Enhancing the high-temperature energy storage properties of PEI dielectrics by constructing trap-rich covalently cross-linked networks via POSS-functionalized BNNS
Polymer films are ideal dielectric materials for energy storage capacitors due to their light weight and flexibility, but lower energy density and poor heat resistance greatly limit their application in high-temperature energy storage. Unlike the traditional method of solely adding wide-bandgap inor...
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Published in | Materials horizons Vol. 11; no. 18; pp. 4348 - 4358 |
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Main Authors | , , , , |
Format | Journal Article |
Language | English |
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Royal Society of Chemistry
16.09.2024
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Abstract | Polymer films are ideal dielectric materials for energy storage capacitors due to their light weight and flexibility, but lower energy density and poor heat resistance greatly limit their application in high-temperature energy storage. Unlike the traditional method of solely adding wide-bandgap inorganic fillers to enhance energy density, in this study we constructed trap-rich hybrid covalently cross-linked networks in polyetherimide (PEI) via reactive polyhedral oligomeric silsesquioxane (POSS)-functionalized boron nitride nanosheets (BNNS@POSS), which not only serve as interfacial layers for dielectric transitions and insulating barriers but also create deeper traps and higher energy barriers in the region of cross-linked chains. This strategy based on the co-modulation of interfaces and traps achieved the compatibility of high polarization and high breakdown strength and improved energy storage performance. Therefore, the composite film BNNS@POSS/PEI with the addition of 5 wt% BNNS@POSS achieved a maximum discharge energy density and charge–discharge efficiency at 150 °C of 6.16 J cm −3 and 89.92%, and maintained high values at 200 °C of 4.12 J cm −3 and 88.38%, respectively. Moreover, the glass transition temperature ( T g ) of the composite dielectrics increased by 20.2 °C. This work provides a promising candidate material and development directions for research in the field of high-temperature energy storage capacitors. |
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AbstractList | Polymer films are ideal dielectric materials for energy storage capacitors due to their light weight and flexibility, but lower energy density and poor heat resistance greatly limit their application in high-temperature energy storage. Unlike the traditional method of solely adding wide-bandgap inorganic fillers to enhance energy density, in this study we constructed trap-rich hybrid covalently cross-linked networks in polyetherimide (PEI) via reactive polyhedral oligomeric silsesquioxane (POSS)-functionalized boron nitride nanosheets (BNNS@POSS), which not only serve as interfacial layers for dielectric transitions and insulating barriers but also create deeper traps and higher energy barriers in the region of cross-linked chains. This strategy based on the co-modulation of interfaces and traps achieved the compatibility of high polarization and high breakdown strength and improved energy storage performance. Therefore, the composite film BNNS@POSS/PEI with the addition of 5 wt% BNNS@POSS achieved a maximum discharge energy density and charge–discharge efficiency at 150 °C of 6.16 J cm −3 and 89.92%, and maintained high values at 200 °C of 4.12 J cm −3 and 88.38%, respectively. Moreover, the glass transition temperature ( T g ) of the composite dielectrics increased by 20.2 °C. This work provides a promising candidate material and