ChemInform Abstract: One-Pot Synthesis of Functionalized β-Amino Sulfides/β-Amino Selenides via Ring Opening of Cyclic Sulfamidates

• Published in: ChemInform Vol. 46; no. 11; p. no
• Main Authors: Venkateswarlu, Cheerladinne, Datta, Bandita, Chandrasekaran, Srinivasan
• Format: Journal Article
• Language: English
• Published: Weinheim WILEY-VCH Verlag 01.03.2015; WILEY‐VCH Verlag
• Subjects: mercaptans; mercaptans, thioethers (acyclic compounds); mercaptans, thioethers (benzene compounds); organo-selenium compounds; ring opening reactions; thioethers (acyclic compounds); thioethers (benzene compounds)

In—situ formed thiolate ions from rongalite react in a highly stereospecific manner at the C—O bond yielding enantiopure products in good to excellent yields.