Sol-gel derived silicate-phosphate glass SiO2–P2O5–CaO–TiO2: The effect of titanium isopropoxide on porosity and thermomechanical stability
Despite of several decades lasting extensive research of bioactive and bioresorbable glasses the systematic parametrization and determination of the key factors affecting porosity and thermomechanical characteristics still remains challenging. Here, we present silica-phosphate glasses, with the comp...
Saved in:
| Published in | Microporous and mesoporous materials Vol. 374; p. 113138 |
|---|---|
| Main Authors | , , , , , , , , , , , , , , , , |
| Format | Journal Article |
| Language | English |
| Published |
Elsevier Inc
15.06.2024
|
| Online Access | Get full text |
Cover
Loading…
| Abstract | Despite of several decades lasting extensive research of bioactive and bioresorbable glasses the systematic parametrization and determination of the key factors affecting porosity and thermomechanical characteristics still remains challenging. Here, we present silica-phosphate glasses, with the composition 70SiO2–20P2O5–(10-x)CaO–xTiO2 (mol%; x = 0, 2.5, 5, and 7.5), prepared by sol-gel method and reinforced by titanium dioxide via titanium isopropoxide (TTIP) incorporation which demonstrated tunable variation of porosity from micro-to macro-region and superb mechanical integrity during the calcination process. The presence of 7.5 mol% TiO2 promotes dimensional stability up to 1000 °C as investigated by thermomechanical analysis. The XRD showed the dominant presence of silicon phosphate [Si(P2O7)], titanium phosphate [Ti(P2O7)] and calcium phosphates [β-Ca(P2O6) and γ- Ca2(P2O7)]. The effect of TiO2 doping on the multiscale morphology and porosity was investigated by means of SEM, MIP, μCT, N2 adsorption and USAXS/SAXS. Increasing TiO2 content leads to the formation of open porosity up to 70 vol% and drives the formation of a refined interconnected macroporosity of 2–30 μm. In contrast, mesoporosity with a dominance of 3–6 nm pores decreases in all samples with increasing TiO2 content. USAXS/SAXS revealed an increase in primary particle size with increasing TiO2 content which is in good agreement with the nitrogen physisorption analysis showing that microporosity decreases with increasing TiO2 content.
[Display omitted]
•The reinforcement of silica-phosphate glass with titanium dioxide via titanium isopropoxide.•The increasing TiO2 content led to the formation of open porosity 70 vol%.•The presence of TiO2 drives a formation of a fully interconnected framework at a macroscale.•Micro-/mesoporosity decreases with increasing TiO2 content.•USAXS/SAXS profiles indicated the hierarchical morphology of sol-gel glasses. |
|---|---|
| AbstractList | Despite of several decades lasting extensive research of bioactive and bioresorbable glasses the systematic parametrization and determination of the key factors affecting porosity and thermomechanical characteristics still remains challenging. Here, we present silica-phosphate glasses, with the composition 70SiO2–20P2O5–(10-x)CaO–xTiO2 (mol%; x = 0, 2.5, 5, and 7.5), prepared by sol-gel method and reinforced by titanium dioxide via titanium isopropoxide (TTIP) incorporation which demonstrated tunable variation of porosity from micro-to macro-region and superb mechanical integrity during the calcination process. The presence of 7.5 mol% TiO2 promotes dimensional stability up to 1000 °C as investigated by thermomechanical analysis. The XRD showed the dominant presence of silicon phosphate [Si(P2O7)], titanium phosphate [Ti(P2O7)] and calcium phosphates [β-Ca(P2O6) and γ- Ca2(P2O7)]. The effect of TiO2 doping on the multiscale morphology and porosity was investigated by means of SEM, MIP, μCT, N2 adsorption and USAXS/SAXS. Increasing TiO2 content leads to the formation of open porosity up to 70 vol% and drives the formation of a refined interconnected macroporosity of 2–30 μm. In contrast, mesoporosity with a dominance of 3–6 nm pores decreases in all samples with increasing TiO2 content. USAXS/SAXS revealed an increase in primary particle size with increasing TiO2 content which is in good agreement with the nitrogen physisorption analysis showing that microporosity decreases with increasing TiO2 content.
[Display omitted]
•The reinforcement of silica-phosphate glass with titanium dioxide via titanium isopropoxide.•The increasing TiO2 content led to the formation of open porosity 70 vol%.•The presence of TiO2 drives a formation of a fully interconnected framework at a macroscale.•Micro-/mesoporosity decreases with increasing TiO2 content.•USAXS/SAXS profiles indicated the hierarchical morphology of sol-gel glasses. |
| ArticleNumber | 113138 |
| Author | Tišler, Zdeněk Bělský, Petr Stich, Theresia Forejtová, Jana Ilavský, Jan Jandová, Věra Docheva, Denitsa Medlín, Rostislav Křenek, Tomáš Kovářík, Tomáš Mikysek, Petr Strejcová, Kateřina Svoboda, Miloš Kadlec, Jaroslav Pola, Michal Deshmukh, Kalim Beneš, Jan |
| Author_xml | – sequence: 1 givenname: Tomáš orcidid: 0000-0003-4838-4069 surname: Kovářík fullname: Kovářík, Tomáš email: toko@ntc.zcu.cz organization: University of West Bohemia, New Technologies – Research Centre, Univerzitní 8, 301 00 Pilsen, Czech Republic – sequence: 2 givenname: Petr surname: Bělský fullname: Bělský, Petr organization: University of West Bohemia, New Technologies – Research Centre, Univerzitní 8, 301 00 Pilsen, Czech Republic – sequence: 3 givenname: Tomáš surname: Křenek fullname: Křenek, Tomáš organization: University of West Bohemia, New Technologies – Research Centre, Univerzitní 8, 301 00 Pilsen, Czech Republic – sequence: 4 givenname: Kalim surname: Deshmukh fullname: Deshmukh, Kalim organization: University of West Bohemia, New Technologies – Research Centre, Univerzitní 8, 301 00 Pilsen, Czech Republic – sequence: 5 givenname: Jana surname: Forejtová fullname: Forejtová, Jana organization: University of West Bohemia, Faculty of Mechanical Engineering, Department of Material Science and Metallurgy, Univerzitní 8, 301 00, Pilsen, Czech Republic – sequence: 6 givenname: Rostislav surname: Medlín fullname: Medlín, Rostislav organization: University of West Bohemia, New Technologies – Research Centre, Univerzitní 8, 301 00 Pilsen, Czech Republic – sequence: 7 givenname: Jan surname: Beneš fullname: Beneš, Jan organization: University of West Bohemia, New Technologies – Research Centre, Univerzitní 8, 301 00 Pilsen, Czech Republic – sequence: 8 givenname: Miloš surname: Svoboda fullname: Svoboda, Miloš organization: University of West Bohemia, New Technologies – Research Centre, Univerzitní 8, 301 00 Pilsen, Czech Republic – sequence: 9 givenname: Jaroslav surname: Kadlec fullname: Kadlec, Jaroslav organization: University of West Bohemia, New Technologies – Research Centre, Univerzitní 8, 301 00 Pilsen, Czech Republic – sequence: 10 givenname: Michal surname: Pola fullname: Pola, Michal organization: University of West Bohemia, New Technologies – Research Centre, Univerzitní 8, 301 00 Pilsen, Czech Republic – sequence: 11 givenname: Věra surname: Jandová fullname: Jandová, Věra organization: Institute of