Local structure and electronic properties in colossally magnetoresistive thin film of La0.87Na0.13MnO3 by Mn-K edge EXAFS and XANES

Mn-K edge EXAFS and XANES spectra of La0.87Na0.13MnO3 manganite films with different thicknesses (750, 250, 125 and 50Å), have been acquired at RT. In the 50Å film a shift of the Fermi level downward in energy is found if compared to the other films. In addition, the density of the empty minority sp...

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Published inNuclear instruments & methods in physics research. Section B, Beam interactions with materials and atoms Vol. 238; no. 1-4; pp. 242 - 247
Main Authors Ghigna, Paolo, Marzola, Andrea, Amantea, Roberta, Malavasi, Lorenzo, Flor, Giorgio, D’Acapito, Francesco, Bardelli, Fabrizio, Mozzati, Maria Cristina
Format Journal Article
LanguageEnglish
Published Elsevier B.V 01.08.2005
Subjects
Dead layer
Manganites
Thin films
XAFS
61.10.Ht
Thin films
73.50.−h
75.47.Lx
Dead layer
Manganites
XAFS
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Abstract Mn-K edge EXAFS and XANES spectra of La0.87Na0.13MnO3 manganite films with different thicknesses (750, 250, 125 and 50Å), have been acquired at RT. In the 50Å film a shift of the Fermi level downward in energy is found if compared to the other films. In addition, the density of the empty minority spin states is decreased. This finding has been attributed to the presence of some Mn ions experiencing a different local chemical environment that results in the breaking of some DE paths, and in addition to an Anderson localisation of the charge carriers. This last conclusion can explain both the strongly insulating nature and the spin glass like behaviour of the magnetic response of the 50Å film, and has been corroborated by the results of the EXAFS analysis.
AbstractList Mn-K edge EXAFS and XANES spectra of La0.87Na0.13MnO3 manganite films with different thicknesses (750, 250, 125 and 50Å), have been acquired at RT. In the 50Å film a shift of the Fermi level downward in energy is found if compared to the other films. In addition, the density of the empty minority spin states is decreased. This finding has been attributed to the presence of some Mn ions experiencing a different local chemical environment that results in the breaking of some DE paths, and in addition to an Anderson localisation of the charge carriers. This last conclusion can explain both the strongly insulating nature and the spin glass like behaviour of the magnetic response of the 50Å film, and has been corroborated by the results of the EXAFS analysis.
Author D’Acapito, Francesco
Mozzati, Maria Cristina
Bardelli, Fabrizio
Marzola, Andrea
Malavasi, Lorenzo
Amantea, Roberta
Ghigna, Paolo
Flor, Giorgio
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  organization: INFM, Unità di Pavia, Dipartimento di Fisica “A. Volta”, Università di Pavia, Via Bassi 6, I-27100 Pavia, Italy
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Cites_doi 10.1103/PhysRevLett.82.4264
10.1021/jp027015z
10.1103/PhysRev.82.403
10.1103/PhysRevLett.74.5144
10.1063/1.121181
10.1103/PhysRevB.63.214405
10.1063/1.124050
10.1017/S088571560001054X
10.1007/3-540-45503-5_3
10.1021/jp0481660
10.1103/PhysRevLett.82.2398
10.1107/S0567739476001551
10.1063/1.1478787
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Keywords 61.10.Ht
Thin films
73.50.−h
75.47.Lx
Dead layer
Manganites
XAFS
