Visualizing the Atomic Structure Between YSZ and LSM: An Interface Stabilized by Complexions?
The YSZ/LSM electrolyte/electrode interface of a half cell is investigated using electron microscopic and theoretical techniques. It is found that, due to strong interdiffusion of all cations except for Sr across the phase boundary, a so-called complexion is formed on the YSZ-side of the interface....
Saved in:
Published in | ECS transactions Vol. 103; no. 1; pp. 1331 - 1337 |
---|---|
Main Authors | , , , , , , , , , , |
Format | Journal Article |
Language | English |
Published |
09.07.2021
|
Online Access | Get full text |
Cover
Loading…
Abstract | The YSZ/LSM electrolyte/electrode interface of a half cell is investigated using electron microscopic and theoretical techniques. It is found that, due to strong interdiffusion of all cations except for Sr across the phase boundary, a so-called complexion is formed on the YSZ-side of the interface. This complexion is thermodynamically stabilized by the neighboring bulk phases and its consequences on activity and stability of SOCs are further discussed. |
---|---|
AbstractList | The YSZ/LSM electrolyte/electrode interface of a half cell is investigated using electron microscopic and theoretical techniques. It is found that, due to strong interdiffusion of all cations except for Sr across the phase boundary, a so-called complexion is formed on the YSZ-side of the interface. This complexion is thermodynamically stabilized by the neighboring bulk phases and its consequences on activity and stability of SOCs are further discussed. |
Author | Götsch, Thomas Scheurer, Christoph Reuter, Karsten Tuerk, Hanna Eichel, Rüdiger-A. Schmidt, Franz-Philipp Schlögl, Robert Knop-Gericke, Axel Lunkenbein, Thomas Vinke, I. C. De Haart, L. G. J. (Bert) |
Author_xml | – sequence: 1 givenname: Thomas surname: Götsch fullname: Götsch, Thomas – sequence: 2 givenname: Hanna surname: Tuerk fullname: Tuerk, Hanna – sequence: 3 givenname: Franz-Philipp surname: Schmidt fullname: Schmidt, Franz-Philipp – sequence: 4 givenname: I. C. orcidid: 0000-0002-1361-9983 surname: Vinke fullname: Vinke, I. C. – sequence: 5 givenname: L. G. J. (Bert) orcidid: 0000-0001-6908-1214 surname: De Haart fullname: De Haart, L. G. J. (Bert) – sequence: 6 givenname: Robert surname: Schlögl fullname: Schlögl, Robert – sequence: 7 givenname: Karsten surname: Reuter fullname: Reuter, Karsten – sequence: 8 givenname: Rüdiger-A. orcidid: 0000-0002-0013-6325 surname: Eichel fullname: Eichel, Rüdiger-A. – sequence: 9 givenname: Axel surname: Knop-Gericke fullname: Knop-Gericke, Axel – sequence: 10 givenname: Christoph surname: Scheurer fullname: Scheurer, Christoph – sequence: 11 givenname: Thomas surname: Lunkenbein fullname: Lunkenbein, Thomas |
BookMark | eNo1kEFLwzAcxYNMcJtePecLtCZN26ReZBang4mHqqAgJU3_0ciajiRF56e36jy9x-O9d_jN0MT2FhA6pSSmNC3OKGGExpQxCsqHAzSlBRNRzhmf7H0m8uQIzbx_JyQfN3yKXh6NH-TGfBn7isMb4EXoO6NwFdygwuAAX0L4ALD4qXrG0rZ4Xd2e44XFKxvAaalg7MrGjBfQ4maHy77bbuDT9NZfHKNDLTceTvY6Rw_Lq_vyJlrfXa_KxTpSNEtDpHMBOslkobTUOZGCc8l5yknKM51RIFIXiieiHQPCE54R0YqUCU0KlUOTsDmK_36V6713oOutM510u5qS-gdO_Qun_ofDvgH0sVm0 |
CitedBy_id | crossref_primary_10_1002_cctc_202200300 crossref_primary_10_1177_09576509231176623 |
ContentType | Journal Article |
DBID | AAYXX CITATION |
DOI | 10.1149/10301.1331ecst |
DatabaseName | CrossRef |
DatabaseTitle | CrossRef |
DatabaseTitleList | CrossRef |
