Tuning the Sharing Modes and Composition in a Tetrahedral GeX 2 (X = S, Se) System via One-Dimensional Confinement
The packing and connectivity of tetrahedral units are central themes in the structural and electronic properties of a host of solids. Here, we report one-dimensional (1D) chains of GeX (X = S or Se) with modification of the tetrahedral connectivity at the single-chain limit. Precise tuning of the ed...
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| Published in | ACS nano Vol. 17; no. 9; pp. 8734 - 8742 |
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| Main Authors | , , , , , , , |
| Format | Journal Article |
| Language | English |
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United States
American Chemical Society
09.05.2023
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| Abstract | The packing and connectivity of tetrahedral units are central themes in the structural and electronic properties of a host of solids. Here, we report one-dimensional (1D) chains of GeX
(X = S or Se) with modification of the tetrahedral connectivity at the single-chain limit. Precise tuning of the edge- and corner-sharing modes between GeX
blocks is achieved by diameter-dependent 1D confinement inside a carbon nanotube. Atomic-resolution scanning transmission electron microscopy directly confirms the existence of two distinct types of GeX
chains. Density functional theory calculations corroborate the diameter-dependent stability of the system and reveal an intriguing electronic structure that sensitively depends on tetrahedral connectivity and composition. GeS
Se
compound chains are also realized, which demonstrate the tunability of the system's semiconducting properties through composition engineering. |
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| AbstractList | The packing and connectivity of tetrahedral units are central themes in the structural and electronic properties of a host of solids. Here, we report one-dimensional (1D) chains of GeX
(X = S or Se) with modification of the tetrahedral connectivity at the single-chain limit. Precise tuning of the edge- and corner-sharing modes between GeX
blocks is achieved by diameter-dependent 1D confinement inside a carbon nanotube. Atomic-resolution scanning transmission electron microscopy directly confirms the existence of two distinct types of GeX
chains. Density functional theory calculations corroborate the diameter-dependent stability of the system and reveal an intriguing electronic structure that sensitively depends on tetrahedral connectivity and composition. GeS
Se
compound chains are also realized, which demonstrate the tunability of the system's semiconducting properties through composition engineering. The packing and connectivity of tetrahedral units are central themes in the structural and electronic properties of a host of solids. Here, we report one-dimensional (1D) chains of GeX2 (X = S or Se) with modification of the tetrahedral connectivity at the single-chain limit. Precise tuning of the edge- and corner-sharing modes between GeX2 blocks is achieved by diameter-dependent 1D confinement inside a carbon nanotube. Atomic-resolution scanning transmission electron microscopy directly confirms the existence of two distinct types of GeX2 chains. Density functional theory calculations corroborate the diameter-dependent stability of the system and reveal an intriguing electronic structure that sensitively depends on tetrahedral connectivity and composition. GeS2(1–x)Se2x compound chains are also realized, which demonstrate the tunability of the system’s semiconducting properties through composition engineering. |
| Author | Zettl, Alex Song, Chengyu Lee, Kihyun Lee, Yangjin Ercius, Peter Choi, Young Woo Cohen, Marvin L Kim, Kwanpyo |
