Processes in the H2PtCl6·6H2O–Solvent Systems. Part 2: Methylvinylsiloxane Solutions

• Published in: Doklady. Chemistry Vol. 506; no. 2; pp. 216 - 222
• Main Authors: Klimova, N. V., Ivanov, A. G., Lebedev, A. V., Storozhenko, P. A.
• Format: Journal Article
• Language: English
• Published: Moscow Pleiades Publishing 01.10.2022; Springer Nature B.V
• Subjects: Chemical reactions; Chemistry; Chemistry and Materials Science; Chemistry/Food Science; Ethanol; High temperature; Hydrochlorination; Hydrosilylation; Industrial Chemistry/Chemical Engineering; Liquid chromatography; NMR spectroscopy; Siloxanes; vinylsiloxanes; trimethylsilylsilicate; Karstedt’s catalyst; β-elimination; colloidal platinum; siloxane complexes; high-temperature hydrosilylation; chloroplatinic acid

Redox processes in the H 2 PtCl 6 ·6H 2 O–1,1,3,3-tetramethyl-1,3-divinyldisiloxane system both in the presence of ethanol and trimethylchlorosilane, and in the absence thereof were studied by 1 Н, 13 С, and  29 Si NMR spectroscopy and gas–liquid chromatography. It was found for the first time that...