Electrocatalytic Activity of a 2D Phosphorene‐Based Heteroelectrocatalyst for Photoelectrochemical Cells

Research into efficient synthesis, fundamental properties, and potential applications of phosphorene is currently the subject of intense investigation. Herein, solution‐processed phosphorene or few‐layer black phosphorus (FL‐BP) sheets are prepared using a microwave exfoliation method and used in ph...

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Published inAngewandte Chemie Vol. 130; no. 10; pp. 2674 - 2677
Main Authors Batmunkh, Munkhbayar, Shrestha, Aabhash, Bat‐Erdene, Munkhjargal, Nine, Md Julker, Shearer, Cameron J., Gibson, Christopher T., Slattery, Ashley D., Tawfik, Sherif Abdulkader, Ford, Michael J., Dai, Sheng, Qiao, Shizhang, Shapter, Joseph G.
Format Journal Article
LanguageEnglish
Published Weinheim Wiley Subscription Services, Inc 01.03.2018
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Abstract Research into efficient synthesis, fundamental properties, and potential applications of phosphorene is currently the subject of intense investigation. Herein, solution‐processed phosphorene or few‐layer black phosphorus (FL‐BP) sheets are prepared using a microwave exfoliation method and used in photoelectrochemical cells. Based on experimental and theoretical (DFT) studies, the FL‐BP sheets are found to act as catalytically active sites and show excellent electrocatalytic activity for triiodide reduction in dye‐sensitized solar cells. Importantly, the device fabricated based on the newly designed cobalt sulfide (CoSx) decorated nitrogen and sulfur co‐doped carbon nanotube heteroelectrocatalyst coated with FL‐BP (FL‐BP@N,S‐doped CNTs‐CoSx) displayed an impressive photovoltaic efficiency of 8.31 %, outperforming expensive platinum based cells. This work paves the way for using phosphorene‐based electrocatalysts for next‐generation energy‐storage systems. Phosphoren‐Blätter wurden durch mikrowellenunterstütztes Abblättern in flüssiger Phase hergestellt, und die elektrokatalytischen Eigenschaften der Produkte wurden experimentell und theoretisch untersucht. Solarzellen mit einem Phosphoren‐Heteroelektrokatalysator lieferten bessere Resultate als teure Einheiten auf Platinbasis.
AbstractList Research into efficient synthesis, fundamental properties, and potential applications of phosphorene is currently the subject of intense investigation. Herein, solution‐processed phosphorene or few‐layer black phosphorus (FL‐BP) sheets are prepared using a microwave exfoliation method and used in photoelectrochemical cells. Based on experimental and theoretical (DFT) studies, the FL‐BP sheets are found to act as catalytically active sites and show excellent electrocatalytic activity for triiodide reduction in dye‐sensitized solar cells. Importantly, the device fabricated based on the newly designed cobalt sulfide (CoSx) decorated nitrogen and sulfur co‐doped carbon nanotube heteroelectrocatalyst coated with FL‐BP (FL‐BP@N,S‐doped CNTs‐CoSx) displayed an impressive photovoltaic efficiency of 8.31 %, outperforming expensive platinum based cells. This work paves the way for using phosphorene‐based electrocatalysts for next‐generation energy‐storage systems. Phosphoren‐Blätter wurden durch mikrowellenunterstütztes Abblättern in flüssiger Phase hergestellt, und die elektrokatalytischen Eigenschaften der Produkte wurden experimentell und theoretisch untersucht. Solarzellen mit einem Phosphoren‐Heteroelektrokatalysator lieferten bessere Resultate als teure Einheiten auf Platinbasis.
Research into efficient synthesis, fundamental properties, and potential applications of phosphorene is currently the subject of intense investigation. Herein, solution‐processed phosphorene or few‐layer black phosphorus (FL‐BP) sheets are prepared using a microwave exfoliation method and used in photoelectrochemical cells. Based on experimental and theoretical (DFT) studies, the FL‐BP sheets are found to act as catalytically active sites and show excellent electrocatalytic activity for triiodide reduction in dye‐sensitized solar cells. Importantly, the device fabricated based on the newly designed cobalt sulfide (CoSx) decorated nitrogen and sulfur co‐doped carbon nanotube heteroelectrocatalyst coated with FL‐BP (FL‐BP@N,S‐doped CNTs‐CoSx) displayed an impressive photovoltaic efficiency of 8.31 %, outperforming expensive platinum based cells. This work paves the way for using phosphorene‐based electrocatalysts for next‐generation energy‐storage systems.
Research into efficient synthesis, fundamental properties, and potential applications of phosphorene is currently the subject of intense investigation. Herein, solution‐processed phosphorene or few‐layer black phosphorus (FL‐BP) sheets are prepared using a microwave exfoliation method and used in photoelectrochemical cells. Based on experimental and theoretical (DFT) studies, the FL‐BP sheets are found to act as catalytically active sites and show excellent electrocatalytic activity for triiodide reduction in dye‐sensitized solar cells. Importantly, the device fabricated based on the newly designed cobalt sulfide (CoS x ) decorated nitrogen and sulfur co‐doped carbon nanotube heteroelectrocatalyst coated with FL‐BP (FL‐BP@N,S‐doped CNTs‐CoS x ) displayed an impressive photovoltaic efficiency of 8.31 %, outperforming expensive platinum based cells. This work paves the way for using phosphorene‐based electrocatalysts for next‐generation energy‐storage systems.
Author Shrestha, Aabhash
Slattery, Ashley D.
Shapter, Joseph G.
Dai, Sheng
Batmunkh, Munkhbayar
Nine, Md Julker
Tawfik, Sherif Abdulkader
Shearer, Cameron J.
Bat‐Erdene, Munkhjargal
Qiao, Shizhang
Ford, Michael J.
Gibson, Christopher T.
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Snippet Research into efficient synthesis, fundamental properties, and potential applications of phosphorene is currently the subject of intense investigation. Herein,...
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SubjectTerms Carbon nanotubes
Chemistry
Cobalt
Dye-sensitized solar cells
Electrocatalysts
Elektrokatalyse
Energy storage
Nanotubes
Nitrogen
Phosphorene
Phosphorus
Photochemie
Photoelectrochemical devices
Photovoltaic cells
Photovoltaics
Platinum
Schwarzer Phosphor
Sheets
Solar cells
Solarzellen
Storage systems
Sulfides
Sulfur
Zweidimensionale Materialien
Title Electrocatalytic Activity of a 2D Phosphorene‐Based Heteroelectrocatalyst for Photoelectrochemical Cells
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