Chemical Process Fundamentals of the Czech Academy of Sciences, Rozvojová 135, 165 02 Prague 6, Czech Republic – sequence: 12 givenname: Petr surname: Mikysek fullname: Mikysek, Petr organization: Institute of Geology of the Czech Academy of Sciences, Rozvojová 269, Praha 6, 165 00, Czech Republic – sequence: 13 givenname: Jan surname: Ilavský fullname: Ilavský, Jan organization: Advanced Photon Source, Argonne National Laboratory, Argonne, IL, 60439, USA – sequence: 14 givenname: Theresia surname: Stich fullname: Stich, Theresia organization: Experimental Trauma Surgery, Clinic and Policlinic for Trauma Surgery, University Hospital Regensburg, Franz-Josef-Strauss-Allee 11, Regensburg, 93053, Germany – sequence: 15 givenname: Denitsa surname: Docheva fullname: Docheva, Denitsa organization: University of West Bohemia, New Technologies – Research Centre, Univerzitní 8, 301 00 Pilsen, Czech Republic – sequence: 16 givenname: Kateřina surname: Strejcová fullname: Strejcová, Kateřina organization: ORLEN UniCRE, a.s., Areál Chempark 2838, Záluží 1, 436 70, Litvínov, Czech Republic – sequence: 17 givenname: Zdeněk surname: Tišler fullname: Tišler, Zdeněk organization: ORLEN UniCRE, a.s., Areál Chempark 2838, Záluží 1, 436 70, Litvínov, Czech Republic |
| BookMark | eNqFkE1OwzAQhS1UJFrgDPgCKZk4iV12qOJPQioSZW0Ze0JcJXFkm4ruuALihpwEoyK2bGaeRvPejL4ZmQxuQELOIJ9DDvX5Zt5b7V2Pwc2LvCjnAAyYOCBTEJxlLF-wSdJM8AwEwBGZhbDJc-BQwJR8PLoue8GOGvR2i4YG21mtImZj68LYJkVfOhUCfbSr4uv986FYVakt1SrVdZpd0HWLFJsGdaSuodFGNdjXntrgRu9G92YNUjfQ0XkXbNxRNRgaW_R9elq3aVmrjoaontPpuDshh43qAp7-9mPydH21Xt5m96ubu-XlfaaB1zETleDFomxAqBI5yytdMmOEhnKhOZRY64Lxoqo5E8IgR6GbJFWNCipR64YdE77PTfBC8NjI0dte-Z2EXP6QlRv5R1b-kJV7ssl5uXdiem9r0cugLQ4ajfUJgjTO_pvxDT0ejSE |
| Cites_doi | 10.1007/s10971-009-2121-0 10.1007/s10856-007-3079-5 10.1039/b814292k 10.3390/molecules27186085 10.1016/j.msec.2014.03.042 10.1107/S160057671800643X 10.1016/j.crci.2015.05.017 10.1016/j.micromeso.2012.02.004 10.1107/S0021889804008969 10.1039/C5MH00260E 10.1016/j.actbio.2016.06.033 10.1016/S0022-3093(01)00854-7 10.1021/jp3012798 10.1039/C5RA10982E 10.1039/b307119g 10.1021/acsomega.0c03335 10.1039/D0RA04287K 10.3390/min10010072 10.1039/B810675D 10.1107/S0021889895005292 10.1243/09544119JEIM836 10.1107/S0021889809002222 10.1016/j.actbio.2011.03.016 10.1111/ijac.13782 10.1007/s11661-012-1431-y 10.1016/j.matchemphys.2010.06.038 10.1111/ijac.12873 10.1016/j.ceramint.2018.05.180 10.1016/j.pmatsci.2015.12.001 10.1177/2041731417719170 10.1016/j.msec.2015.11.077 10.1002/jbm.1250 10.1016/j.msec.2011.04.022 10.1016/j.ceramint.2016.09.050 10.1016/j.biomaterials.2007.03.018 10.1016/j.jnoncrysol.2006.08.047 10.3390/molecules26082392 10.1007/978-3-319-93728-1_24 10.1006/jcat.1995.1118 10.1016/j.jmrt.2019.04.018 10.1016/j.mineng.2011.09.009 10.1016/j.ceramint.2017.01.061 10.1007/s10856-006-0432-z 10.1021/acs.chemrev.5b00690 10.1016/j.msec.2010.02.006 10.1016/j.ceramint.2019.07.096 10.1002/anbr.202000055 10.1023/A:1009627216939 10.3390/ma15041292 10.1016/j.biomaterials.2005.07.017 10.1007/s10856-012-4667-6 10.1016/S0142-9612(03)00546-5 10.1021/cr00099a003 10.1039/c0sm01348j 10.1016/j.actbio.2012.07.023 10.1590/0001-37652014106012 10.1038/srep10677 10.1016/j.bsecv.2021.03.004 10.1016/j.actbio.2007.11.007 10.1007/s10853-006-0160-2 10.1021/acs.langmuir.1c01593 |
| ContentType | Journal Article |
| Copyright | 2024 The Authors |
| Copyright_xml | – notice: 2024 The Authors |
| DBID | 6I. AAFTH AAYXX CITATION |
| DOI | 10.1016/j.micromeso.2024.113138 |
| DatabaseName | ScienceDirect Open Access Titles Elsevier:ScienceDirect:Open Access CrossRef |
| DatabaseTitle | CrossRef |
| DatabaseTitleList | |
| DeliveryMethod | fulltext_linktorsrc |
| Discipline | Engineering |
| EISSN | 1873-3093 |
| ExternalDocumentID | 10_1016_j_micromeso_2024_113138 S1387181124001604 |
| GroupedDBID | --K --M .~1 0R~ 123 1B1 1~. 1~5 4.4 457 4G. 5VS 6I. 7-5 71M 8P~ AABNK AABXZ AACTN AAEDT AAEDW AAEPC AAFTH AAIAV AAIKJ AAKOC AALRI AAOAW AAQFI AAXUO ABFNM ABMAC ABNUV ABXRA ABYKQ ACDAQ ACGFS ACRLP ADBBV ADEWK ADEZE AEBSH AEKER AENEX AEZYN AFKWA AFRZQ AFTJW AGHFR AGUBO AGYEJ AHPOS AIEXJ AIKHN AITUG AJOXV AKRWK AKURH ALMA_UNASSIGNED_HOLDINGS AMFUW AMRAJ AXJTR BKOJK BLXMC CS3 DU5 EBS EFJIC ENUVR EO8 EO9 EP2 EP3 F5P FDB FEDTE FIRID FNPLU FYGXN G-Q GBLVA HVGLF IHE J1W KOM MAGPM MO0 N9A O-L O9- OAUVE OZT P-8 P-9 P2P PC. Q38 RIG RNS ROL RPZ SDF SDG SES SEW SPC SPCBC SSG SSM SSZ T5K XPP ZMT ~02 ~G- 29M AAQXK AAXKI AAYXX ABXDB ACNNM ADMUD ASPBG AVWKF AZFZN CITATION EJD FGOYB HZ~ M41 R2- |
| ID | FETCH-LOGICAL-c176t-8587294f18a4e7305c43dd8c149c714e6c2372567388de7e8cf738a6ea1586cf3 |
| IEDL.DBID | .~1 |
| ISSN | 1387-1811 |
| IngestDate | Thu Sep 12 20:03:54 EDT 2024 Sat May 04 15:44:36 EDT 2024 |
| IsDoiOpenAccess | true |
| IsOpenAccess | true |
| IsPeerReviewed | true |
| IsScholarly | true |
| Language | English |
| License | This is an open access article under the CC BY license. |
| LinkModel | DirectLink |
| MergedId | FETCHMERGED-LOGICAL-c176t-8587294f18a4e7305c43dd8c149c714e6c2372567388de7e8cf738a6ea1586cf3 |
| ORCID | 0000-0003-4838-4069 |
| OpenAccessLink | https://www.sciencedirect.com/science/article/pii/S1387181124001604 |
| ParticipantIDs | crossref_primary_10_1016_j_micromeso_2024_113138 elsevier_sciencedirect_doi_10_1016_j_micromeso_2024_113138 |
| PublicationCentury | 2000 |
| PublicationDate | 2024-06-15 |
| PublicationDateYYYYMMDD | 2024-06-15 |
| PublicationDate_xml | – month: 06 year: 2024 text: 2024-06-15 day: 15 |
| PublicationDecade | 2020 |
| PublicationTitle | Microporous and mesoporous materials |
| PublicationYear | 2024 |
| Publisher | Elsevier Inc |
| Publisher_xml | – name: Elsevier Inc |
| References | Ahmed (bib54) 2004; 25 Neel, Knowles (bib23) 2008; 19 Baino, Fiorilli, Vitale-Brovarone (bib13) 2016; 42 Galarneau (bib33) 2016; 19 Baino, Fiume, Miola, Verné (bib5) 2018; 15 Zaharescu, Predoana, Pandele-Cusu (bib47) 2018 Boudin (bib52) 1993 Pierre (bib3) 2020 Hertz (bib49) 2012; 156 Rezabeigi, Wood-Adams, Drew (bib42) 2014; 40 Sakka (bib32) 2018 Ilavsky, Jemian (bib40) 2009; 42 Lin (bib64) 2009; 19 Lakhkar (bib29) 2012; 8 Mata (bib59) 2022; 61 Fu, Saiz, Rahaman, Tomsia (bib17) 2011; 31 Lepry, Nazhat (bib26) 2021; 1 Budnyk (bib35) 2012; 116 Pica (bib10) 2021; 26 . Sakka (bib2) 2018 Neel (bib20) 2009; 19 Fadeevam (bib51) 2022; 27 Shih (bib65) 2010; 30 Jones, Ehrenfried, Hench (bib41) 2006; 27 Simonsen, Søgaard (bib71) 2010; 53 Cacciotti, Lombardi, Bianco (bib48) 2012; 23 Neel, Chrzanowski, Knowles (bib53) 2008; 4 Gayathri Devi, Rajendrana, Rajendran (bib56) 2010; 124 Rahaman, Day, Bal, Fu, Jung, Bonewald, Tomsia (bib6) 2011; 7 El-Naggara (bib11) 2019; 12 Comesaña, Lusquiños, del Val (bib18) 2015; 5 Beaucage (bib66) 1995; 28 Rajendran, Gayathri Devi, Azooz, El-Batal (bib55) 2007; 353 Baino (bib15) 2018; 44 Sepulveda, Jones, Hench (bib58) 2002; 59 Deshmukh, Kovářík, Křenek, Docheva, Stich, Pola (bib60) 2020; 10 Ribas (bib16) 2019; 45 Jones, Lin, Yue, Lee, Hanna, Smith, Newport (bib61) 2010; 224 J. Ilavsky, F. Zhang, F., R. N. Andrews, I. Kuzmenko, P. R. Jemian, L. E. Levine, A. J. Allen, Development of combined microstructure and structure characterization facility for in situ and operando studies at the Advanced Photon Source, J. Appl. Crystallogr. 