Ein neuartiger Zugang zu Fulvenkomplexen des Titans - diastereoselektive Komplexierung von Pentafulvenen an Cyclopentadienyltitan-Fragmente
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Published in | Angewandte Chemie Vol. 113; no. 11; pp. 2112 - 2115 |
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Main Authors | , , , , , , |
Format | Journal Article |
Language | German |
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Weinheim
WILEY-VCH Verlag GmbH
01.06.2001
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Author | Haase, Detlev Becke, Sigurd Stroot, Jörg Saak, Wolfgang Heinrichs, Jürgen Lützen, Arne Beckhaus, Rüdiger |
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Cites_doi | 10.1016/0022-328X(91)83283-A 10.1016/0022-328X(94)87203-1 10.1021/om00072a015 10.1039/dt9850002037 10.1021/om970288+ 10.1039/b007854i 10.1021/ja00705a006 10.1039/a827323z 10.1021/om981048c 10.1021/om960007i 10.1021/om980123g 10.1016/S0022-328X(96)06746-0 10.1021/ja991046z 10.1002/(SICI)1521-3765(20000103)6:1<81::AID-CHEM81>3.0.CO;2-9 10.1515/znb-1989-1222 10.1021/ar9900109 10.1021/om970066b 10.1021/om980702l 10.1039/a900173e 10.1021/ja00035a030 10.1016/0022-2852(72)90051-3 10.1021/cr00078a002 10.1021/ja970140h 10.1021/jo00185a001 |
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Mach , V. Varga , V. Hanus , P. Sedmera , J. Organomet. Chem. 1991, 415, 87-95 G. Erker , U. Korek , Z. Naturforsch. B 1989, 44, 1593-1598. P.-M. Pellny , F. G. Kirchbauer , V. V. Burlakov , W. Baumann , A. Spannenberg , U. Rosenthal , J. Am. Chem. Soc. 1999, 121, 8313-8323 Das Fulvendianion (Fv) wurde erstmals in Form von Li2Fv isoliert: T. Matsuo , A. Sekiguchi , M. Ichinohe , K. Ebata , H. Sakurai , Organometallics 1998, 17, 3143-3145. J. M. Fischer , W. E. Piers , V. G. Young, Jr. , Organometallics 1996, 15, 2410-2412. J. M. O'Connor , C. P. Casey , Chem. Rev. 1987, 87, 307-318 C. McDade , J. C. Green , J. E. Bercaw , Organometallics 1982, 1, 1629-1634 M. J. Veiros , L. F. Calhorda , Coord. Chem. Rev. 1999, 186, 37-51. Y.-X. Chen , T. J. Marks , Organometallics 1997, 16, 3649-3657 J. J. Eisch , F. A. Owuor , X. Shi , Organometallics 1999, 18, 1583-1585 Ziegler Catalysts-Recent Scientific Innovations and Technological Improvements (Hrsg.: G. Fink, R. Mülhaupt, H. Brintzinger), Springer, Berlin, 1995 R. Beckhaus , J. Sang , J. Oster , T. Wagner , J. Organomet. Chem. 1994, 484, 179-190 K. J. Stone , R. D. Little , J. Org. Chem. 1984, 49, 1849-1853. Y. Sun , R. E. v. H. Spence , W. E. Piers , M. Parvez , G. P. A. Yap , J. Am. Chem. Soc. 1997, 119, 5132-5143. C5H4=CMe2: J. F. Chaing , S. H. Bauer , J. Am. Chem. Soc. 1970, 92, 261-265. Fulvenkomplexe wurden bereits ausgehend von Titan(0)-aren-Derivaten hergestellt ( J. A. Bandy , V. S. B. Mtetwa , K. Prout , J. C. Green , C. E. Davies , M. L. H. Green , N. J. Hazel , A. Izquierdo , J. J. Martin-Polo , J. Chem. Soc. Dalton Trans. 1985, 2037-2049); zur reduktiven Dimerisierung von Fulvenen zu Ansametallocenen siehe Lit. [4e]. G. A. Luinstra , J. H. Teuben , J. Am. Chem. Soc. 1992, 114, 3361-3367 P.-M. Pellny , F. G. Kirchbauer , V. V. Burlakov , W. Baumann , A. Spannenberg , U. Rosenthal , Chem. Eur. J. 2000, 6, 81-90 H. Lee , J. B. Bonanno , T. Hascall , J. Cordaro , J. M. Hahan , G. Parkin , J. 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References_xml | – volume-title: Metallocenes year: 1998 ident: 10.1002/1521-3757(20010601)113:11<2112::AID-ANGE2112>3.0.CO;2-L-BIB1 – volume-title: Metallocene-based Polyolefins—Preparation, Properties and Technology year: 2000 ident: 10.1002/1521-3757(20010601)113:11<2112::AID-ANGE2112>3.0.CO;2-L-BIB2B – volume: 415 start-page: 87 year: 1991 ident: 10.1002/1521-3757(20010601)113:11<2112::AID-ANGE2112>3.0.CO;2-L-BIB3E publication-title: J. Organomet. Chem. doi: 10.1016/0022-328X(91)83283-A contributor: fullname: Mach – volume: 484 start-page: 179 year: 1994 ident: 10.1002/1521-3757(20010601)113:11<2112::AID-ANGE2112>3.0.CO;2-L-BIB3C publication-title: J. Organomet. 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StartPage | 2112 |
SubjectTerms | Fulvenkomplexe Insertionen pi-Wechselwirkungen Titan |
Title | Ein neuartiger Zugang zu Fulvenkomplexen des Titans - diastereoselektive Komplexierung von Pentafulvenen an Cyclopentadienyltitan-Fragmente |
URI | https://api.istex.fr/ark:/67375/WNG-X9301QLQ-G/fulltext.pdf |
Volume | 113 |
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