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References Binsted, Gurman, Campbell, Stephenson (bib12) 1998
O’Donnel, Rzchowski, Eckstein, Bozovic (bib4) 1998; 72
Malavasi, Mozzati, Ghigna, Azzoni, Flor (bib7) 2003; 107
Sun, Abraham, Rao, Eom (bib5) 1999; 74
Zener (bib1) 1951; 82
Zeise, Semmelhack, Han, Sena, Blythe (bib6) 2002; 91
Malavasi, Flor (bib10) 2003; 107
Elfimov, Anisimov, Sawatzky (bib14) 1999; 82
Shannon (bib8) 1976; 32
Malavasi, Mozzati, Alessandri, Depero, Azzoni, Flor (bib13) 2004; 108
Millis, Littelwood, Shraiman (bib2) 1995; 74
Benfatto, Joly, Natoli (bib15) 1999; 82
Egami (bib3) 2001
Spinolo, Maglia (bib9) 1999; 14
Bridges, Booth, Anderson, Kwei, Neumeier, Snyder, Mitchell, Gardner, Brosha (bib11) 2001; 63
Spinolo (10.1016/j.nimb.2005.06.055_bib9) 1999; 14
Malavasi (10.1016/j.nimb.2005.06.055_bib13) 2004; 108
Bridges (10.1016/j.nimb.2005.06.055_bib11) 2001; 63
Benfatto (10.1016/j.nimb.2005.06.055_bib15) 1999; 82
Sun (10.1016/j.nimb.2005.06.055_bib5) 1999; 74
Zeise (10.1016/j.nimb.2005.06.055_bib6) 2002; 91
Millis (10.1016/j.nimb.2005.06.055_bib2) 1995; 74
Shannon (10.1016/j.nimb.2005.06.055_bib8) 1976; 32
O’Donnel (10.1016/j.nimb.2005.06.055_bib4) 1998; 72
Binsted (10.1016/j.nimb.2005.06.055_bib12) 1998
Malavasi (10.1016/j.nimb.2005.06.055_bib10) 2003; 107
Zener (10.1016/j.nimb.2005.06.055_bib1) 1951; 82
Egami (10.1016/j.nimb.2005.06.055_bib3) 2001
Malavasi (10.1016/j.nimb.2005.06.055_bib7) 2003; 107
Elfimov (10.1016/j.nimb.2005.06.055_bib14) 1999; 82
References_xml – volume: 74
  start-page: 5144
  year: 1995
  ident: bib2
  publication-title: Phys. Rev. Lett.
  contributor:
    fullname: Shraiman
– volume: 108
  start-page: 13643
  year: 2004
  ident: bib13
  publication-title: J. Phys. Chem. B
  contributor:
    fullname: Flor
– year: 2001
  ident: bib3
  article-title: Local atomic structure of CMR manganites and related oxides in localized to itinerant electronic transition in perovskite oxides
  publication-title: Structure and Bonding 98
  contributor:
    fullname: Egami
– volume: 107
  year: 2003
  ident: bib10
  publication-title: J. Phys. Chem. B.
  contributor:
    fullname: Flor
– volume: 91
  start-page: 9930
  year: 2002
  ident: bib6
  publication-title: J. Appl. Phys.
  contributor:
    fullname: Blythe
– volume: 32
  start-page: 751
  year: 1976
  ident: bib8
  publication-title: Acta Crystall. A
  contributor:
    fullname: Shannon
– volume: 63
  start-page: 214405
  year: 2001
  ident: bib11
  publication-title: Phys. Rev. B
  contributor:
    fullname: Brosha
– volume: 82
  start-page: 4264
  year: 1999
  ident: bib14
  publication-title: Phys. Rev. Lett.
  contributor:
    fullname: Sawatzky
– volume: 82
  start-page: 403
  year: 1951
  ident: bib1
  publication-title: Phys. Rev.
  contributor:
    fullname: Zener
– volume: 72
  start-page: 1775
  year: 1998
  ident: bib4
  publication-title: Appl. Phys. Lett.
  contributor:
    fullname: Bozovic
– volume: 107
  start-page: 2500
  year: 2003
  ident: bib7
  publication-title: J. Phys. Chem. B.
  contributor:
    fullname: Flor
– volume: 74
  start-page: 3017
  year: 1999
  ident: bib5
  publication-title: Appl. Phys. Lett.
  contributor:
    fullname: Eom
– volume: 14
  start-page: 208
  year: 1999
  ident: bib9
  publication-title: Powder Diffr.
  contributor:
    fullname: Maglia
– volume: 82
  start-page: 2398
  year: 1999
  ident: bib15
  publication-title: Phys. Rev. Lett.