51, 867-882. Owens (bib4) 2016; 77 Kozik (bib27) 2020; 5 Nakanishi (bib37) 1997; 4 Hench, West (bib70) 1990; 90 Colodrero (bib9) 2022; 15 Knowles (bib19) 2003; 13 Moghanian (bib30) 2021; 18 Changa (bib36) 2017; 43 Li, Senesi, Lee (bib68) 2016; 116 Neel (bib24) 2007; 28 Valliant, Jones (bib50) 2011; 7 Izquierdo-Barba, Vallet-Regí (bib14) 2015; 1 Ribeiro (bib43) 2014; 86 Xu (bib63) 2020; 10 Hench (bib1) 2006; 17 VanDeventer, Provis, Duxson (bib62) 2012; 29 Beaucage, Kammler, Pratsinitis (bib67) 2004; 37 Danks, Hall, Schnepp (bib12) 2016; 3 Jalilpour, Rezvani, Farhadi (bib25) 2019; 5 Styskalik (bib46) 2015; 5 Soloviev, Søgaard (bib69) 2006; 41 Chang, Yan, Liu, Sun (bib22) 2017; 43 Islam (bib21) 2017; 8 Catauro, Renella, Papale, Ciprioti (bib44) 2016; 61 Smith, ElKashty, Tamimi, Tran, Cerruti (bib28) 2021; 37 E. Koontz, 24. Thermal analysis of glass, J.D. Musgraves, J. Hu, L. Calvez (Eds.), Springer Handbook of Glass, Springer Handbooks Ilavsky, Zhang, Allen, Levine, Jemian, Long (bib38) 2013; 44 Massiot, Centeno, Carrizosa, Odriozola (bib45) 2001; 292 Dutoit, Schneider, Baiker (bib34) 1995; 153 Pérez-Carrillo (bib8) 2016; 42 Owens (bib7) 2016; 77 Dalilah Johari (bib57) 2019; 8 Jones (10.1016/j.micromeso.2024.113138_bib61) 2010; 224 Li (10.1016/j.micromeso.2024.113138_bib68) 2016; 116 Sakka (10.1016/j.micromeso.2024.113138_bib32) 2018 Dutoit (10.1016/j.micromeso.2024.113138_bib34) 1995; 153 Owens (10.1016/j.micromeso.2024.113138_bib7) 2016; 77 El-Naggara (10.1016/j.micromeso.2024.113138_bib11) 2019; 12 Hench (10.1016/j.micromeso.2024.113138_bib1) 2006; 17 Owens (10.1016/j.micromeso.2024.113138_bib4) 2016; 77 Knowles (10.1016/j.micromeso.2024.113138_bib19) 2003; 13 Fadeevam (10.1016/j.micromeso.2024.113138_bib51) 2022; 27 Massiot (10.1016/j.micromeso.2024.113138_bib45) 2001; 292 Lin (10.1016/j.micromeso.2024.113138_bib64) 2009; 19 Ribas (10.1016/j.micromeso.2024.113138_bib16) 2019; 45 Cacciotti (10.1016/j.micromeso.2024.113138_bib48) 2012; 23 Sakka (10.1016/j.micromeso.2024.113138_bib2) 2018 Valliant (10.1016/j.micromeso.2024.113138_bib50) 2011; 7 10.1016/j.micromeso.2024.113138_bib31 Mata (10.1016/j.micromeso.2024.113138_bib59) 2022; 61 Chang (10.1016/j.micromeso.2024.113138_bib22) 2017; 43 Jalilpour (10.1016/j.micromeso.2024.113138_bib25) 2019; 5 Comesaña (10.1016/j.micromeso.2024.113138_bib18) 2015; 5 Ilavsky (10.1016/j.micromeso.2024.113138_bib40) 2009; 42 Rahaman (10.1016/j.micromeso.2024.113138_bib6) 2011; 7 Deshmukh (10.1016/j.micromeso.2024.113138_bib60) 2020; 10 10.1016/j.micromeso.2024.113138_bib39 Kozik (10.1016/j.micromeso.2024.113138_bib27) 2020; 5 Pérez-Carrillo (10.1016/j.micromeso.2024.113138_bib8) 2016; 42 Neel (10.1016/j.micromeso.2024.113138_bib24) 2007; 28 Rezabeigi (10.1016/j.micromeso.2024.113138_bib42) 2014; 40 Lakhkar (10.1016/j.micromeso.2024.113138_bib29) 2012; 8 Colodrero (10.1016/j.micromeso.2024.113138_bib9) 2022; 15 Moghanian (10.1016/j.micromeso.2024.113138_bib30) 2021; 18 Boudin (10.1016/j.micromeso.2024.113138_bib52) 1993 Xu (10.1016/j.micromeso.2024.113138_bib63) 2020; 10 Styskalik (10.1016/j.micromeso.2024.113138_bib46) 2015; 5 Jones (10.1016/j.micromeso.2024.113138_bib41) 2006; 27 Neel (10.1016/j.micromeso.2024.113138_bib20) 2009; 19 Ilavsky (10.1016/j.micromeso.2024.113138_bib38) 2013; 44 Beaucage (10.1016/j.micromeso.2024.113138_bib67) 2004; 37 Beaucage (10.1016/j.micromeso.2024.113138_bib66) 1995; 28 Pierre (10.1016/j.micromeso.2024.113138_bib3) 2020 Nakanishi (10.1016/j.micromeso.2024.113138_bib37) 1997; 4 Ahmed (10.1016/j.micromeso.2024.113138_bib54) 2004; 25 Baino (10.1016/j.micromeso.2024.113138_bib5) 2018; 15 Fu (10.1016/j.micromeso.2024.113138_bib17) 2011; 31 Islam (10.1016/j.micromeso.2024.113138_bib21) 2017; 8 Smith (10.1016/j.micromeso.2024.113138_bib28) 2021; 37 Hertz (10.1016/j.micromeso.2024.113138_bib49) 2012; 156 Danks (10.1016/j.micromeso.2024.113138_bib12) 2016; 3 Baino (10.1016/j.micromeso.2024.113138_bib15) 2018; 44 Galarneau (10.1016/j.micromeso.2024.113138_bib33) 2016; 19 Changa (10.1016/j.micromeso.2024.113138_bib36) 2017; 43 Soloviev (10.1016/j.micromeso.2024.113138_bib69) 2006; 41 Rajendran (10.1016/j.micromeso.2024.113138_bib55) 2007; 353 Gayathri Devi (10.1016/j.micromeso.2024.113138_bib56) 2010; 124 Dalilah Johari (10.1016/j.micromeso.2024.113138_bib57) 2019; 8 Neel (10.1016/j.micromeso.2024.113138_bib53) 2008; 4 Lepry (10.1016/j.micromeso.2024.113138_bib26) 2021; 1 Budnyk (10.1016/j.micromeso.2024.113138_bib35) 2012; 116 Catauro (10.1016/j.micromeso.2024.113138_bib44) 2016; 61 Shih (10.1016/j.micromeso.2024.113138_bib65) 2010; 30 Neel (10.1016/j.micromeso.2024.113138_bib23) 2008; 19 Baino (10.1016/j.micromeso.2024.113138_bib13) 2016; 42 VanDeventer (10.1016/j.micromeso.2024.113138_bib62) 2012; 29 Zaharescu (10.1016/j.micromeso.2024.113138_bib47) 2018 Izquierdo-Barba (10.1016/j.micromeso.2024.113138_bib14) 2015; 1 Ribeiro (10.1016/j.micromeso.2024.113138_bib43) 2014; 86 Pica (10.1016/j.micromeso.2024.113138_bib10) 2021; 26 Hench (10.1016/j.micromeso.2024.113138_bib70) 1990; 90 Simonsen (10.1016/j.micromeso.2024.113138_bib71) 2010; 53 Sepulveda (10.1016/j.micromeso.2024.113138_bib58) 2002; 59 |
| References_xml | – volume: 29 start-page: 89 year: 2012 end-page: 104 ident: bib62 article-title: Technical and commercial progress in the adoption of geopolymer cement publication-title: Miner. Eng. contributor: fullname: Duxson – volume: 19 start-page: 690 year: 2009 end-page: 701 ident: bib20 article-title: Bioactive functional materials: a perspective on phosphate-based glasses publication-title: J. Mater. Chem. contributor: fullname: Neel – volume: 153 start-page: 165e176 year: 1995 ident: bib34 article-title: Titania-silica mixed oxides: I. Influence of sol-gel and drying conditions on structural properties publication-title: J. Catal. contributor: fullname: Baiker – volume: 27 start-page: 6085 year: 2022 ident: bib51 article-title: Strontium substituted β-tricalcium phosphate ceramics: physiochemical properties and cytocompatibility publication-title: Molecules contributor: fullname: Fadeevam – volume: 19 start-page: 1276 year: 2009 end-page: 1282 ident: bib64 article-title: Nanostructure evolution and calcium distribution in sol–gel derived bioactive glass publication-title: J. Mater. Chem. contributor: fullname: Lin – volume: 156 start-page: 51 year: 2012 end-page: 61 ident: bib49 article-title: Preparation and characterisation of porous silica and silica/titania monoliths for potential use in bone replacement publication-title: Microporous Mesoporous Mater. contributor: fullname: Hertz – volume: 5 start-page: 73670 year: 2015 end-page: 73676 ident: bib46 article-title: Non-aqueous template-assisted synthesis of mesoporous nanocrystalline silicon orthophosphate publication-title: RSC Adv. contributor: fullname: Styskalik – volume: 10 year: 2020 ident: bib60 article-title: Recent advances and future perspectives of sol–gel derived porous bioactive glasses: a review publication-title: RSC Adv. contributor: fullname: Pola – volume: 27 start-page: 964 year: 2006 end-page: 973 ident: bib41 article-title: Optimising bioactive glass scaffolds for bone tissue engineering publication-title: Biomaterials contributor: fullname: Hench – volume: 31 start-page: 1245 year: 2011 end-page: 1256 ident: bib17 article-title: Bioactive glass scaffolds for bone tissue engineering: state of the art and future perspectives publication-title: Mater. Sci. Eng. C contributor: fullname: Tomsia – volume: 116 start-page: 10064 year: 2012 end-page: 10072 ident: bib35 article-title: Synthesis and characterization of high-surface-area Silica−Titania monoliths publication-title: J. Phys. Chem. C contributor: fullname: Budnyk – volume: 43 start-page: 5881 year: 2017 end-page: 5886 ident: bib36 article-title: Photocatalyic activity of double pore structure TiO2/SiO2 monoliths publication-title: Ceram. Int. contributor: fullname: Changa – volume: 5 start-page: 27221 year: 2020 end-page: 27226 ident: bib27 article-title: Preparation of CaO@TiO2−SiO2 biomaterial with a Sol−Gel method for bone implantation publication-title: ACS Omega contributor: fullname: Kozik – volume: 4 start-page: 523 year: 2008 end-page: 534 ident: bib53 article-title: Effect of increasing titanium dioxide content on bulk and surface properties of phosphate-based glasses publication-title: Acta Biomat contributor: fullname: Knowles – volume: 17 start-page: 967 year: 2006 end-page: 978 ident: bib1 publication-title: J. Mater. Sci. Mater. Med. contributor: fullname: Hench – volume: 19 start-page: 231 year: 2016 end-page: 247 ident: bib33 article-title: Hierarchical porous silica monoliths: a novel class of microreactors for process intensification in catalysis and adsorption publication-title: C. R. Chimie contributor: fullname: Galarneau – volume: 5 year: 2015 ident: bib18 article-title: Toward smart implant synthesis: bonding bioceramics of different resorbability to match bone growth rates publication-title: Sci. Rep. contributor: fullname: del Val – volume: 30 start-page: 657 year: 2010 end-page: 663 ident: bib65 article-title: Synthesis and in vitro bioactivity of mesoporous bioactive glass scaffolds publication-title: Mater. Sci. Eng. C contributor: fullname: Shih – volume: 4 start-page: 67 year: 1997 end-page: 112 ident: bib37 article-title: Pore structure control of silica gels based on phase separation publication-title: J. Porous Mater. contributor: fullname: Nakanishi – volume: 10 start-page: 72 year: 2020 ident: bib63 article-title: Pore structure and fractal characteristics of different shale lithofacies in the dalong formation in the western area of the lower yangtze platform publication-title: Minerals contributor: fullname: Xu – volume: 8 start-page: 4181 year: 2012 end-page: 4190 ident: bib29 article-title: Titanium phosphate glass microspheres for bone tissue engineering publication-title: Acta Biomat contributor: fullname: Lakhkar – volume: 7 start-page: 2355 year: 2011 end-page: 2373 ident: bib6 article-title: Bioactive glass in tissue engineering publication-title: Acta Biomater. contributor: fullname: Tomsia – volume: 13 start-page: 2395 year: 2003 end-page: 2401 ident: bib19 article-title: Phosphate based glasses for biomedical applications publication-title: J. Mater. Chem. contributor: fullname: Knowles – volume: 23 start-page: 1849 year: 2012 end-page: 1866 ident: bib48 article-title: Sol–gel derived 45S5 bioglass: synthesis, microstructural evolution and thermal behaviour publication-title: J. Mater. Sci. Mater. Med. contributor: fullname: Bianco – volume: 1 year: 2021 ident: bib26 article-title: A review of phosphate and borate sol–gel glasses for biomedical applications publication-title: Adv. NanoBiomed Res. contributor: fullname: Nazhat – volume: 25 start-page: 491 year: 2004 end-page: 499 ident: bib54 article-title: Phosphate glasses for tissue engineering: Part 1. Processing and characterisation of a ternary-based P2O5–CaO–Na2O glass system publication-title: Biomaterials contributor: fullname: Ahmed – volume: 15 start-page: 841 year: 2018 end-page: 860 ident: bib5 article-title: Bioactive sol-gel glasses: processing, properties, and applications publication-title: Int. J. Appl. Ceram. Technol. contributor: fullname: Verné – volume: 77 start-page: 1 year: 2016 end-page: 79 ident: bib4 article-title: Sol–gel based materials for biomedical applications publication-title: Prog. Mater. Sci. contributor: fullname: Owens – year: 2020 ident: bib3 article-title: Applications of sol-gel processing publication-title: Introduction to Sol-Gel Processing contributor: fullname: Pierre – year: 2018 ident: bib47 article-title: Thermal analysis on gels, glasses, and powders publication-title: Handbook of Sol-Gel Science and Technology contributor: fullname: Pandele-Cusu – volume: 292 start-page: 158 year: 2001 end-page: 166 ident: bib45 article-title: Thermal evolution of sol-gel-obtained phosphosilicate solids (SiPO) publication-title: J. Non-Cryst. Solids contributor: fullname: Odriozola – volume: 53 start-page: 485 year: 2010 end-page: 497 ident: bib71 article-title: Sol–gel reactions of titanium alkoxides and water: influence of pH and alkoxy group on cluster formation and properties of the resulting products publication-title: J. Sol. Gel Sci. Technol. contributor: fullname: Søgaard – volume: 18 start-page: 1430 year: 2021 end-page: 1441 ident: bib30 article-title: Characterization, in vitro bioactivity and biological studies of sol-gel-derived TiO2 substituted 58S bioactive glass publication-title: Int. J. Appl. Ceram. Technol. contributor: fullname: Moghanian – volume: 41 start-page: 6159 year: 2006 end-page: 6161 ident: bib69 article-title: Application of electro-spray ionization mass spectrometry for characterization of titanium polyoxoalkoxides in sol-gel processes publication-title: J. Mater. Sci. contributor: fullname: Søgaard – volume: 44 start-page: 14953 year: 2018 end-page: 14966 ident: bib15 article-title: Bioactive glasses – when glass science and technology meet regenerative medicine publication-title: Ceram. Int. contributor: fullname: Baino – volume: 45 start-page: 21051 year: 2019 end-page: 21061 ident: bib16 article-title: Current advances in bone tissue engineering concerning ceramic and bioglass scaffolds: a review publication-title: Ceram. Int. contributor: fullname: Ribas – volume: 86 year: 2014 ident: bib43 article-title: Sol-gel as methodology to obtain bioactive materials publication-title: An. Acad. Bras. Cienc. contributor: fullname: Ribeiro – volume: 37 start-page: 14243 year: 2021 end-page: 14253 ident: bib28 article-title: Titanium-containing silicate-based sol–gel bioactive glass: development, characterization, and applications publication-title: Langmuir contributor: fullname: Cerruti – volume: 59 start-page: 340 year: 2002 end-page: 348 ident: bib58 article-title: Bioactive sol-gel foams for tissue repair publication-title: J. Biomed. Mater. Res. contributor: fullname: Hench – volume: 77 start-page: 1 year: 2016 end-page: 79 ident: bib7 article-title: Sol–gel based materials for biomedical applications publication-title: