New Synthetic Method of MgF2 Hollow Nanoparticles by Fluorination of Raw Material Particle Surfaces —Toward Low-temperature Mass Synthesis
We conducted research aimed at developing a novel method for synthesis of MgF2 hollow nanoparticles that is simpler than the conventional synthetic method. First, Mg(OH)2 raw material nanoparticles were contact with hydrofluoric acid vapor in a gas-solid reactor at 473 K. As a result, the surfaces o...
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| Published in | Funtai Kogakkaishi Vol. 61; no. 2; pp. 91 - 97 |
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| Main Authors | , , , , , , |
| Format | Journal Article |
| Language | English Japanese |
| Published |
Kyoto
The Society of Powder Technology, Japan
10.02.2024
Japan Science and Technology Agency |
| Subjects | |
| Online Access | Get full text |
| ISSN | 0386-6157 1883-7239 |
| DOI | 10.4164/sptj.61.91 |
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| Abstract | We conducted research aimed at developing a novel method for synthesis of MgF2 hollow nanoparticles that is simpler than the conventional synthetic method. First, Mg(OH)2 raw material nanoparticles were contact with hydrofluoric acid vapor in a gas-solid reactor at 473 K. As a result, the surfaces of the Mg(OH)2 nanoparticles were fluorinated to obtain Mg(OH)2-MgF2 core-shell particles. Next, the MgF2 hollow nanoparticles were synthesized by soaking the core-shell particles in 1.0 mol/L hydrochloric acid to dissolve only the Mg(OH)2 core portion. We have succeeded in developing a method for synthesizing MgF2 hollow nanoparticles with different MgF2 shell thicknesses by controlling the surface fluorination reaction period of Mg(OH)2 raw material nanoparticles. |
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| AbstractList | We conducted research aimed at developing a novel method for synthesis of MgF2 hollow nanoparticles that is simpler than the conventional synthetic method. First, Mg(OH)2 raw material nanoparticles were contact with hydrofluoric acid vapor in a gas-solid reactor at 473 K. As a result, the surfaces of the Mg(OH)2 nanoparticles were fluorinated to obtain Mg(OH)2-MgF2 core-shell particles. Next, the MgF2 hollow nanoparticles were synthesized by soaking the core-shell particles in 1.0 mol/L hydrochloric acid to dissolve only the Mg(OH)2 core portion. We have succeeded in developing a method for synthesizing MgF2 hollow nanoparticles with different MgF2 shell thicknesses by controlling the surface fluorination reaction period of Mg(OH)2 raw material nanoparticles. We conducted research aimed at developing a novel method for synthesis of MgF2 hollow nanoparticles that is simpler than the conventional synthetic method. First, Mg(OH)2 raw material nanoparticles were contact with hydrofluoric acid vapor in a gas-solid reactor at 473 K. As a result, the surfaces of the Mg(OH)2 nanoparticles were fluorinated to obtain Mg(OH)2-MgF2 core-shell particles. Next, the MgF2 hollow nanoparticles were synthesized by soaking the core-shell particles in 1.0 mol/L hydrochloric acid to dissolve only the Mg(OH)2 core portion. We have succeeded in developing a method for synthesizing MgF2 hollow nanoparticles with different MgF2 shell thicknesses by controlling the surface fluorination reaction period of Mg(OH)2 raw material nanoparticles. |
| ArticleNumber | 61.91 |
