ChemInform Abstract: Synthesis of Novel Aryl and Heteroaryl Acyl Sulfonimidamides via Pd-Catalyzed Carbonylation Using a Nongaseous Precursor

This novel methodology, employing sulfonimidamides as nucleophiles and CO gas released in situ from solid Mo(CO)6 in a sealed two‐chamber system, shows high functional group tolerance affording a wide range of carbamate protected sulfonimidamides in good to excellent yields.

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Bibliographic Details
Published inChemInform Vol. 44; no. 32; p. no
Main Authors Borhade, Sanjay R., Sandstroem, Anja, Arvidsson, Per I.
Format Journal Article
LanguageEnglish
Published Weinheim WILEY-VCH Verlag 06.08.2013
WILEY‐VCH Verlag
Wiley Subscription Services, Inc
Subjects
carbonylation
carboxylic amides (benzene compounds)
catalysis
catalysis, phase‐transfer catalysis
phase-transfer catalysis
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Summary:This novel methodology, employing sulfonimidamides as nucleophiles and CO gas released in situ from solid Mo(CO)6 in a sealed two‐chamber system, shows high functional group tolerance affording a wide range of carbamate protected sulfonimidamides in good to excellent yields.
Bibliography:ark:/67375/WNG-11L6TRQQ-G
ArticleID:CHIN201332077
istex:346E79C3DF5006B48C37024B6EA368C30C15BCCB
ISSN:0931-7597
1522-2667
DOI:10.1002/chin.201332077