Visualizing the Atomic Structure Between YSZ and LSM: An Interface Stabilized by Complexions?

The YSZ/LSM electrolyte/electrode interface of a half cell is investigated using electron microscopic and theoretical techniques. It is found that, due to strong interdiffusion of all cations except for Sr across the phase boundary, a so-called complexion is formed on the YSZ-side of the interface....

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Published inECS transactions Vol. 103; no. 1; pp. 1331 - 1337
Main Authors Götsch, Thomas, Tuerk, Hanna, Schmidt, Franz-Philipp, Vinke, I. C., De Haart, L. G. J. (Bert), Schlögl, Robert, Reuter, Karsten, Eichel, Rüdiger-A., Knop-Gericke, Axel, Scheurer, Christoph, Lunkenbein, Thomas
Format Journal Article
LanguageEnglish
Published 09.07.2021
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Abstract The YSZ/LSM electrolyte/electrode interface of a half cell is investigated using electron microscopic and theoretical techniques. It is found that, due to strong interdiffusion of all cations except for Sr across the phase boundary, a so-called complexion is formed on the YSZ-side of the interface. This complexion is thermodynamically stabilized by the neighboring bulk phases and its consequences on activity and stability of SOCs are further discussed.
AbstractList The YSZ/LSM electrolyte/electrode interface of a half cell is investigated using electron microscopic and theoretical techniques. It is found that, due to strong interdiffusion of all cations except for Sr across the phase boundary, a so-called complexion is formed on the YSZ-side of the interface. This complexion is thermodynamically stabilized by the neighboring bulk phases and its consequences on activity and stability of SOCs are further discussed.
Author Götsch, Thomas
Scheurer, Christoph
Reuter, Karsten
Tuerk, Hanna
Eichel, Rüdiger-A.
Schmidt, Franz-Philipp
Schlögl, Robert
Knop-Gericke, Axel
Lunkenbein, Thomas
Vinke, I. C.
De Haart, L. G. J. (Bert)
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