| Author | Hattori, Shinichi Omoto, Shin Okada, Yoshiki Sato, Keisuke Kinoshita, Takuya Tsuji, Ryusuke Yonezawa, Tetsuo |
| Author_xml | – sequence: 1 fullname: Hattori, Shinichi organization: Development Department, Morita Chemical Industries Co., Ltd – sequence: 1 fullname: Tsuji, Ryusuke organization: Department of Chemical, Energy and Environmental Engineering, Faculty of Environmental and Urban Engineering, Graduate School of Science and Engineering, Kansai University – sequence: 1 fullname: Sato, Keisuke organization: Development Department, Morita Chemical Industries Co., Ltd – sequence: 1 fullname: Okada, Yoshiki organization: Department of Chemical, Energy and Environmental Engineering, Faculty of Environmental and Urban Engineering, Graduate School of Science and Engineering, Kansai University – sequence: 1 fullname: Yonezawa, Tetsuo organization: Development Department, Morita Chemical Industries Co., Ltd – sequence: 1 fullname: Kinoshita, Takuya organization: Department of Chemical, Energy and Environmental Engineering, Faculty of Environmental and Urban Engineering, Graduate School of Science and Engineering, Kansai University – sequence: 1 fullname: Omoto, Shin organization: Department of Chemical, Energy and Environmental Engineering, Faculty of Environmental and Urban Engineering, Graduate School of Science and Engineering, Kansai University |
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| Cites_doi | 10.4164/sptj.31.176 10.1021/acs.langmuir.7b00737 10.1007/s10971-004-5782-8 10.1016/j.solmat.2017.12.010 10.4139/sfj1970.32.421 10.1252/kakoronbunshu.44.85 10.1021/am500139m 10.1016/j.solmat.2020.110680 |
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| References | [8] N. Chundi, B. Das, C. S. R. Kolli, S. P. Madiwala, S. Koppoju, E. Ramasamy, S. Shanmugasundaram, Single layer hollow MgF2 nanoparticles as high-performance omnidirectional broadband antireflective coating for solar application, Sol. Energy Mater. Sol. Cells 215 (2020) 110680–10690. [9] J. Aida, S. Mitachi, T. Yamada, O. Abe, Synthesis and crystallization of La1-xSrxMnO3+δ from mechanochemically prepared precursors, J. Soc. Powder Technol., Japan 47 (2010) 158–165. [1] H. Nagayama, Antireflection films, J. Surf. Finish. Soc. Japan 32 (1985) 421–426. [10] Y. Shimamura, T. Iwasaki, M. Iwata, S. Watano, Analysis of the reaction process in the formation of lanthanum nickel oxide via a mechanochemical route, Kagaku Kogaku Ronbunshu 44 (2018) 85–90. [12] K. Hashimoto, Hannou Kogaku, Baifuukan (1979) p. 224. [2] T. Murata, H. Ishizawa, I. Motoyama, A. Tanaka, Investigations of MgF2 optical thin films prepared autoclaved sol, J. Sol-Gel Sci. Technol. 32 (2004) 161–165. [3] M. Fuji, N. Tanaka, Q. Wen, C. Takai-Yamashita, K. Fujimoto, T. Hotta, M. Ishihara, I. Nakayama, Status and prospects of research on hollow particles, Annu. Rep. Adv. Ceram. Res. Cent. Nagoya Inst. of Technol. 9 (2020) 16–28. [4] Japanese Unexamined Patent Application No. JP2012-76967, 2012-04-19. [5] A. B. D. Nandiyanto, T. Ogi, K. Okuyama, Control of the shell structural properties and cavity diameter hollow magnesium fluoride particles, ACS Appl. Mater. Interfaces 6 (2014) 4418–4427. [7] K. C. S. Reddy, D. Karthik, D. Bhanupriya, K. Ganesh, M. Ramakrishna, S. Sakthirel, Broad band antireflective coating using novel in-situ synthesis of hollow MgF2 nanoparticles, Sol. Energy Mater. Sol. Cells 176 (2018) 259–265. [11] O. Abe, Y. Suzuki, Synthesis and study of the properties of barium titanate powder by the mechanochemical process, J. Soc. Powder Technol., Japan 31 (1993) 176–181. [6] L. Bao, Z. Ji, H. Wang, R. Chen, Hollow rodlike MgF2 with an ultralow refractive index for the preparation of multifunctional antireflective coatings, Langmuir 33 (2017) 6240–6247. 11 1 12 2 3 4 5 6 7 8 9 10 |
