Ion-association vis á vis hydrophobic effect in novel ionic liquids-tetraalkylphosphonium/polyisobutylenesuccinimide-tethered tetraalkylammonium diarylphosphates/thiophosphates: Synthesis and application

• Published in: Journal of molecular liquids Vol. 296; p. 112084
• Main Authors: Mondal, Sujit, Mandal, Tanmay, Sharma, Meeta, Kumar, Ravindra, Arora, Ajay K., Christopher, J., Kapur, Gurpreet S.
• Format: Journal Article
• Language: English
• Published: Elsevier B.V 15.12.2019
• Subjects: Hydrophobic effect; Ion association; Ionic liquid; NMR; Phosphonium phosphate/thiophosphate; PIBSI-ammonium phosphate/thiophosphate; Hydrophobic effect; NMR; Phosphonium phosphate/thiophosphate; PIBSI-ammonium phosphate/thiophosphate; Ionic liquid; Ion association

A comprehensive study using conventional 1H, 31P NMR as well as advanced PFGSE-DOSY NMR on structurally unique ionic liquids (ILs) having, in one hand, both phosphorus based counter ions called tetraalkylphosphonium diarylphosphate (PP)/diarylthiophosphate (PTP), and on the other hand polyisobutylen...