Evaluation of electrical conductivity of Fe-doped forsterite ceramics synthetized by sol–gel method
This work aims to investigate the effect of sintering temperature and iron doping on the electrical conductivity of forsterite in the temperature range of 300–400 °C. For this purpose, olivine compositions (Mg 2- x Fe x SiO 4 ; x = 0, 0.05 and 0.1) were synthetized by sol-gel process and then chara...
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| Published in | European physical journal. Applied physics Vol. 97; p. 61 |
|---|---|
| Main Authors | , , , , , , , |
| Format | Journal Article |
| Language | English |
| Published |
21.09.2022
|
| Online Access | Get full text |
| ISSN | 1286-0042 1286-0050 |
| DOI | 10.1051/epjap/2022220035 |
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| Abstract | This work aims to investigate the effect of sintering temperature and iron doping on the electrical conductivity of forsterite in the temperature range of 300–400 °C. For this purpose, olivine compositions (Mg
2-
x
Fe
x
SiO
4
;
x
= 0, 0.05 and 0.1) were synthetized by sol-gel process and then characterized by different techniques. The obtained results indicate the successful formation of dense single phase olivine ceramics. It was also found that Fe inserted in forsterite lattice has both Fe (II) and Fe (III) oxidation states. Regarding the electrical conductivity, it turned out to be more sensitive to both investigation parameters, in contrast with the activation energy characterizing the diffusion of carriers charge responsible of electrical conductivity. The prepared samples were characterized by: XRD, SEM techniques and Raman, Mössbauer and impedance spectroscopies. |
|---|---|
| AbstractList | This work aims to investigate the effect of sintering temperature and iron doping on the electrical conductivity of forsterite in the temperature range of 300–400 °C. For this purpose, olivine compositions (Mg
2-
x
Fe
x
SiO
4
;
x
= 0, 0.05 and 0.1) were synthetized by sol-gel process and then characterized by different techniques. The obtained results indicate the successful formation of dense single phase olivine ceramics. It was also found that Fe inserted in forsterite lattice has both Fe (II) and Fe (III) oxidation states. Regarding the electrical conductivity, it turned out to be more sensitive to both investigation parameters, in contrast with the activation energy characterizing the diffusion of carriers charge responsible of electrical conductivity. The prepared samples were characterized by: XRD, SEM techniques and Raman, Mössbauer and impedance spectroscopies. |
| Author | El Idrissi Raghni, Moulay Ahmed Ahamdane, Hamid Mansori, Mohammed El Asri, Saloua El Hadri, Mohammed Sajieddine, Mohammed Ounacer, Mohamed Hajji, Lahoucine |
| Author_xml | – sequence: 1 givenname: Saloua surname: El Asri fullname: El Asri, Saloua – sequence: 2 givenname: Mohammed surname: El Hadri fullname: El Hadri, Mohammed – sequence: 3 givenname: Hamid surname: Ahamdane fullname: Ahamdane, Hamid – sequence: 4 givenname: Lahoucine surname: Hajji fullname: Hajji, Lahoucine – sequence: 5 givenname: Mohamed surname: Ounacer fullname: Ounacer, Mohamed – sequence: 6 givenname: Mohammed surname: Sajieddine fullname: Sajieddine, Mohammed – sequence: 7 givenname: Moulay Ahmed surname: El Idrissi Raghni fullname: El Idrissi Raghni, Moulay Ahmed – sequence: 8 givenname: Mohammed surname: Mansori fullname: Mansori, Mohammed |
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