development directions for research in the field of high-temperature energy storage capacitors. Polymer films are ideal dielectric materials for energy storage capacitors due to their light weight and flexibility, but lower energy density and poor heat resistance greatly limit their application in high-temperature energy storage. Unlike the traditional method of solely adding wide-bandgap inorganic fillers to enhance energy density, in this study we constructed trap-rich hybrid covalently cross-linked networks in polyetherimide (PEI) via reactive polyhedral oligomeric silsesquioxane (POSS)-functionalized boron nitride nanosheets (BNNS@POSS), which not only serve as interfacial layers for dielectric transitions and insulating barriers but also create deeper traps and higher energy barriers in the region of cross-linked chains. This strategy based on the co-modulation of interfaces and traps achieved the compatibility of high polarization and high breakdown strength and improved energy storage performance. Therefore, the composite film BNNS@POSS/PEI with the addition of 5 wt% BNNS@POSS achieved a maximum discharge energy density and charge–discharge efficiency at 150 °C of 6.16 J cm−3 and 89.92%, and maintained high values at 200 °C of 4.12 J cm−3 and 88.38%, respectively. Moreover, the glass transition temperature (Tg) of the composite dielectrics increased by 20.2 °C. This work provides a promising candidate material and development directions for research in the field of high-temperature energy storage capacitors. Polymer films are ideal dielectric materials for energy storage capacitors due to their light weight and flexibility, but lower energy density and poor heat resistance greatly limit their application in high-temperature energy storage. Unlike the traditional method of solely adding wide-bandgap inorganic fillers to enhance energy density, in this study we constructed trap-rich hybrid covalently cross-linked networks in polyetherimide (PEI) via reactive polyhedral oligomeric silsesquioxane (POSS)-functionalized boron nitride nanosheets (BNNS@POSS), which not only serve as interfacial layers for dielectric transitions and insulating barriers but also create deeper traps and higher energy barriers in the region of cross-linked chains. This strategy based on the co-modulation of interfaces and traps achieved the compatibility of high polarization and high breakdown strength and improved energy storage performance. Therefore, the composite film BNNS@POSS/PEI with the addition of 5 wt% BNNS@POSS achieved a maximum discharge energy density and charge-discharge efficiency at 150 °C of 6.16 J cm-3 and 89.92%, and maintained high values at 200 °C of 4.12 J cm-3 and 88.38%, respectively. Moreover, the glass transition temperature (Tg) of the composite dielectrics increased by 20.2 °C. This work provides a promising candidate material and development directions for research in the field of high-temperature energy storage capacitors.Polymer films are ideal dielectric materials for energy storage capacitors due to their light weight and flexibility, but lower energy density and poor heat resistance greatly limit their application in high-temperature energy storage. Unlike the traditional method of solely adding wide-bandgap inorganic fillers to enhance energy density, in this study we constructed trap-rich hybrid covalently cross-linked networks in polyetherimide (PEI) via reactive polyhedral oligomeric silsesquioxane (POSS)-functionalized boron nitride nanosheets (BNNS@POSS), which not only serve as interfacial layers for dielectric transitions and insulating barriers but also create deeper traps and higher energy barriers in the region of cross-linked chains. This strategy based