Crystal Structures and Proton Conductivities of a MOF and Two POM–MOF Composites Based on Cu II Ions and 2,2′‐Bipyridyl‐3,3′‐dicarboxylic Acid

• Published in: Chemistry : a European journal Vol. 19; no. 5; pp. 1607 - 1616
• Main Authors: Wei, Meilin, Wang, Xiaoxiang, Duan, Xianying
• Format: Journal Article
• Language: English
• Published: 28.01.2013

We have succeeded in constructing a metal–organic framework (MOF), [Cu(bpdc)(H 2 O) 2 ] n (H 2 bpdc=2,2′‐bipyridyl‐3,3′‐dicarboxylic acid, 1 ), and two poly‐POM–MOFs (POM=polyoxometalate), {H[Cu(Hbpdc)(H 2 O) 2 ] 2 [PM 12 O 40 ] ⋅ n  H 2 O} n (M=Mo for 2 , W for 3 ), by the controllable self‐assembl...