Conglomerate crystallization behavior of racemic [Co(N4)(aminoacidato)] 2+ complexes

• Published in: Crystal engineering Vol. 4; no. 2; pp. 141 - 157
• Main Authors: Hu, Xiaopeng, Cai, Jiwen, Chen, Caihong, Chen, Xiao-Ming, Liang-Nian Ji
• Format: Journal Article
• Language: English
• Published: Elsevier Ltd 01.06.2001
• Subjects: Amino acid; Cobalt(iii); Conglomerate crystallization; Triethylenetetramine; Tris(2-aminoethyl)amine; Cobalt(iii); Amino acid; Tris(2-aminoethyl)amine; Conglomerate crystallization; Triethylenetetramine

Crystal structures, absolute configurations, and crystalline packing features of nine complexes, namely, cis- α-Λ-(RR)( δλδ)-[Co(trien)(D-histidinato)](ClO 4) 2·2H 2O 1, cis- β 1-Δ-(RR)( λδδ)- [Co(trien)(L-asparaginato)](ClO 4) 2 2, cis- β 2-Λ(SS)( λλδ)-[Co(trien)(L-valinato)](ClO 4) 2·H 2O 3, cis-...