Commercial Cu 2 Cr 2 O 5 Decorated with Iron Carbide Nanoparticles as a Multifunctional Catalyst for Magnetically Induced Continuous‐Flow Hydrogenation of Aromatic Ketones
Abstract Copper chromite is decorated with iron carbide nanoparticles, producing a magnetically activatable multifunctional catalytic system. This system (ICNPs@Cu 2 Cr 2 O 5 ) can reduce aromatic ketones to aromatic alcohols when exposed to magnetic induction. Under magnetic excitation, the ICNPs g...
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| Published in | Angewandte Chemie Vol. 133; no. 51; pp. 26843 - 26850 |
|---|---|
| Main Authors | , , , , , , , , , |
| Format | Journal Article |
| Language | English |
| Published |
13.12.2021
|
| Online Access | Get full text |
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| Abstract | Abstract
Copper chromite is decorated with iron carbide nanoparticles, producing a magnetically activatable multifunctional catalytic system. This system (ICNPs@Cu
2
Cr
2
O
5
) can reduce aromatic ketones to aromatic alcohols when exposed to magnetic induction. Under magnetic excitation, the ICNPs generate locally confined hot spots, selectively activating the Cu
2
Cr
2
O
5
surface while the global temperature remains low (≈80 °C). The catalyst selectively hydrogenates a scope of benzylic and non‐benzylic ketones under mild conditions (3 bar H
2
, heptane), while ICNPs@Cu
2
Cr
2
O
5
or Cu
2
Cr
2
O
5
are inactive when the same global temperature is adjusted by conventional heating. A flow reactor is presented that allows the use of magnetic induction for continuous‐flow hydrogenation at elevated pressure. The excellent catalytic properties of ICNPs@Cu
2
Cr
2
O
5
for the hydrogenation of biomass‐derived furfuralacetone are conserved for at least 17 h on stream, demonstrating for the first time the application of a magnetically heated catalyst to a continuously operated hydrogenation reaction in the liquid phase. |
|---|---|
| AbstractList | Abstract
Copper chromite is decorated with iron carbide nanoparticles, producing a magnetically activatable multifunctional catalytic system. This system (ICNPs@Cu
2
Cr
2
O
5
) can reduce aromatic ketones to aromatic alcohols when exposed to magnetic induction. Under magnetic excitation, the ICNPs generate locally confined hot spots, selectively activating the Cu
2
Cr
2
O
5
surface while the global temperature remains low (≈80 °C). The catalyst selectively hydrogenates a scope of benzylic and non‐benzylic ketones under mild conditions (3 bar H
2
, heptane), while ICNPs@Cu
2
Cr
2
O
5
or Cu
2
Cr
2
O
5
are inactive when the same global temperature is adjusted by conventional heating. A flow reactor is presented that allows the use of magnetic induction for continuous‐flow hydrogenation at elevated pressure. The excellent catalytic properties of ICNPs@Cu
2
Cr
2
O
5
for the hydrogenation of biomass‐derived furfuralacetone are conserved for at least 17 h on stream, demonstrating for the first time the application of a magnetically heated catalyst to a continuously operated hydrogenation reaction in the liquid phase. |
| Author | Kreissl, Hannah Vorholt, Andreas J. Levin, Natalia Jin, Jing Schüette, Dirk Chaudret, Bruno Bordet, Alexis Störtte, Sven Leitner, Walter Lin, Sheng‐Hsiang |
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Copper chromite is decorated with iron carbide nanoparticles, producing a magnetically activatable multifunctional catalytic system. This system... |
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