Relationship of Molecular-Mass Characteristics of Polyisoprene, Component of Vulcanized Sealant, with Particle Sizes of Catalytic System TiCl4–Al(i-C4H9)3 in Isoprene Polymerization

• Published in: Polymer science. Series D, Glues and sealing materials Vol. 14; no. 3; pp. 392 - 395
• Main Authors: Ganiev, G. M., Tereshchenko, K. A., Shiyan, D. A., Ziganshina, A. S., Zakharov, V. P., Ulitin, N. V.
• Format: Journal Article
• Language: English
• Published: Moscow Pleiades Publishing 01.07.2021; Springer Nature B.V
• Subjects: Chemistry; Chemistry and Materials Science; Isoprene; Polymer Sciences; Polymerization; Titanium chlorides; vulcanized sealant; inverse kinetic problem; tubular turbulent apparatus; turbulence; catalytic system of Ziegler–Natta; polyisoprene

A model of isoprene polymerization kinetics in the presence of the catalytic system TiCl 4 –Al( i -C 4 H 9 ) 3 has been developed. The feature of the model is its ability to forecast molecular-mass characteristics of polyisoprene on the basis of particle sizes of the catalytic system. It allows one...