  contributor:
    fullname: Natoli
– year: 1998
  ident: bib12
  article-title: EXCURV98 program
  contributor:
    fullname: Stephenson
– year: 1998
  ident: 10.1016/j.nimb.2005.06.055_bib12
  contributor:
    fullname: Binsted
– volume: 82
  start-page: 4264
  year: 1999
  ident: 10.1016/j.nimb.2005.06.055_bib14
  publication-title: Phys. Rev. Lett.
  doi: 10.1103/PhysRevLett.82.4264
  contributor:
    fullname: Elfimov
– volume: 107
  start-page: 2500
  year: 2003
  ident: 10.1016/j.nimb.2005.06.055_bib7
  publication-title: J. Phys. Chem. B.
  doi: 10.1021/jp027015z
  contributor:
    fullname: Malavasi
– volume: 107
  year: 2003
  ident: 10.1016/j.nimb.2005.06.055_bib10
  publication-title: J. Phys. Chem. B.
  contributor:
    fullname: Malavasi
– volume: 82
  start-page: 403
  year: 1951
  ident: 10.1016/j.nimb.2005.06.055_bib1
  publication-title: Phys. Rev.
  doi: 10.1103/PhysRev.82.403
  contributor:
    fullname: Zener
– volume: 74
  start-page: 5144
  year: 1995
  ident: 10.1016/j.nimb.2005.06.055_bib2
  publication-title: Phys. Rev. Lett.
  doi: 10.1103/PhysRevLett.74.5144
  contributor:
    fullname: Millis
– volume: 72
  start-page: 1775
  year: 1998
  ident: 10.1016/j.nimb.2005.06.055_bib4
  publication-title: Appl. Phys. Lett.
  doi: 10.1063/1.121181
  contributor:
    fullname: O’Donnel
– volume: 63
  start-page: 214405
  year: 2001
  ident: 10.1016/j.nimb.2005.06.055_bib11
  publication-title: Phys. Rev. B
  doi: 10.1103/PhysRevB.63.214405
  contributor:
    fullname: Bridges
– volume: 74
  start-page: 3017
  year: 1999
  ident: 10.1016/j.nimb.2005.06.055_bib5
  publication-title: Appl. Phys. Lett.
  doi: 10.1063/1.124050
  contributor:
    fullname: Sun
– volume: 14
  start-page: 208
  year: 1999
  ident: 10.1016/j.nimb.2005.06.055_bib9
  publication-title: Powder Diffr.
  doi: 10.1017/S088571560001054X
  contributor:
    fullname: Spinolo
– year: 2001
  ident: 10.1016/j.nimb.2005.06.055_bib3
  article-title: Local atomic structure of CMR manganites and related oxides in localized to itinerant electronic transition in perovskite oxides
  doi: 10.1007/3-540-45503-5_3
  contributor:
    fullname: Egami
– volume: 108
  start-page: 13643
  issue: 36
  year: 2004
  ident: 10.1016/j.nimb.2005.06.055_bib13
  publication-title: J. Phys. Chem. B
  doi: 10.1021/jp0481660
  contributor:
    fullname: Malavasi
– volume: 82
  start-page: 2398
  year: 1999
  ident: 10.1016/j.nimb.2005.06.055_bib15
  publication-title: Phys. Rev. Lett.
  doi: 10.1103/PhysRevLett.82.2398
  contributor:
    fullname: Benfatto
– volume: 32
  start-page: 751
  year: 1976
  ident: 10.1016/j.nimb.2005.06.055_bib8
  publication-title: Acta Crystall. A
  doi: 10.1107/S0567739476001551
  contributor:
    fullname: Shannon
– volume: 91
  start-page: 9930
  year: 2002
  ident: 10.1016/j.nimb.2005.06.055_bib6
  publication-title: J. Appl. Phys.
  doi: 10.1063/1.1478787
  contributor:
    fullname: Zeise
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Snippet Mn-K edge EXAFS and XANES spectra of La0.87Na0.13MnO3 manganite films with different thicknesses (750, 250, 125 and 50Å), have been acquired at RT. In the 50Å...
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SubjectTerms Dead layer
Manganites
Thin films
XAFS
Title Local structure and electronic properties in colossally magnetoresistive thin film of La0.87Na0.13MnO3 by Mn-K edge EXAFS and XANES
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