| References_xml | – reference: [1] H. Nagayama, Antireflection films, J. Surf. Finish. Soc. Japan 32 (1985) 421–426. – reference: [2] T. Murata, H. Ishizawa, I. Motoyama, A. Tanaka, Investigations of MgF2 optical thin films prepared autoclaved sol, J. Sol-Gel Sci. Technol. 32 (2004) 161–165. – reference: [11] O. Abe, Y. Suzuki, Synthesis and study of the properties of barium titanate powder by the mechanochemical process, J. Soc. Powder Technol., Japan 31 (1993) 176–181. – reference: [12] K. Hashimoto, Hannou Kogaku, Baifuukan (1979) p. 224. – reference: [8] N. Chundi, B. Das, C. S. R. Kolli, S. P. Madiwala, S. Koppoju, E. Ramasamy, S. Shanmugasundaram, Single layer hollow MgF2 nanoparticles as high-performance omnidirectional broadband antireflective coating for solar application, Sol. Energy Mater. Sol. Cells 215 (2020) 110680–10690. – reference: [4] Japanese Unexamined Patent Application No. JP2012-76967, 2012-04-19. – reference: [7] K. C. S. Reddy, D. Karthik, D. Bhanupriya, K. Ganesh, M. Ramakrishna, S. Sakthirel, Broad band antireflective coating using novel in-situ synthesis of hollow MgF2 nanoparticles, Sol. Energy Mater. Sol. Cells 176 (2018) 259–265. – reference: [6] L. Bao, Z. Ji, H. Wang, R. Chen, Hollow rodlike MgF2 with an ultralow refractive index for the preparation of multifunctional antireflective coatings, Langmuir 33 (2017) 6240–6247. – reference: [9] J. Aida, S. Mitachi, T. Yamada, O. Abe, Synthesis and crystallization of La1-xSrxMnO3+δ from mechanochemically prepared precursors, J. Soc. Powder Technol., Japan 47 (2010) 158–165. – reference: [3] M. Fuji, N. Tanaka, Q. Wen, C. Takai-Yamashita, K. Fujimoto, T. Hotta, M. Ishihara, I. Nakayama, Status and prospects of research on hollow particles, Annu. Rep. Adv. Ceram. Res. Cent. Nagoya Inst. of Technol. 9 (2020) 16–28. – reference: [5] A. B. D. Nandiyanto, T. Ogi, K. Okuyama, Control of the shell structural properties and cavity diameter hollow magnesium fluoride particles, ACS Appl. Mater. Interfaces 6 (2014) 4418–4427. – reference: [10] Y. Shimamura, T. Iwasaki, M. Iwata, S. Watano, Analysis of the reaction process in the formation of lanthanum nickel oxide via a mechanochemical route, Kagaku Kogaku Ronbunshu 44 (2018) 85–90. – ident: 3 – ident: 11 doi: 10.4164/sptj.31.176 – ident: 6 doi: 10.1021/acs.langmuir.7b00737 – ident: 2 doi: 10.1007/s10971-004-5782-8 – ident: 4 – ident: 7 doi: 10.1016/j.solmat.2017.12.010 – ident: 1 doi: 10.4139/sfj1970.32.421 – ident: 12 – ident: 9 – ident: 10 doi: 10.1252/kakoronbunshu.44.85 – ident: 5 doi: 10.1021/am500139m – ident: 8 doi: 10.1016/j.solmat.2020.110680 |
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| SubjectTerms | Core-shell particles Fluorination Gas-solid reactor Hydrochloric acid Hydrochloric acid dissolution Hydrofluoric acid Low temperature Magnesium fluorides Mg(OH)2 nanoparticles MgF2 hollow nanoparticles Nanoparticles Raw materials Surface fluorination reaction Synthesis |
| Title | New Synthetic Method of MgF2 Hollow Nanoparticles by Fluorination of Raw Material Particle Surfaces —Toward Low-temperature Mass Synthesis |
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