DeliveryMethod | fulltext_linktorsrc |
Discipline | Chemistry |
EISSN | 1938-6737 |
EndPage | 1337 |
ExternalDocumentID | 10_1149_10301_1331ecst |
GroupedDBID | 0R~ 29G AATNI AAYXX ABDNZ ABJNI ACHIP ADNWM AKPSB ALMA_UNASSIGNED_HOLDINGS AOAED ATQHT CITATION CJUJL EBS EJD IOP JGOPE KOT MV1 N5L NFQFE REC RHI RNS ROL RPA |
ID | FETCH-LOGICAL-c154t-f68ef25a9cfaf60a877a77470475f51e0af9c728d0470727508d8438f09c6eb23 |
ISSN | 1938-5862 |
IngestDate | Fri Aug 23 03:41:53 EDT 2024 |
IsPeerReviewed | false |
IsScholarly | true |
Issue | 1 |
Language | English |
LinkModel | OpenURL |
MergedId | FETCHMERGED-LOGICAL-c154t-f68ef25a9cfaf60a877a77470475f51e0af9c728d0470727508d8438f09c6eb23 |
ORCID | 0000-0002-1361-9983 0000-0002-0013-6325 0000-0001-6908-1214 |
PageCount | 7 |
ParticipantIDs | crossref_primary_10_1149_10301_1331ecst |
PublicationCentury | 2000 |
PublicationDate | 2021-07-09 |
PublicationDateYYYYMMDD | 2021-07-09 |
PublicationDate_xml | – month: 07 year: 2021 text: 2021-07-09 day: 09 |
PublicationDecade | 2020 |
PublicationTitle | ECS transactions |
PublicationYear | 2021 |
SSID | ssj0061147 |
Score | 2.3069487 |
Snippet | The YSZ/LSM electrolyte/electrode interface of a half cell is investigated using electron microscopic and theoretical techniques. It is found that, due to... |
SourceID | crossref |
SourceType | Aggregation Database |
StartPage | 1331 |
Title | Visualizing the Atomic Structure Between YSZ and LSM: An Interface Stabilized by Complexions? |
Volume | 103 |
hasFullText | 1 |
inHoldings | 1 |
isFullTextHit | |
isPrint | |
link | http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwnV1LT9tAEF6l9EAvVSmg0pf2UIkDcnD82EcvKES0oYIWKYCgUhWt17uCQ10kzKH5Gf3FzHi9zobmQHuxkrXXiT2fZmdnvpkh5INMC5ZiaHCgRBFlgomo0NJGYDxr7HXLVILJycdf2fgs-3KRX_R6fwLW0l1d9PVsaV7J_0gVxkCumCX7D5LtbgoD8BnkC0eQMBwfJePz61vMiZz5lKdhjTnGGGm-c5GB_ZaFdTn53kQJjibHoSfQKqzDWTdFdmfOFEX9gDUy4S8_5PyNJthQwncX72zxzxhr32f1rWsqFTCOGtqGcVzssaqqbgWY6Kuf12XtDedZ5Nw6N_78OWyQG0frYX9n1A8dE8mgIbHKQJfKFJO6WmVr5mPYGmdBAcfpX0hz6nTg07mM_8qXq_1MNh4I0FZ9nGN0G5pbqK_9YN3r2IguN1tOm_lTP_8JeZpwmSNN9PDbiV_dGVzJHVPBPVxbCBTm7y7-fmDoBBbL6QvyvN1q0KHDzRrpmeolWR35Dn_r5EeAHwr4oQ4_tMMPbfFDAT8U8EMBPx_psKIdeugcPbT4TQP07G2Qs08Hp6Nx1LbbiDTY0XVkmTA2yZXUVlkWK8G5gs0BjzOe23xgYmWl5okoYSDm2BdAlCJLhY2lZqZI0k2yUv2qzCtCC8UsRni5VCyTWqnUlJlMbSIzzlnJtsi2fzfTG1dVZbpcCq8ffeUb8myOwrdkBV6VeQcGY128byR4D-OIZ7I |
link.rule.ids | 315,786,790,27955,27956 |
linkProvider | IOP Publishing |
openUrl | ctx_ver=Z39.88-2004&ctx_enc=info%3Aofi%2Fenc%3AUTF-8&rfr_id=info%3Asid%2Fsummon.serialssolutions.com&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=article&rft.atitle=Visualizing+the+Atomic+Structure+Between+YSZ+and+LSM%3A+An+Interface+Stabilized+by+Complexions%3F&rft.jtitle=ECS+transactions&rft.au=G%C3%B6tsch%2C+Thomas&rft.au=Tuerk%2C+Hanna&rft.au=Schmidt%2C+Franz-Philipp&rft.au=Vinke%2C+I.+C.&rft.date=2021-07-09&rft.issn=1938-5862&rft.eissn=1938-6737&rft.volume=103&rft.issue=1&rft.spage=1331&rft.epage=1337&rft_id=info:doi/10.1149%2F10301.1331ecst&rft.externalDBID=n%2Fa&rft.externalDocID=10_1149_10301_1331ecst |
thumbnail_l | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/lc.gif&issn=1938-5862&client=summon |
thumbnail_m | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/mc.gif&issn=1938-5862&client=summon |
thumbnail_s | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/sc.gif&issn=1938-5862&client=summon |