Nickel(0)‐Catalyzed Hydroalkenylation of Imines with Styrene and Its Derivatives

• Published in: Angewandte Chemie Vol. 130; no. 13; pp. 3454 - 3458
• Main Authors: Xiao, Li‐Jun, Zhao, Chao‐Yue, Cheng, Lei, Feng, Bo‐Ya, Feng, Wei‐Min, Xie, Jian‐Hua, Xu, Xiu‐Fang, Zhou, Qi‐Lin
• Format: Journal Article
• Language: English; German
• Published: Weinheim Wiley Subscription Services, Inc 19.03.2018
• Subjects: Aliphatic compounds; Alkene; Alkenes; Allylverbindungen; Amines; Chemistry; Derivatives; Imine; Imines; Mathematical analysis; Nickel; Reagents; Reaktionsmechanismen; Styrene

A nickel(0)‐catalyzed hydroalkenylation of imines with styrene and its derivatives is described. A wide range of aromatic and aliphatic imines directly coupled with styrene and its derivatives, thus providing various synthetically useful allylic amines with up to 95 % yield. The reaction offers a ne...