Prog. Mater. Sci. contributor: fullname: Owens – volume: 42 start-page: 18 year: 2016 end-page: 32 ident: bib13 article-title: Bioactive glass-based materials with hierarchical porosity for medical applications: review of recent advances publication-title: Acta. Biomat. contributor: fullname: Vitale-Brovarone – volume: 12 start-page: 319 year: 2019 end-page: 331 ident: bib11 article-title: Sorption of cesium and cobalt ions onto novel zirconium silicophosphate/polyacrylamide nanocomposite publication-title: J. radiat. res. appl. sci. contributor: fullname: El-Naggara – year: 2018 ident: bib32 article-title: Sol-gel formation of bulk glasses publication-title: Handbook of Sol-Gel Science and Technology contributor: fullname: Sakka – volume: 37 start-page: 523 year: 2004 end-page: 535 ident: bib67 article-title: Particle size distributions from small-angle scattering using global scattering functions publication-title: J. Appl. Crystallogr. contributor: fullname: Pratsinitis – volume: 42 start-page: 18965 year: 2016 end-page: 18973 ident: bib8 article-title: Synthesis and properties of TiO2-P2O5 and SiO2-TiO2-P2O5 porous hybrids obtained by templating in highly concentrated emulsions publication-title: Ceram. Int. contributor: fullname: Pérez-Carrillo – volume: 28 start-page: 2967 year: 2007 end-page: 2977 ident: bib24 article-title: In vitro bioactivity and gene expression by cells cultured on titanium dioxide doped phosphate-based glasses publication-title: Biomat contributor: fullname: Neel – volume: 61 start-page: 51 year: 2016 end-page: 55 ident: bib44 article-title: Investigation of bioactivity, biocompatibility and thermal behavior of sol–gel silica glass containing a high PEG percentage publication-title: Mater. Sci. Eng. C. contributor: fullname: Ciprioti – volume: 353 start-page: 77 year: 2007 end-page: 84 ident: bib55 article-title: Physicochemical studies of phosphate based P2O5–Na2O–CaO–TiO2 glasses for biomedical applications publication-title: J. Non-Cryst. Solids contributor: fullname: El-Batal – volume: 224 start-page: 1373 year: 2010 end-page: 1387 ident: bib61 article-title: Bioactive glass scaffolds for bone regeneration and their hierarchical characterization publication-title: Proc. Inst. Mech. Eng. H. contributor: fullname: Newport – volume: 8 start-page: 1 year: 2017 end-page: 16 ident: bib21 article-title: Bioactive calcium phosphate–based glasses and ceramics and their biomedical applications: a review publication-title: J. Tissue Eng. contributor: fullname: Islam – volume: 40 start-page: 248 year: 2014 end-page: 252 ident: bib42 article-title: Synthesis of 45S5 Bioglass® via a straightforward organic, nitrate-free sol–gel process publication-title: Mater. Sci. Eng. C. contributor: fullname: Drew – volume: 8 start-page: 2350 year: 2019 end-page: 2358 ident: bib57 article-title: Comparison on the TiO2 crystalline phases deposited via dip and spin coating using green sol–gel route publication-title: J. Mater. Res. Technol. contributor: fullname: Dalilah Johari – volume: 1 start-page: 140 year: 2015 end-page: 150 ident: bib14 article-title: Mesoporous bioactive glasses: relevance of their porous structure compared to that of classical bioglasses Biomed publication-title: Glasses contributor: fullname: Vallet-Regí – volume: 26 start-page: 2392 year: 2021 ident: bib10 article-title: Treatment of wastewaters with zirconium phosphate based materials: a review on efficient systems for the removal of heavy metal and dye water pollutants publication-title: Molecules contributor: fullname: Pica – volume: 44 start-page: 68 year: 2013 end-page: 76 ident: bib38 article-title: Ultra-small-angle X-ray scattering instrument at the advanced photon source: history, recent development, and Current status publication-title: Metall. Mater. Trans. A contributor: fullname: Long – volume: 42 start-page: 347 year: 2009 end-page: 353 ident: bib40 article-title: : tool suite for modeling and analysis of small-angle scattering publication-title: J. Appl. Crystallogr. contributor: fullname: Jemian – volume: 43 start-page: 5881 year: 2017 end-page: 5886 ident: bib22 article-title: Photocatalyic activity of double pore structure TiO2/SiO2 monoliths publication-title: Ceram. Int. contributor: fullname: Sun – volume: 19 start-page: 377 year: 2008 end-page: 386 ident: bib23 article-title: Physical and biocompatibility studies of novel titanium dioxide doped phosphate-based glasses for bone tissue engineering applications publication-title: J. Mater. Sci. Mater. Med. contributor: fullname: Knowles – volume: 124 start-page: 312 year: 2010 end-page: 318 ident: bib56 article-title: Structure, solubility and bioactivity in TiO2-doped phosphate-based bioglasses and glass–ceramics publication-title: Mat. Chem. Phys. contributor: fullname: Rajendran – volume: 61 start-page: 384 year: 2022 end-page: 396 ident: bib59 article-title: 3D multiphasic porous scaffolds of calcium phosphates doping with silicon and magnesium publication-title: Bol. Soc. Espanola Ceram. Vidr. contributor: fullname: Mata – volume: 90 start-page: 33 year: 1990 end-page: 72 ident: bib70 article-title: The sol-gel process publication-title: Chem. Rev. contributor: fullname: West – volume: 15 start-page: 1292 year: 2022 ident: bib9 article-title: Properties and applications of metal phosphates and pyrophosphates as Proton conductors publication-title: Materials contributor: fullname: Colodrero – start-page: 2062 year: 1993 end-page: 2064 ident: bib52 article-title: Redetermination of the [beta]-Ca2P2O7 structure publication-title: Acta Cryst contributor: fullname: Boudin – volume: 7 start-page: 5083 year: 2011 ident: bib50 article-title: Softening bioactive glass for bone regeneration: sol–gel hybrid materials publication-title: Soft Matter contributor: fullname: Jones – volume: 5 start-page: 6 year: 2019 end-page: 11 ident: bib25 article-title: Characterization and bioactivity of a quaternary phosphate-based glass powder synthesized by sol-gel method publication-title: ACERP contributor: fullname: Farhadi – volume: 28 start-page: 717 year: 1995 end-page: 728 ident: bib66 article-title: Approximations leading to a unified exponential/power-law approach to small-angle scattering publication-title: J. Appl. Crystallogr. contributor: fullname: Beaucage – volume: 3 start-page: 91 year: 2016 ident: bib12 article-title: The evolution of ‘sol–gel’ chemistry as a technique for materials synthesis publication-title: Mater. Horiz. contributor: fullname: Schnepp – volume: 116 start-page: 11128 year: 2016 end-page: 11180 ident: bib68 article-title: Small angle X-ray scattering for nanoparticle research publication-title: Chem. Rev. contributor: fullname: Lee – year: 2018 ident: bib2 article-title: Sol-gel formation of bulk glasses publication-title: Handbook of Sol-Gel Science and Technology contributor: fullname: Sakka – volume: 53 start-page: 485 year: 2010 ident: 10.1016/j.micromeso.2024.113138_bib71 article-title: Sol–gel reactions of titanium alkoxides and water: influence of pH and alkoxy group on cluster formation and properties of the resulting products