Co3O4 confined in activated carbon-supported Mg/Al-LDH for µM peroxymonosulfate activation with minute-level antibiotics degradation
•5Co3O4@LDH-AC was innovatively designed by confining Co3O4 in activated carbon supported Mg/Al-LDH.•5Co3O4@LDH-AC exhibited ultra-fast degradation efficiency of levofloxacin within 4 min.•Ultra-fast degradation of levofloxacin achieved through µM addition of peroxymonosulfate.•5Co3O4@LDH-AC + PMS s...
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| Published in | Chemical engineering journal (Lausanne, Switzerland : 1996) Vol. 516; p. 163872 |
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| Main Authors | , , , , , , |
| Format | Journal Article |
| Language | English |
| Published |
Elsevier B.V
15.07.2025
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| Subjects | |
| Online Access | Get full text |
| ISSN | 1385-8947 |
| DOI | 10.1016/j.cej.2025.163872 |
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| Abstract | •5Co3O4@LDH-AC was innovatively designed by confining Co3O4 in activated carbon supported Mg/Al-LDH.•5Co3O4@LDH-AC exhibited ultra-fast degradation efficiency of levofloxacin within 4 min.•Ultra-fast degradation of levofloxacin achieved through µM addition of peroxymonosulfate.•5Co3O4@LDH-AC + PMS system shown excellent stability in treating real wastewater from hospital effluent.
Herein, an efficient and stable catalyst of Co3O4@LDH-AC was innovatively prepared through uniform loading of an activated carbon substrate with Mg/Al layered double hydroxide (Mg/Al-LDH) followed by dispersing Co3O4 nanoparticles in the confined space of LDH. This unique flower-like spherical structure significantly improved the adsorption capacity and would increase the concentration of reactants in the confined space. Experimental results showed that levofloxacin (LFX) completely degraded in 4 min with the addition of µM peroxymonosulfate (PMS). The fast conversion of Co2+ and Co3+ in catalyst for the generation of highly reactive species is revealed via EPR, in-situ Raman, in-situ FT-IR, and XPS. Further tests of 5Co3O4@LDH-AC in effluent of hospital wastewater treatment showed that it not only possessed strong anti-interference capabilities, but also maintained stable catalytic activity in fixed-bed reactor for a long operation time. Therefore, the excellent catalytic performance in confined space offers the possibility of application for the degradation of micropollutants in real pharmaceutical wastewater discharged from hospital (800–1200 tons/day, COD > 150 mg/L). |
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| AbstractList | •5Co3O4@LDH-AC was innovatively designed by confining Co3O4 in activated carbon supported Mg/Al-LDH.•5Co3O4@LDH-AC exhibited ultra-fast degradation efficiency of levofloxacin within 4 min.•Ultra-fast degradation of levofloxacin achieved through µM addition of peroxymonosulfate.•5Co3O4@LDH-AC + PMS system shown excellent stability in treating real wastewater from hospital effluent.
Herein, an efficient and stable catalyst of Co3O4@LDH-AC was innovatively prepared through uniform loading of an activated carbon substrate with Mg/Al layered double hydroxide (Mg/Al-LDH) followed by dispersing Co3O4 nanoparticles in the confined space of LDH. This unique flower-like spherical structure significantly improved the adsorption capacity and would increase the concentration of reactants in the confined space. Experimental results showed that levofloxacin (LFX) completely degraded in 4 min with the addition of µM peroxymonosulfate (PMS). The fast conversion of Co2+ and Co3+ in catalyst for the generation of highly reactive species is revealed via EPR, in-situ Raman, in-situ FT-IR, and XPS. Further tests of 5Co3O4@LDH-AC in effluent of hospital wastewater treatment showed that it not only possessed strong anti-interference capabilities, but also maintained stable catalytic activity in fixed-bed reactor for a long operation time. Therefore, the excellent catalytic performance in confined space offers the possibility of application for the degradation of micropollutants in real pharmaceutical wastewater discharged from hospital (800–1200 tons/day, COD > 150 mg/L). |
| ArticleNumber | 163872 |
| Author | Lam, Jason Chun-Ho Li, Tao Zhang, Jian Chen, Hongbin Sun, Weikun Qiu, Zumin Liu, Shengqin |
| Author_xml | – sequence: 1 givenname: Tao surname: Li fullname: Li, Tao organization: School of Chemistry and Chemical Engineering, Nanchang University, No. 999 Xuefu Avenue, Nanchang 330031, China – sequence: 2 givenname: Weikun surname: Sun fullname: Sun, Weikun organization: School of Chemistry and Chemical Engineering, Nanchang University, No. 999 Xuefu Avenue, Nanchang 330031, China – sequence: 3 givenname: Jian surname: Zhang fullname: Zhang, Jian email: zhangjian@iue.ac.cn organization: School of Chemistry and Chemical Engineering, Nanchang University, No. 999 Xuefu Avenue, Nanchang 330031, China – sequence: 4 givenname: Shengqin surname: Liu fullname: Liu, Shengqin organization: School of Energy and Environment, City University of Hong Kong, Kowloon Tong, Hong Kong SAR 999077, China – sequence: 5 givenname: Hongbin surname: Chen fullname: Chen, Hongbin organization: School of Chemistry and Chemical Engineering, Nanchang University, No. 999 Xuefu Avenue, Nanchang 330031, China – sequence: 6 givenname: Zumin surname: Qiu fullname: Qiu, Zumin email: mzqiu@ncu.edu.cn organization: School of Chemistry and Chemical Engineering, Nanchang University, No. 999 Xuefu Avenue, Nanchang 330031, China – sequence: 7 givenname: Jason Chun-Ho surname: Lam fullname: Lam, Jason Chun-Ho organization: School of Energy and Environment, City University of Hong Kong, Kowloon Tong, Hong Kong SAR 999077, China |
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| Keywords | Ultra-fast antibiotics degradation Flower-like Mg/Al-LDH Hospital wastewater treatment Confined catalysis µM peroxymonosulfate |
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| SubjectTerms | Confined catalysis Flower-like Mg/Al-LDH Hospital wastewater treatment Ultra-fast antibiotics degradation µM peroxymonosulfate |
| Title | Co3O4 confined in activated carbon-supported Mg/Al-LDH for µM peroxymonosulfate activation with minute-level antibiotics degradation |
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