari, Pereira Ramos, Luiz
Format Journal Article
LanguageEnglish
Published Basel MDPI AG 01.07.2024
Subjects
Acetaldehyde
Adsorption
Aluminum oxide
Carbon
Catalysis
Catalysts
Catalytic converters
Chemical synthesis
Copper
Copper converters
Ethanol
Heat resistance
Hydrogen production
Mixed oxides
Niobium oxides
Nitrates
Particle size
Physicochemical properties
Raw materials
Reforming
Steam
Zeolites
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Abstract Catalytic studies hydrogen production via steam reforming of ethanol (SRE) are essential for process optimization. Likewise, selecting the ideal support for the active phase can be critical to achieve high conversion rates during the catalytic steam reforming process. In this work, copper-based catalysts were synthesized using two different supports, NaY zeolite and Nb2O5/Al2O3 mixed oxides. The materials were prepared using wet impregnation and characterized for their physicochemical properties using different analytical techniques. Differences in the catalyst morphologies were readily attributed to the characteristics of the support. The Cu/NaY catalyst exhibited a higher specific surface area (210.40 m2 g−1) compared to the Cu/Nb2O5/Al2O3 catalyst (26.00 m2 g−1), resulting in a homogeneous metal dispersion over the support surface. The obtained results showed that, at 300 °C, both the Cu/Nb2O5/Al2O3 and Cu/NaY catalysts produced approximately 50% hydrogen and 40% acetaldehyde, but with significant differences in conversion (6% and 56%, respectively). At 450 °C, a greater product distribution and a 10% higher conversion were observed when the catalyst was supported on NaY compared to Nb2O5/Al2O3. Hence, the performance of copper-based catalysts was influenced significantly by the textural properties of the support.
AbstractList Catalytic studies hydrogen production via steam reforming of ethanol (SRE) are essential for process optimization. Likewise, selecting the ideal support for the active phase can be critical to achieve high conversion rates during the catalytic steam reforming process. In this work, copper-based catalysts were synthesized using two different supports, NaY zeolite and Nb2O5/Al2O3 mixed oxides. The materials were prepared using wet impregnation and characterized for their physicochemical properties using different analytical techniques. Differences in the catalyst morphologies were readily attributed to the characteristics of the support. The Cu/NaY catalyst exhibited a higher specific surface area (210.40 m2 g−1) compared to the Cu/Nb2O5/Al2O3 catalyst (26.00 m2 g−1), resulting in a homogeneous metal dispersion over the support surface. The obtained results showed that, at 300 °C, both the Cu/Nb2O5/Al2O3 and Cu/NaY catalysts produced approximately 50% hydrogen and 40% acetaldehyde, but with significant differences in conversion (6% and 56%, respectively). At 450 °C, a greater product distribution and a 10% higher conversion were observed when the catalyst was supported on NaY compared to Nb2O5/Al2O3. Hence, the performance of copper-based catalysts was influenced significantly by the textural properties of the support.
Author Rizzo-Domingues, Roberta Carolina Pelissari
Nippes, Ramiro Picoli
de Souza, Marcos
Macruz, Paula Derksen
Domingues Gomes, Aline
Pereira Ramos, Luiz
Ferreira, Bruna Rodrigues
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Snippet Catalytic studies hydrogen production via steam reforming of ethanol (SRE) are essential for process optimization. Likewise, selecting the ideal support for...
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StartPage 1331
SubjectTerms Acetaldehyde
Adsorption
Aluminum oxide
Carbon
Catalysis
Catalysts
Catalytic converters
Chemical synthesis
Copper
Copper converters
Ethanol
Heat resistance
Hydrogen production
Mixed oxides
Niobium oxides
Nitrates
Particle size
Physicochemical properties
Raw materials
Reforming
Steam
Zeolites
Title Effect of Support on Steam Reforming of Ethanol for H2 Production with Copper-Based Catalysts
URI https://www.proquest.com/docview/3085027850
Volume 12
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