on the co-modulation of interfaces and traps achieved the compatibility of high polarization and high breakdown strength and improved energy storage performance. Therefore, the composite film BNNS@POSS/PEI with the addition of 5 wt% BNNS@POSS achieved a maximum discharge energy density and charge-discharge efficiency at 150 °C of 6.16 J cm-3 and 89.92%, and maintained high values at 200 °C of 4.12 J cm-3 and 88.38%, respectively. Moreover, the glass transition temperature (Tg) of the composite dielectrics increased by 20.2 °C. This work provides a promising candidate material and development directions for research in the field of high-temperature energy storage capacitors. |
Author | Zhou, Yijie Tang, Qiufan Zhang, Zongwu Ma, Xiaoyan Hou, Xiao |
Author_xml | – sequence: 1 givenname: Yijie surname: Zhou fullname: Zhou, Yijie – sequence: 2 givenname: Zongwu surname: Zhang fullname: Zhang, Zongwu – sequence: 3 givenname: Qiufan surname: Tang fullname: Tang, Qiufan – sequence: 4 givenname: Xiaoyan surname: Ma fullname: Ma, Xiaoyan – sequence: 5 givenname: Xiao surname: Hou fullname: Hou, Xiao |
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Cites_doi | 10.1021/acsami.3c06778 10.1002/adma.202211487 10.1002/marc.202100116 10.1002/inf2.12368 10.1002/adma.202101976 10.1002/adma.201701864 10.1002/adma.202303849 10.1007/s12274-023-5580-7 10.1016/j.ensm.2024.103485 10.1016/j.jhazmat.2020.123439 10.1039/D3MH00499F 10.1002/advs.202102221 10.1016/j.cej.2021.131860 10.1016/j.ensm.2021.07.018 10.1016/j.cej.2023.143324 10.1002/adma.202302392 10.1016/j.compscitech.2020.108528 10.1016/j.apsusc.2019.01.082 10.1002/adma.202306562 10.1039/D1EE03186D 10.1016/j.cej.2022.139917 10.1002/advs.202302949 10.1002/adfm.202314910 10.1021/acs.nanolett.0c03528 10.1016/j.cej.2022.137106 10.1039/D3MH01822A 10.1039/D2MH00912A 10.1021/acsanm.3c03648 10.1038/s41565-023-01541-w 10.1016/j.pmatsci.2018.10.003 10.1016/j.nanoen.2024.109271 10.1039/D2TA07214A 10.1002/adma.201600377 10.1038/s41467-023-38145-w 10.1038/s41467-020-17760-x 10.1021/acssuschemeng.8b04370 10.1039/D3MH00907F 10.1002/smll.202208105 10.1002/adfm.202102644 10.1002/adma.202310272 10.1016/j.cej.2023.147581 10.1016/j.cej.2023.143803 10.1039/D3EE03644H |
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References | Yuan (D4MH00299G/cit42/1) 2020; 11 Feng (D4MH00299G/cit12/1) 2022; 9 Yang (D4MH00299G/cit43/1) 2024; 17 Yang (D4MH00299G/cit39/1) 2024; 19 Zuo (D4MH00299G/cit20/1) 2023; 6 Shang (D4MH00299G/cit21/1) 2024; 11 Ran (D4MH00299G/cit4/1) 2023; 35 Chen (D4MH00299G/cit25/1) 2024; 479 Azizi (D4MH00299G/cit28/1) 2017; 29 Li (D4MH00299G/cit22/1) 2023; 10 Chi (D4MH00299G/cit16/1) 2019; 7 Peng (D4MH00299G/cit32/1) 2021; 21 Xiong (D4MH00299G/cit5/1) 2022; 10 Mannodi-Kanakkithodi (D4MH00299G/cit37/1) 2016; 28 Li (D4MH00299G/cit7/1) 2023; 466 Chen (D4MH00299G/cit10/1) 2023; 35 Yue (D4MH00299G/cit26/1) 2024; 11 Liu (D4MH00299G/cit3/1) 2022; 15 Xie (D4MH00299G/cit41/1) 2024 Ding (D4MH00299G/cit18/1) 2023; 453 Xue (D4MH00299G/cit29/1) 2024 Li (D4MH00299G/cit33/1) 2019; 478 Zhang (D4MH00299G/cit35/1) 2021; 401 Li (D4MH00299G/cit15/1) 2023; 10 Liu (D4MH00299G/cit24/1) 2023; 5 Cheng (D4MH00299G/cit19/1) 2021; 42 He (D4MH00299G/cit38/1) 2022; 446 Zhang (D4MH00299G/cit30/1) 2024; 121 Dong (D4MH00299G/cit9/1) 2021; 31 Huang (D4MH00299G/cit14/1) 2019; 100 Meng (D4MH00299G/cit23/1) 2023 Li (D4MH00299G/cit27/1) 2023; 15 Yang (D4MH00299G/cit40/1) 2023; 35 Wang (D4MH00299G/cit34/1) 2023; 14 Ding (D4MH00299G/cit6/1) 2023; 16 Feng (D4MH00299G/cit8/1) 2021; 8 Dong (D4MH00299G/cit1/1) 2023; 35 Dai (D4MH00299G/cit2/1) 2022; 34 Feng (D4MH00299G/cit13/1) 2021; 42 Wu (D4MH00299G/cit17/1) 2022; 427 Yu (D4MH00299G/cit36/1) 2023; 469 Ren (D4MH00299G/cit11/1) 2021; 201 Wang (D4MH00299G/cit31/1) 2023; 19 |
