3C- and 1H-NMR study of some Pt(II) complexes with dithiocarbazic ligands

• Published in: Polyhedron Vol. 7; no. 13; pp. 1211 - 1216
• Main Authors: Giuliani, A.M., Trotta, E.
• Format: Journal Article
• Language: English
• Published: Oxford Elsevier Ltd 1988; New York, NY Elsevier Science
• Subjects: Atomic and molecular physics; Exact sciences and technology; Molecular properties and interactions with photons; Nuclear resonance and relaxation; Physics; Organic dithiocarbazate; Divalent metal Complexes; Chemical solution; NMR parameter; Organic ligand; Transition metal Complexes; Experimental study; NMR spectrum; Inorganic compound; Platinum II Complexes

Pt(II) complexes with singly- and doubly-deprotonated dithiocarbazic ligands have been examined by 1H- and 13C-NMR. Complexation induces a deshielding of all the ligand resonances, except that of the thiono carbon. The shielding of C(1) is greater in complexes with singly-deprotonated rather than wi...