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| Cites_doi | 10.1021/acs.nanolett.2c00213 10.1126/science.149.3683.535 10.1038/293611a0 10.1021/acs.nanolett.8b05074 10.1038/354445a0 10.1021/acs.inorgchem.9b02190 10.1021/jacs.0c10175 10.1201/9781420023848.ch2 10.1126/science.1242248 10.1021/ja01349a006 10.1038/nature08641 10.1021/acs.nanolett.9b04741 10.1021/acsnano.1c03705 10.1002/anie.201107097 10.1038/24521 10.1088/0953-8984/14/11/302 10.1038/nature08239 10.1002/jcc.20495 10.1103/PhysRevB.35.1345 10.1103/PhysRevB.71.174201 10.1021/acs.nanolett.9b00133 10.1103/PhysRevB.100.041403 10.1021/acs.nanolett.6b04031 10.1039/b200537a 10.1063/1.1749915 10.1103/PhysRevLett.100.115501 10.1103/PhysRevLett.77.3865 10.1103/PhysRevLett.124.206403 10.1021/acsnano.2c06359 10.1038/2121353a0 10.1126/science.289.5483.1324 10.1073/pnas.0601389103 10.1126/sciadv.aav3194 10.1038/2121354a0 10.1002/anie.201611740 10.1021/acs.nanolett.1c04615 10.1126/science.1082346 10.1126/science.aat4749 10.1038/s41928-020-0365-4 10.1038/nmat4069 10.1103/PhysRevB.65.104208 10.1016/j.jcrysgro.2015.12.005 |
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| Keywords | Germanium dichalcogenide Transmission electron microscopy One-dimensional materials Atomic chain Nanotubes |
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| References | ref9/cit9 ref45/cit45 ref6/cit6 ref36/cit36 ref3/cit3 ref27/cit27 ref18/cit18 ref11/cit11 ref25/cit25 ref16/cit16 ref29/cit29 Singh J. (ref4/cit4) 2003; 5 ref32/cit32 ref23/cit23 ref39/cit39 ref8/cit8 ref31/cit31 ref2/cit2 ref43/cit43 ref34/cit34 Miessler G. L. (ref14/cit14) 2013 ref37/cit37 Herman F. (ref5/cit5) 2013 ref28/cit28 ref40/cit40 ref20/cit20 ref17/cit17 ref10/cit10 ref26/cit26 ref35/cit35 ref19/cit19 ref21/cit21 ref12/cit12 ref15/cit15 ref42/cit42 ref41/cit41 ref22/cit22 ref13/cit13 ref33/cit33 ref30/cit30 ref1/cit1 ref24/cit24 ref38/cit38 ref44/cit44 ref7/cit7 |
| References_xml | – ident: ref41/cit41 doi: 10.1021/acs.nanolett.2c00213 – ident: ref8/cit8 doi: 10.1126/science.149.3683.535 – ident: ref9/cit9 doi: 10.1038/293611a0 – ident: ref32/cit32 doi: 10.1021/acs.nanolett.8b05074 – ident: ref12/cit12 doi: 10.1038/354445a0 – ident: ref25/cit25 doi: 10.1021/acs.inorgchem.9b02190 – ident: ref30/cit30 doi: 10.1021/jacs.0c10175 – volume: 5 start-page: 21 volume-title: Advances in Amorphous Semiconductors year: 2003 ident: ref4/cit4 doi: 10.1201/9781420023848.ch2 contributor: fullname: Singh J. – ident: ref19/cit19 doi: 10.1126/science.1242248 – ident: ref6/cit6 doi: 10.1021/ja01349a006 – ident: ref3/cit3 doi: 10.1038/nature08641 – ident: ref24/cit24 doi: 10.1021/acs.nanolett.9b04741 – ident: ref33/cit33 doi: 10.1021/acsnano.1c03705 – ident: ref20/cit20 doi: 10.1002/anie.201107097 – ident: ref21/cit21 doi: 10.1038/24521 – start-page: 469 volume-title: Tetrahedrally-Bonded Amorphous Semiconductors year: 2013 ident: ref5/cit5 contributor: fullname: Herman F. – ident: ref44/cit44 – ident: ref42/cit42 doi: 10.1088/0953-8984/14/11/302 – ident: ref2/cit2 doi: 10.1038/nature08239 – ident: ref45/cit45 doi: 10.1002/jcc.20495 – ident: ref13/cit13 doi: 10.1103/PhysRevB.35.1345 – ident: ref15/cit15 doi: 10.1103/PhysRevB.71.174201 – ident: ref40/cit40 doi: 10.1021/acs.nanolett.9b00133 – ident: ref28/cit28 doi: 10.1103/PhysRevB.100.041403 – ident: ref39/cit39 doi: 10.1021/acs.nanolett.6b04031 – ident: ref38/cit38 doi: 10.1039/b200537a – ident: ref7/cit7 doi: 10.1063/1.1749915 – ident: ref16/cit16 doi: 10.1103/PhysRevLett.100.115501 – ident: ref43/cit43 doi: 10.1103/PhysRevLett.77.3865 – ident: ref29/cit29 doi: 10.1103/PhysRevLett.124.206403 – ident: ref35/cit35 doi: 10.1021/acsnano.2c06359 – ident: ref10/cit10 doi: 10.1038/2121353a0 – start-page: 215 volume-title: Inorganic Chemistry year: 2013 ident: ref14/cit14 contributor: fullname: Miessler G. L. – ident: ref26/cit26 doi: 10.1126/science.289.5483.1324 – ident: ref1/cit1 doi: 10.1073/pnas.0601389103 – ident: ref17/cit17 doi: 10.1126/sciadv.aav3194 – ident: ref11/cit11 doi: 10.1038/2121354a0 – ident: ref23/cit23 doi: 10.1002/anie.201611740 – ident: ref36/cit36 doi: 10.1021/acs.nanolett.1c04615 – ident: ref22/cit22 doi: 10.1126/science.1082346 – ident: ref27/cit27 doi: 10.1126/science.aat4749 – ident: ref34/cit34 doi: 10.1038/s41928-020-0365-4 – ident: ref31/cit31 doi: 10.1038/nmat4069 – ident: ref18/cit18 doi: 10.1103/PhysRevB.65.104208 – ident: ref37/cit37 doi: 10.1016/j.jcrysgro.2015.12.005 |
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| Title | Tuning the Sharing Modes and Composition in a Tetrahedral GeX 2 (X = S, Se) System via One-Dimensional Confinement |
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