Bis(2,2′‐bipyridine‐κ2N,N′)(carbonato‐κ2O,O′)cobalt(III) trifluoromethanesulfonate

In the title compound, [Co(CO3)(C10H8N2)2](CF3SO3), the CoIII ion is coordinated by four N atoms from two chelating 2,2′‐bipyridine ligands and two O atoms from a bidentate chelating carbonate anion, and has a distorted octahedral environment. C—H...O hydrogen bonding is observed between bipyridine...

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Bibliographic Details
Published inActa crystallographica. Section E, Structure reports online Vol. 63; no. 7; pp. m1906 - m1907
Main Authors Lv, Yang‐Xiao, Ling, Yun, Li, Huan, Zhang, Lei
Format Journal Article
LanguageEnglish
Published 5 Abbey Square, Chester, Cheshire CH1 2HU, England Blackwell Publishing Ltd 15.07.2007
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Summary:In the title compound, [Co(CO3)(C10H8N2)2](CF3SO3), the CoIII ion is coordinated by four N atoms from two chelating 2,2′‐bipyridine ligands and two O atoms from a bidentate chelating carbonate anion, and has a distorted octahedral environment. C—H...O hydrogen bonding is observed between bipyridine ligands and uncoordinated (CF3SO3)− anions and between bipyridine and carbonate ligands.
ISSN:1600-5368
1600-5368
DOI:10.1107/S1600536807028516