References_xml | – volume: 15 start-page: 41828 year: 2023 ident: D4MH00299G/cit27/1 publication-title: ACS Appl. Mater. Interfaces doi: 10.1021/acsami.3c06778 contributor: fullname: Li – volume: 35 start-page: 2211487 year: 2023 ident: D4MH00299G/cit1/1 publication-title: Adv. Mater. doi: 10.1002/adma.202211487 contributor: fullname: Dong – volume: 42 start-page: 2100116 year: 2021 ident: D4MH00299G/cit13/1 publication-title: Macromol. Rapid Commun. doi: 10.1002/marc.202100116 contributor: fullname: Feng – volume: 5 start-page: e12368 year: 2023 ident: D4MH00299G/cit24/1 publication-title: InfoMat doi: 10.1002/inf2.12368 contributor: fullname: Liu – volume: 34 start-page: 2101976 year: 2022 ident: D4MH00299G/cit2/1 publication-title: Adv. Mater. doi: 10.1002/adma.202101976 contributor: fullname: Dai – volume: 29 start-page: 1701864 year: 2017 ident: D4MH00299G/cit28/1 publication-title: Adv. Mater. doi: 10.1002/adma.201701864 contributor: fullname: Azizi – volume: 35 start-page: 2303849 year: 2023 ident: D4MH00299G/cit4/1 publication-title: Adv. Mater. doi: 10.1002/adma.202303849 contributor: fullname: Ran – volume: 16 start-page: 10183 year: 2023 ident: D4MH00299G/cit6/1 publication-title: Nano Res. doi: 10.1007/s12274-023-5580-7 contributor: fullname: Ding – start-page: 103485 year: 2024 ident: D4MH00299G/cit29/1 publication-title: Energy Storage Mater. doi: 10.1016/j.ensm.2024.103485 contributor: fullname: Xue – volume: 401 start-page: 123439 year: 2021 ident: D4MH00299G/cit35/1 publication-title: J. Hazard. Mater. doi: 10.1016/j.jhazmat.2020.123439 contributor: fullname: Zhang – volume: 10 start-page: 3651 year: 2023 ident: D4MH00299G/cit15/1 publication-title: Mater. Horiz. doi: 10.1039/D3MH00499F contributor: fullname: Li – volume: 8 start-page: 2102221 year: 2021 ident: D4MH00299G/cit8/1 publication-title: Adv. Sci. doi: 10.1002/advs.202102221 contributor: fullname: Feng – volume: 427 start-page: 131860 year: 2022 ident: D4MH00299G/cit17/1 publication-title: Chem. Eng. J. doi: 10.1016/j.cej.2021.131860 contributor: fullname: Wu – volume: 42 start-page: 445 year: 2021 ident: D4MH00299G/cit19/1 publication-title: Energy Storage Mater. doi: 10.1016/j.ensm.2021.07.018 contributor: fullname: Cheng – volume: 466 start-page: 143324 year: 2023 ident: D4MH00299G/cit7/1 publication-title: Chem. Eng. J. doi: 10.1016/j.cej.2023.143324 contributor: fullname: Li – volume: 35 start-page: 2302392 year: 2023 ident: D4MH00299G/cit40/1 publication-title: Adv. Mater. doi: 10.1002/adma.202302392 contributor: fullname: Yang – volume: 201 start-page: 108528 year: 2021 ident: D4MH00299G/cit11/1 publication-title: Compos. Sci. Technol. doi: 10.1016/j.compscitech.2020.108528 contributor: fullname: Ren – volume: 478 start-page: 451 year: 2019 ident: D4MH00299G/cit33/1 publication-title: Appl. Surf. Sci. doi: 10.1016/j.apsusc.2019.01.082 contributor: fullname: Li – volume: 35 start-page: 2306562 year: 2023 ident: D4MH00299G/cit10/1 publication-title: Adv. Mater. doi: 10.1002/adma.202306562 contributor: fullname: Chen – volume: 15 start-page: 56 year: 2022 ident: D4MH00299G/cit3/1 publication-title: Energy Environ. Sci. doi: 10.1039/D1EE03186D contributor: fullname: Liu – volume: 453 start-page: 139917 year: 2023 ident: D4MH00299G/cit18/1 publication-title: Chem. Eng. J. doi: 10.1016/j.cej.2022.139917 contributor: fullname: Ding – volume: 10 start-page: 2302949 year: 2023 ident: D4MH00299G/cit22/1 publication-title: Adv. Sci. doi: 10.1002/advs.202302949 contributor: fullname: Li – start-page: 2314910 year: 2024 ident: D4MH00299G/cit41/1 publication-title: Adv. Funct. Mater. doi: 10.1002/adfm.202314910 contributor: fullname: Xie – volume: 21 start-page: 203 year: 