publication-title: J. Sol. Gel Sci. Technol. doi: 10.1007/s10971-009-2121-0 contributor: fullname: Simonsen – volume: 19 start-page: 377 year: 2008 ident: 10.1016/j.micromeso.2024.113138_bib23 article-title: Physical and biocompatibility studies of novel titanium dioxide doped phosphate-based glasses for bone tissue engineering applications publication-title: J. Mater. Sci. Mater. Med. doi: 10.1007/s10856-007-3079-5 contributor: fullname: Neel – volume: 19 start-page: 1276 year: 2009 ident: 10.1016/j.micromeso.2024.113138_bib64 article-title: Nanostructure evolution and calcium distribution in sol–gel derived bioactive glass publication-title: J. Mater. Chem. doi: 10.1039/b814292k contributor: fullname: Lin – volume: 27 start-page: 6085 issue: 18 year: 2022 ident: 10.1016/j.micromeso.2024.113138_bib51 article-title: Strontium substituted β-tricalcium phosphate ceramics: physiochemical properties and cytocompatibility publication-title: Molecules doi: 10.3390/molecules27186085 contributor: fullname: Fadeevam – volume: 40 start-page: 248 year: 2014 ident: 10.1016/j.micromeso.2024.113138_bib42 article-title: Synthesis of 45S5 Bioglass® via a straightforward organic, nitrate-free sol–gel process publication-title: Mater. Sci. Eng. C. doi: 10.1016/j.msec.2014.03.042 contributor: fullname: Rezabeigi – ident: 10.1016/j.micromeso.2024.113138_bib39 doi: 10.1107/S160057671800643X – volume: 19 start-page: 231 year: 2016 ident: 10.1016/j.micromeso.2024.113138_bib33 article-title: Hierarchical porous silica monoliths: a novel class of microreactors for process intensification in catalysis and adsorption publication-title: C. R. Chimie doi: 10.1016/j.crci.2015.05.017 contributor: fullname: Galarneau – volume: 12 start-page: 319 issue: 1 year: 2019 ident: 10.1016/j.micromeso.2024.113138_bib11 article-title: Sorption of cesium and cobalt ions onto novel zirconium silicophosphate/polyacrylamide nanocomposite publication-title: J. radiat. res. appl. sci. contributor: fullname: El-Naggara – volume: 156 start-page: 51 year: 2012 ident: 10.1016/j.micromeso.2024.113138_bib49 article-title: Preparation and characterisation of porous silica and silica/titania monoliths for potential use in bone replacement publication-title: Microporous Mesoporous Mater. doi: 10.1016/j.micromeso.2012.02.004 contributor: fullname: Hertz – volume: 37 start-page: 523 year: 2004 ident: 10.1016/j.micromeso.2024.113138_bib67 article-title: Particle size distributions from small-angle scattering using global scattering functions publication-title: J. Appl. Crystallogr. doi: 10.1107/S0021889804008969 contributor: fullname: Beaucage – volume: 3 start-page: 91 year: 2016 ident: 10.1016/j.micromeso.2024.113138_bib12 article-title: The evolution of ‘sol–gel’ chemistry as a technique for materials synthesis publication-title: Mater. Horiz. doi: 10.1039/C5MH00260E contributor: fullname: Danks – volume: 42 start-page: 18 year: 2016 ident: 10.1016/j.micromeso.2024.113138_bib13 article-title: Bioactive glass-based materials with hierarchical porosity for medical applications: review of recent advances publication-title: Acta. Biomat. doi: 10.1016/j.actbio.2016.06.033 contributor: fullname: Baino – volume: 292 start-page: 158 year: 2001 ident: 10.1016/j.micromeso.2024.113138_bib45 article-title: Thermal evolution of sol-gel-obtained phosphosilicate solids (SiPO) publication-title: J. Non-Cryst. Solids doi: 10.1016/S0022-3093(01)00854-7 contributor: fullname: Massiot – volume: 116 start-page: 10064 year: 2012 ident: 10.1016/j.micromeso.2024.113138_bib35 article-title: Synthesis and characterization of high-surface-area Silica−Titania monoliths publication-title: J. Phys. Chem. C doi: 10.1021/jp3012798 contributor: fullname: Budnyk – volume: 5 start-page: 73670 year: 2015 ident: 10.1016/j.micromeso.2024.113138_bib46 article-title: Non-aqueous template-assisted synthesis of mesoporous nanocrystalline silicon orthophosphate publication-title: RSC Adv. doi: 10.1039/C5RA10982E contributor: fullname: Styskalik – volume: 13 start-page: 2395 year: 2003 ident: 10.1016/j.micromeso.2024.113138_bib19 article-title: Phosphate based glasses for biomedical applications publication-title: J. Mater. Chem. doi: 10.1039/b307119g contributor: fullname: Knowles – volume: 1 start-page: 140 year: 2015 ident: 10.1016/j.micromeso.2024.113138_bib14 article-title: Mesoporous bioactive glasses: relevance of their porous structure compared to that of classical bioglasses Biomed publication-title: Glasses contributor: fullname: Izquierdo-Barba – volume: 5 start-page: 6 issue: No.2 year: 2019 ident: 10.1016/j.micromeso.2024.113138_bib25 article-title: Characterization and bioactivity of a quaternary phosphate-based glass powder synthesized by sol-gel method publication-title: ACERP contributor: fullname: Jalilpour – year: 2020 ident: 10.1016/j.micromeso.2024.113138_bib3 article-title: Applications of sol-gel processing contributor: fullname: Pierre – volume: 5 start-page: 27221 year: 2020 ident: 10.1016/j.micromeso.2024.113138_bib27 article-title: Preparation of CaO@TiO2−SiO2 biomaterial with a Sol−Gel method for bone implantation publication-title: ACS Omega doi: 10.1021/acsomega.0c03335 contributor: fullname: Kozik – volume: 10 year: 2020 ident: 10.1016/j.micromeso.2024.113138_bib60 article-title: Recent advances and future perspectives of sol–gel derived porous bioactive glasses: a review publication-title: RSC Adv. doi: 10.1039/D0RA04287K contributor: fullname: Deshmukh – volume: 10 start-page: 72 issue: 1 year: 2020 ident: 10.1016/j.micromeso.2024.113138_bib63 article-title: Pore structure and fractal characteristics of different shale lithofacies in the dalong formation in the western area of the lower yangtze platform publication-title: Minerals doi: 10.3390/min10010072 contributor: fullname: Xu – volume: 19 start-page: 690 year: 2009 ident: 10.1016/j.micromeso.2024.113138_bib20 article-title: Bioactive functional materials: a perspective on phosphate-based glasses publication-title: J. Mater. Chem. doi: 10.1039/B810675D contributor: fullname: Neel – volume: 28 start-page: 717 year: 1995 ident: 10.1016/j.micromeso.2024.113138_bib66 article-title: Approximations leading to a unified exponential/power-law approach to small-angle scattering publication-title: J. Appl. Crystallogr. doi: 10.1107/S0021889895005292 contributor: fullname: Beaucage – volume: 224 start-page: 1373 issue: 12 year: 2010 ident: 10.1016/j.micromeso.2024.113138_bib61 article-title: Bioactive glass scaffolds for bone regeneration and their hierarchical characterization publication-title: Proc. Inst. Mech. Eng. H. doi: 10.1243/09544119JEIM836 contributor: fullname: Jones – volume: 42 start-page: 347 year: 2009 ident: 10.1016/j.micromeso.2024.113138_bib40 article-title: Irena: tool suite for modeling and analysis of small-angle scattering publication-title: J. Appl. Crystallogr. doi: 10.1107/S0021889809002222 contributor: fullname: Ilavsky – volume: 7 start-page: 2355 year: 2011 ident: 10.1016/j.micromeso.2024.113138_bib6 article-title: Bioactive glass in tissue engineering publication-title: Acta Biomater. doi: 10.1016/j.actbio.2011.03.016 