Enhanced photoluminescence properties and energy transfer in a new Tb3+ and Ce3+ co-doped KBa2(PO3)5 green-emitting phosphor
A series of KBa2−x−y(PO3)5:xTb3+, yCe3+ phosphors have been synthesized by the conventional high temperature solid-state reaction method. The crystal structure, the morphology, and the luminescent properties were investigated by X-ray power diffraction (XRD), scanning electron microscopy (SEM) and p...
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| Published in | Optik (Stuttgart) Vol. 168; pp. 152 - 158 |
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| Main Authors | , , , , , |
| Format | Journal Article |
| Language | English |
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Elsevier GmbH
01.09.2018
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| Abstract | A series of KBa2−x−y(PO3)5:xTb3+, yCe3+ phosphors have been synthesized by the conventional high temperature solid-state reaction method. The crystal structure, the morphology, and the luminescent properties were investigated by X-ray power diffraction (XRD), scanning electron microscopy (SEM) and photoluminescence spectra (PL). In the Ce3+ and Tb3+ co-doped system, the efficient energy transfer mechanism has been demonstrated to be an electric dipole-dipole interaction. The experimental results show that the optimum Tb3+ and Ce3+ doping concentrations are 0.4 and 0.01, respectively. The new phosphor of KBa1.59(PO3)5:0.4Tb3+, 0.01Ce3+ shows remarkable CIE chromaticity coordinates, indicating that it has potential application as a green-emitting phosphor in white light-emitting diodes (W-LEDs). |
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| AbstractList | A series of KBa2−x−y(PO3)5:xTb3+, yCe3+ phosphors have been synthesized by the conventional high temperature solid-state reaction method. The crystal structure, the morphology, and the luminescent properties were investigated by X-ray power diffraction (XRD), scanning electron microscopy (SEM) and photoluminescence spectra (PL). In the Ce3+ and Tb3+ co-doped system, the efficient energy transfer mechanism has been demonstrated to be an electric dipole-dipole interaction. The experimental results show that the optimum Tb3+ and Ce3+ doping concentrations are 0.4 and 0.01, respectively. The new phosphor of KBa1.59(PO3)5:0.4Tb3+, 0.01Ce3+ shows remarkable CIE chromaticity coordinates, indicating that it has potential application as a green-emitting phosphor in white light-emitting diodes (W-LEDs). |
| Author | Duan, Meng-Yu Fan, Yun-Chang Zhao, Dan Nie, Cong-kui Zhang, Lei Zhao, Ji |
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| Title | Enhanced photoluminescence properties and energy transfer in a new Tb3+ and Ce3+ co-doped KBa2(PO3)5 green-emitting phosphor |
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