Intermolecular relaxation in glycerol as revealed by field cycling 1H NMR relaxometry dilution experiments

• Published in: The Journal of chemical physics Vol. 136; no. 3; p. 034508
• Main Authors: Meier, R, Kruk, D, Gmeiner, J, Rössler, E A
• Format: Journal Article
• Language: English
• Published: United States 21.01.2012
• Subjects: Diffusion; Glycerol - chemistry; Magnetic Resonance Spectroscopy; Protons; Rotation

(1)H spin-lattice relaxation rates R(1) = 1/T(1) have been measured for partly deuterated glycerol-h(5) diluted in fully deuterated glycerol-h(0) for progressively lower concentrations of glycerol-h(5). By means of the field cycling (FC) technique relaxation dispersion data, R(1)(ω), have been colle...