contributor: fullname: Rahaman – volume: 18 start-page: 1430 year: 2021 ident: 10.1016/j.micromeso.2024.113138_bib30 article-title: Characterization, in vitro bioactivity and biological studies of sol-gel-derived TiO2 substituted 58S bioactive glass publication-title: Int. J. Appl. Ceram. Technol. doi: 10.1111/ijac.13782 contributor: fullname: Moghanian – volume: 44 start-page: 68 year: 2013 ident: 10.1016/j.micromeso.2024.113138_bib38 article-title: Ultra-small-angle X-ray scattering instrument at the advanced photon source: history, recent development, and Current status publication-title: Metall. Mater. Trans. A doi: 10.1007/s11661-012-1431-y contributor: fullname: Ilavsky – volume: 124 start-page: 312 year: 2010 ident: 10.1016/j.micromeso.2024.113138_bib56 article-title: Structure, solubility and bioactivity in TiO2-doped phosphate-based bioglasses and glass–ceramics publication-title: Mat. Chem. Phys. doi: 10.1016/j.matchemphys.2010.06.038 contributor: fullname: Gayathri Devi – volume: 15 start-page: 841 year: 2018 ident: 10.1016/j.micromeso.2024.113138_bib5 article-title: Bioactive sol-gel glasses: processing, properties, and applications publication-title: Int. J. Appl. Ceram. Technol. doi: 10.1111/ijac.12873 contributor: fullname: Baino – volume: 44 start-page: 14953 year: 2018 ident: 10.1016/j.micromeso.2024.113138_bib15 article-title: Bioactive glasses – when glass science and technology meet regenerative medicine publication-title: Ceram. Int. doi: 10.1016/j.ceramint.2018.05.180 contributor: fullname: Baino – start-page: 2062 issue: C49 year: 1993 ident: 10.1016/j.micromeso.2024.113138_bib52 article-title: Redetermination of the [beta]-Ca2P2O7 structure publication-title: Acta Cryst contributor: fullname: Boudin – volume: 77 start-page: 1 year: 2016 ident: 10.1016/j.micromeso.2024.113138_bib4 article-title: Sol–gel based materials for biomedical applications publication-title: Prog. Mater. Sci. doi: 10.1016/j.pmatsci.2015.12.001 contributor: fullname: Owens – volume: 8 start-page: 1 year: 2017 ident: 10.1016/j.micromeso.2024.113138_bib21 article-title: Bioactive calcium phosphate–based glasses and ceramics and their biomedical applications: a review publication-title: J. Tissue Eng. doi: 10.1177/2041731417719170 contributor: fullname: Islam – volume: 61 start-page: 51 year: 2016 ident: 10.1016/j.micromeso.2024.113138_bib44 article-title: Investigation of bioactivity, biocompatibility and thermal behavior of sol–gel silica glass containing a high PEG percentage publication-title: Mater. Sci. Eng. C. doi: 10.1016/j.msec.2015.11.077 contributor: fullname: Catauro – volume: 59 start-page: 340 issue: 2 year: 2002 ident: 10.1016/j.micromeso.2024.113138_bib58 article-title: Bioactive sol-gel foams for tissue repair publication-title: J. Biomed. Mater. Res. doi: 10.1002/jbm.1250 contributor: fullname: Sepulveda – volume: 31 start-page: 1245 year: 2011 ident: 10.1016/j.micromeso.2024.113138_bib17 article-title: Bioactive glass scaffolds for bone tissue engineering: state of the art and future perspectives publication-title: Mater. Sci. Eng. C doi: 10.1016/j.msec.2011.04.022 contributor: fullname: Fu – volume: 42 start-page: 18965 year: 2016 ident: 10.1016/j.micromeso.2024.113138_bib8 article-title: Synthesis and properties of TiO2-P2O5 and SiO2-TiO2-P2O5 porous hybrids obtained by templating in highly concentrated emulsions publication-title: Ceram. Int. doi: 10.1016/j.ceramint.2016.09.050 contributor: fullname: Pérez-Carrillo – volume: 28 start-page: 2967 year: 2007 ident: 10.1016/j.micromeso.2024.113138_bib24 article-title: In vitro bioactivity and gene expression by cells cultured on titanium dioxide doped phosphate-based glasses publication-title: Biomat doi: 10.1016/j.biomaterials.2007.03.018 contributor: fullname: Neel – volume: 353 start-page: 77 year: 2007 ident: 10.1016/j.micromeso.2024.113138_bib55 article-title: Physicochemical studies of phosphate based P2O5–Na2O–CaO–TiO2 glasses for biomedical applications publication-title: J. Non-Cryst. Solids doi: 10.1016/j.jnoncrysol.2006.08.047 contributor: fullname: Rajendran – volume: 26 start-page: 2392 issue: 8 year: 2021 ident: 10.1016/j.micromeso.2024.113138_bib10 article-title: Treatment of wastewaters with zirconium phosphate based materials: a review on efficient systems for the removal of heavy metal and dye water pollutants publication-title: Molecules doi: 10.3390/molecules26082392 contributor: fullname: Pica – ident: 10.1016/j.micromeso.2024.113138_bib31 doi: 10.1007/978-3-319-93728-1_24 – volume: 153 start-page: 165e176 year: 1995 ident: 10.1016/j.micromeso.2024.113138_bib34 article-title: Titania-silica mixed oxides: I. Influence of sol-gel and drying conditions on structural properties publication-title: J. Catal. doi: 10.1006/jcat.1995.1118 contributor: fullname: Dutoit – volume: 8 start-page: 2350 issue: 2 year: 2019 ident: 10.1016/j.micromeso.2024.113138_bib57 article-title: Comparison on the TiO2 crystalline phases deposited via dip and spin coating using green sol–gel route publication-title: J. Mater. Res. Technol. doi: 10.1016/j.jmrt.2019.04.018 contributor: fullname: Dalilah Johari – volume: 29 start-page: 89 year: 2012 ident: 10.1016/j.micromeso.2024.113138_bib62 article-title: Technical and commercial progress in the adoption of geopolymer cement publication-title: Miner. Eng. doi: 10.1016/j.mineng.2011.09.009 contributor: fullname: VanDeventer – volume: 43 start-page: 5881 year: 2017 ident: 10.1016/j.micromeso.2024.113138_bib22 article-title: Photocatalyic activity of double pore structure TiO2/SiO2 monoliths publication-title: Ceram. Int. doi: 10.1016/j.ceramint.2017.01.061 contributor: fullname: Chang – volume: 17 start-page: 967 year: 2006 ident: 10.1016/j.micromeso.2024.113138_bib1 publication-title: J. Mater. Sci. Mater. Med. doi: 10.1007/s10856-006-0432-z contributor: fullname: Hench – volume: 116 start-page: 11128 year: 2016 ident: 10.1016/j.micromeso.2024.113138_bib68 article-title: Small angle X-ray scattering for nanoparticle research publication-title: Chem. Rev. doi: 10.1021/acs.chemrev.5b00690 contributor: fullname: Li – volume: 30 start-page: 657 year: 2010 ident: 10.1016/j.micromeso.2024.113138_bib65 article-title: Synthesis and in vitro bioactivity of mesoporous bioactive glass scaffolds publication-title: Mater. Sci. Eng. C doi: 10.1016/j.msec.2010.02.006 contributor: fullname: Shih – volume: 45 start-page: 21051 year: 2019 ident: 10.1016/j.micromeso.2024.113138_bib16 article-title: Current advances in bone tissue engineering concerning ceramic and bioglass scaffolds: a review publication-title: Ceram. Int. doi: 10.1016/j.ceramint.2019.07.096 contributor: fullname: Ribas – volume: 1 year: 2021 ident: 10.1016/j.micromeso.2024.113138_bib26 article-title: A review of phosphate and borate sol–gel glasses for biomedical applications publication-title: Adv. NanoBiomed Res. doi: 10.1002/anbr.202000055 contributor: fullname: Lepry – volume: 4 start-page: 67 year: 1997 ident: 10.1016/j.micromeso.2024.113138_bib37 article-title: Pore structure control of silica gels based on phase separation publication-title: J. Porous Mater. doi: 10.1023/A:1009627216939 contributor: fullname: Nakanishi – volume: 15 start-page: 1292 issue: 4 year: 2022 ident: 10.1016/j.micromeso.2024.113138_bib9 article-title: Properties and applications of metal phosphates and pyrophosphates as Proton conductors publication-title: Materials doi: 10.3390/ma15041292 contributor: fullname: Colodrero – volume: 27 start-page: 964 issue: 7 year: 2006 ident: 10.1016/j.micromeso.2024.113138_bib41 article-title: Optimising bioactive glass scaffolds for bone tissue engineering publication-title: Biomaterials doi: 10.1016/j.biomaterials.2005.07.017 contributor: fullname: Jones – volume: 23 start-page: 1849 year: 2012 ident: 10.1016/j.micromeso.2024.113138_bib48 article-title: Sol–gel derived 45S5 bioglass: synthesis, microstructural evolution and thermal behaviour publication-title: J. Mater. Sci. Mater. Med. doi: 10.1007/s10856-012-4667-6 contributor: fullname: Cacciotti – volume: 25 start-page: 491 year: 2004 ident: 10.1016/j.micromeso.2024.113138_bib54 article-title: Phosphate glasses for tissue engineering: Part 1. Processing and characterisation of a ternary-based P2O5–CaO–Na2O glass system publication-title: Biomaterials doi: 10.1016/S0142-9612(03)00546-5 contributor: fullname: Ahmed – year: 2018 ident: 10.1016/j.micromeso.2024.113138_bib2 article-title: Sol-gel formation of bulk glasses contributor: fullname: Sakka – volume: 90 start-page: 33 issue: 1 year: 1990 ident: 10.1016/j.micromeso.2024.113138_bib70 article-title: The sol-gel process publication-title: Chem. Rev. doi: 10.1021/cr00099a003 contributor: fullname: Hench – volume: 43 start-page: 5881 year: 2017 ident: 10.1016/j.micromeso.2024.113138_bib36 article-title: Photocatalyic activity of double pore structure TiO2/SiO2 monoliths publication-title: Ceram. Int. doi: 10.1016/j.ceramint.2017.01.061 contributor: fullname: Changa – volume: 77 start-page: 1 year: 2016 ident: 10.1016/j.micromeso.2024.113138_bib7 article-title: Sol–gel based materials for biomedical applications publication-title: Prog. Mater. Sci. doi: 10.1016/j.pmatsci.2015.12.001 contributor: fullname: Owens – year: 2018 ident: 10.1016/j.micromeso.2024.113138_bib32 article-title: Sol-gel formation of bulk glasses contributor: fullname: Sakka – volume: 7 start-page: 5083 year: 2011 ident: 10.1016/j.micromeso.2024.113138_bib50 article-title: Softening bioactive glass for bone regeneration: sol–gel hybrid materials publication-title: Soft Matter doi: 10.1039/c0sm01348j contributor: fullname: Valliant – volume: 8 start-page: 4181 year: 2012 ident: 10.1016/j.micromeso.2024.113138_bib29 article-title: Titanium phosphate glass microspheres for bone tissue engineering publication-title: Acta Biomat doi: 10.1016/j.actbio.2012.07.023 contributor: fullname: Lakhkar – volume: 86 issue: 1 year: 2014 ident: 10.1016/j.micromeso.2024.113138_bib43 article-title: Sol-gel as methodology to obtain bioactive materials publication-title: An. Acad. Bras. Cienc. doi: 10.1590/0001-37652014106012 contributor: fullname: Ribeiro – volume: 5 year: 2015 ident: 10.1016/j.micromeso.2024.113138_bib18 article-title: Toward smart implant synthesis: bonding bioceramics of different resorbability to match bone growth rates publication-title: Sci. Rep. doi: 10.1038/srep10677 contributor: fullname: Comesaña – volume: 61 start-page: 384 issue: 5 year: 2022 ident: 10.1016/j.micromeso.2024.113138_bib59 article-title: 3D multiphasic porous scaffolds of calcium phosphates doping with silicon and magnesium publication-title: Bol. Soc. Espanola Ceram. Vidr. doi: 10.1016/j.bsecv.2021.03.004 contributor: fullname: Mata – volume: 4 start-page: 523 year: 2008 ident: 10.1016/j.micromeso.2024.113138_bib53 article-title: Effect of increasing titanium dioxide content on bulk and surface properties of phosphate-based glasses publication-title: Acta Biomat doi: 10.1016/j.actbio.2007.11.007 contributor: fullname: Neel – volume: 41 start-page: 6159 year: 2006 ident: 10.1016/j.micromeso.2024.113138_bib69 article-title: Application of electro-spray ionization mass spectrometry for characterization of titanium polyoxoalkoxides in sol-gel processes publication-title: J. Mater. Sci. doi: 10.1007/s10853-006-0160-2 contributor: fullname: Soloviev – volume: 37 start-page: 14243 issue: 49 year: 2021 ident: 10.1016/j.micromeso.2024.113138_bib28 article-title: Titanium-containing silicate-based sol–gel bioactive glass: development, characterization, and applications publication-title: Langmuir doi: 10.1021/acs.langmuir.1c01593 contributor: fullname: Smith – year: 2018 ident: 10.1016/j.micromeso.2024.113138_bib47 article-title: Thermal analysis on gels, glasses, and powders contributor: fullname: Zaharescu |
| SSID | ssj0017121 |
| Score | 2.4748054 |
| Snippet | Despite of several decades lasting extensive research of bioactive and bioresorbable glasses the systematic parametrization and determination of the key... |
| SourceID | crossref elsevier |
| SourceType | Aggregation Database Publisher |
| StartPage | 113138 |
| Title | Sol-gel derived silicate-phosphate glass SiO2–P2O5–CaO–TiO2: The effect of titanium isopropoxide on porosity and thermomechanical stability |
| URI | https://dx.doi.org/10.1016/j.micromeso.2024.113138 |
| Volume | 374 |
| hasFullText | 1 |
| inHoldings | 1 |
| isFullTextHit | |
| isPrint | |
| link | http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwpV3PS8MwFA5jXvQg_sT5ixy81pkmTbPdZChD1IlT8FbaJHWVrS1uE72I_4L4H_qX-F7byQTBg5c2DQ20eS8vX9rvyyPkQFgVudKPHSNk6Agb4Ycm23J4xCUzsRurGP_oXlzK7q04u_PuaqQz08IgrbKK_WVML6J1VdOserOZJ0mzzziAfQV4QRTJknFPUAGTEfj04es3zYP5rNJewWDCu39wvEYF6c2OUQXoCsxvwlCo8tsMNTfrnK6Q5Qou0uPyiVZJzaZrZGluE8F18t7Phs69HVIDFU_W0HFSCtucfJCN8wGUaIGRaT_puZ9vH1duz4NTJ-zB8Qbq2hSchZbMDprFFHVnaTId0WSc5ZhF4TkxlmYpBayOHK8XGqaGInIcwWuhdBgtTQFnFkzblw1ye3py0-k6VaIFRzNfThzlKcDYImYqFBaGvKcFN0ZpWD1pnwkrtct9wEY-V8pY3yodQzGUNmSekjrmm6SeZqndIhSCVuS1OAJRLgB6Rlq3YAWoXA7QypdhgxzNOjfIy_00ghnR7CH4tkeA9ghKezRIe2aE4IdrBBD1_2q8_Z_GO2QRr5AZxrxdUp88Tu0eYJBJtF842T5ZOO5cn199ARcx4A0 |
| link.rule.ids | 315,786,790,4521 |
| linkProvider | Elsevier |
| openUrl | ctx_ver=Z39.88-2004&ctx_enc=info%3Aofi%2Fenc%3AUTF-8&rfr_id=info%3Asid%2Fsummon.serialssolutions.com&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=article&rft.atitle=Sol-gel+derived+silicate-phosphate+glass+SiO2%E2%80%93P2O5%E2%80%93CaO%E2%80%93TiO2%3A+The+effect+of+titanium+isopropoxide+on+porosity+and+thermomechanical+stability&rft.jtitle=Microporous+and+mesoporous+materials&rft.au=Kov%C3%A1%C5%99%C3%ADk%2C+Tom%C3%A1%C5%A1&rft.au=B%C4%9Blsk%C3%BD%2C+Petr&rft.au=K%C5%99enek%2C+Tom%C3%A1%C5%A1&rft.au=Deshmukh%2C+Kalim&rft.date=2024-06-15&rft.pub=Elsevier+Inc&rft.issn=1387-1811&rft.eissn=1873-3093&rft.volume=374&rft_id=info:doi/10.1016%2Fj.micromeso.2024.113138&rft.externalDocID=S1387181124001604 |
| thumbnail_l | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/lc.gif&issn=1387-1811&client=summon |
| thumbnail_m | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/mc.gif&issn=1387-1811&client=summon |
| thumbnail_s | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/sc.gif&issn=1387-1811&client=summon |