Solid State Characterization of One- and Two-Electron Oxidized Cu-II-salen Complexes with para-Substituents: Geometric Structure-Magnetic Property Relationship

• Published in: European journal of inorganic chemistry Vol. 2021; no. 39; pp. 4133 - 4145
• Main Authors: Takeyama, Tomoyuki, Suzuki, Takashi, Kikuchi, Misa, Kobayashi, Misato, Oshita, Hiromi, Kawashima, Kyohei, Mori, Seiji, Abe, Hitoshi, Hoshino, Norihisa, Iwatsuki, Satoshi, Shimazaki, Yuichi
• Format: Journal Article
• Language: English
• Published: WEINHEIM Wiley 21.10.2021
• Subjects: Chemistry; Chemistry, Inorganic & Nuclear; Physical Sciences; Science & Technology; Magnetic property; RADICAL STABILITY; TRANSITION-METAL-COMPLEXES; ACTIVE-SITE; PHASE-TRANSITIONS; CRYSTAL-STRUCTURE; Stacking interactions; Phenoxyl radical; GALACTOSE-OXIDASE; COPPER(II) COMPLEXES; EFFECTIVE EXCHANGE INTEGRALS; Oxidation; BASIS-SETS; Copper; ELECTRONIC-STRUCTURE

One- and two-electron oxidized Cu-II complexes of Schiff base ligands with para-substituted phenolate moieties were synthesized and characterized. The crystal structure of the one-electron oxidized methylthio-substituted complex [Cu(MeS-salen)]SbCl6 revealed the intermolecular pi-pi stacking interac...