Discovery and Supramolecular Interactions of Neutral Palladium-Oxo Clusters Pd 16 and Pd 24

• Published in: Angewandte Chemie International Edition Vol. 60; no. 7; pp. 3632 - 3639
• Main Authors: Bhattacharya, Saurav, Basu, Uttara, Haouas, Mohamed, Su, Pei, Espenship, Michael Forrester, Wang, Fei, Solé-Daura, Albert, Taffa, Dereje H, Wark, Michael, Poblet, Josep M, Laskin, Julia, Cadot, Emmanuel, Kortz, Ulrich
• Format: Journal Article
• Language: English
• Published: Germany Wiley-VCH Verlag 15.02.2021
• Subjects: Chemical Sciences; inorganic chemistry; polyoxopalladium; organic-inorganic frameworks; neutral clusters; supramolecular chemistry

We report on the synthesis, structure, and physicochemical characterization of the first three examples of neutral palladium-oxo clusters (POCs). The 16-palladium(II)-oxo cluster [Pd O (OH) ((CH ) As) ] (Pd ) comprises a cyclic palladium-oxo unit capped by eight dimethylarsinate groups. The chloro-d...