2021 ident: D4MH00299G/cit32/1 publication-title: Nano Lett. doi: 10.1021/acs.nanolett.0c03528 contributor: fullname: Peng – volume: 446 start-page: 137106 year: 2022 ident: D4MH00299G/cit38/1 publication-title: Chem. Eng. J. doi: 10.1016/j.cej.2022.137106 contributor: fullname: He – volume: 11 start-page: 1528 year: 2024 ident: D4MH00299G/cit21/1 publication-title: Mater. Horiz. doi: 10.1039/D3MH01822A contributor: fullname: Shang – volume: 9 start-page: 3002 year: 2022 ident: D4MH00299G/cit12/1 publication-title: Mater. Horiz. doi: 10.1039/D2MH00912A contributor: fullname: Feng – volume: 6 start-page: 18381 year: 2023 ident: D4MH00299G/cit20/1 publication-title: ACS Appl. Nano Mater. doi: 10.1021/acsanm.3c03648 contributor: fullname: Zuo – volume: 19 start-page: 588 year: 2024 ident: D4MH00299G/cit39/1 publication-title: Nat. Nanotechnol. doi: 10.1038/s41565-023-01541-w contributor: fullname: Yang – volume: 100 start-page: 187 year: 2019 ident: D4MH00299G/cit14/1 publication-title: Prog. Mater. Sci. doi: 10.1016/j.pmatsci.2018.10.003 contributor: fullname: Huang – volume: 121 start-page: 109271 year: 2024 ident: D4MH00299G/cit30/1 publication-title: Nano Energy doi: 10.1016/j.nanoen.2024.109271 contributor: fullname: Zhang – volume: 10 start-page: 24611 year: 2022 ident: D4MH00299G/cit5/1 publication-title: J. Mater. Chem. A doi: 10.1039/D2TA07214A contributor: fullname: Xiong – volume: 28 start-page: 6277 year: 2016 ident: D4MH00299G/cit37/1 publication-title: Adv. Mater. doi: 10.1002/adma.201600377 contributor: fullname: Mannodi-Kanakkithodi – volume: 14 start-page: 2406 year: 2023 ident: D4MH00299G/cit34/1 publication-title: Nat. Commun. doi: 10.1038/s41467-023-38145-w contributor: fullname: Wang – volume: 11 start-page: 3919 year: 2020 ident: D4MH00299G/cit42/1 publication-title: Nat. Commun. doi: 10.1038/s41467-020-17760-x contributor: fullname: Yuan – volume: 7 start-page: 748 year: 2019 ident: D4MH00299G/cit16/1 publication-title: ACS Sustainable Chem. Eng. doi: 10.1021/acssuschemeng.8b04370 contributor: fullname: Chi – volume: 11 start-page: 726 year: 2024 ident: D4MH00299G/cit26/1 publication-title: Mater. Horiz. doi: 10.1039/D3MH00907F contributor: fullname: Yue – volume: 19 start-page: 2208105 year: 2023 ident: D4MH00299G/cit31/1 publication-title: Small doi: 10.1002/smll.202208105 contributor: fullname: Wang – volume: 31 start-page: 2102644 year: 2021 ident: D4MH00299G/cit9/1 publication-title: Adv. Funct. Mater. doi: 10.1002/adfm.202102644 contributor: fullname: Dong – start-page: 2310272 year: 2023 ident: D4MH00299G/cit23/1 publication-title: Adv. Mater. doi: 10.1002/adma.202310272 contributor: fullname: Meng – volume: 479 start-page: 147581 year: 2024 ident: D4MH00299G/cit25/1 publication-title: Chem. Eng. J. doi: 10.1016/j.cej.2023.147581 contributor: fullname: Chen – volume: 469 start-page: 143803 year: 2023 ident: D4MH00299G/cit36/1 publication-title: Chem. Eng. J. doi: 10.1016/j.cej.2023.143803 contributor: fullname: Yu – volume: 17 start-page: 1592 year: 2024 ident: D4MH00299G/cit43/1 publication-title: Energy Environ. Sci. doi: 10.1039/D3EE03644H contributor: fullname: Yang |
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SubjectTerms | Boron nitride Capacitors Charge efficiency Crosslinking Dielectric breakdown Dielectric strength Discharge Energy storage Glass transition temperature Heat resistance High temperature Materials selection Polyetherimides Polyhedral oligomeric silsesquioxane Polymer films Thermal resistance |
Title | Enhancing the high-temperature energy storage properties of PEI dielectrics by constructing trap-rich covalently cross-linked networks via POSS-functionalized BNNS |
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