Additive-free red phosphorus/Ti 3 C 2 T x MXene nanocomposite anodes for metal–ion batteries

Herein, we report on scalable, environmentally benign, and additive-free, high-performance anodes for alkali–metal–ion batteries (MIBs, where M = Li + , Na + , K + ). The intercalators in these anodes are the red phosphorus (RP) nanoparticles of uniform size (∼40 nm), which are dispersible and blend...

Full description

Saved in:
Bibliographic Details
Published inEnergy advances Vol. 1; no. 12; pp. 999 - 1008
Main Authors Subramaniyam, Chandrasekar M, Kang, Min-A, Li, Jian, VahidMohammadi, Armin, Hamedi, Mahiar Max
Format Journal Article
LanguageEnglish
Published 08.12.2022
Online AccessGet full text

Cover

Abstract Herein, we report on scalable, environmentally benign, and additive-free, high-performance anodes for alkali–metal–ion batteries (MIBs, where M = Li + , Na + , K + ). The intercalators in these anodes are the red phosphorus (RP) nanoparticles of uniform size (∼40 nm), which are dispersible and blend with water-dispersed Ti 3 C 2 T x MXene, forming a highly viscous aqueous slurry to fabricate additive-free nanocomposite electrodes. We further enhanced their performance using a very low weight percentage of various carbonaceous nanomaterials. Our RP-MWCNT/MXene nanocomposite anodes exhibited enhanced ion transport and low charge transfer resistance, delivering specific capacities of 1293.7 mA h g −1 at 500 mA g −1 and 263.3 mA h g −1 at 2600 mA g −1 for 10 000 cycles in Li + cells, 371.6 mA h g −1 at 500 mA g −1 in Na + cells, and 732.8 mA h g −1 at 50 mA g −1 in K + cells. Our work shows a path towards fabricating nanoarchitectured electrodes using sustainable materials to eliminate inert polymer binders, toxic processing solvents, and rare earth elements from the battery fabrication process for next-generation alkali–metal–ion batteries.
AbstractList Herein, we report on scalable, environmentally benign, and additive-free, high-performance anodes for alkali-metal-ion batteries (MIBs, where M = Li+, Na+, K+). The intercalators in these anodes are the red phosphorus (RP) nanoparticles of uniform size (~40 nm), which are dispersible and blend with water-dispersed Ti3C2Tx MXene, forming a highly viscous aqueous slurry to fabricate additive-free nanocomposite electrodes. We further enhanced their performance using a very low weight percentage of various carbonaceous nanomaterials. Our RP-MWCNT/MXene nanocomposite anodes exhibited enhanced ion transport and low charge transfer resistance, delivering specific capacities of 1293.7 mA h g-1 at 500 mA g-1 and 263.3 mA h g-1 at 2600 mA g-1 for 10 000 cycles in Li+ cells, 371.6 mA h g-1 at 500 mA g-1 in Na+ cells, and 732.8 mA h g-1 at 50 mA g-1 in K+ cells. Our work shows a path towards fabricating nanoarchitectured electrodes using sustainable materials to eliminate inert polymer binders, toxic processing solvents, and rare earth elements from the battery fabrication process for next-generation alkali-metal-ion batteries.
Herein, we report on scalable, environmentally benign, and additive-free, high-performance anodes for alkali–metal–ion batteries (MIBs, where M = Li + , Na + , K + ). The intercalators in these anodes are the red phosphorus (RP) nanoparticles of uniform size (∼40 nm), which are dispersible and blend with water-dispersed Ti 3 C 2 T x MXene, forming a highly viscous aqueous slurry to fabricate additive-free nanocomposite electrodes. We further enhanced their performance using a very low weight percentage of various carbonaceous nanomaterials. Our RP-MWCNT/MXene nanocomposite anodes exhibited enhanced ion transport and low charge transfer resistance, delivering specific capacities of 1293.7 mA h g −1 at 500 mA g −1 and 263.3 mA h g −1 at 2600 mA g −1 for 10 000 cycles in Li + cells, 371.6 mA h g −1 at 500 mA g −1 in Na + cells, and 732.8 mA h g −1 at 50 mA g −1 in K + cells. Our work shows a path towards fabricating nanoarchitectured electrodes using sustainable materials to eliminate inert polymer binders, toxic processing solvents, and rare earth elements from the battery fabrication process for next-generation alkali–metal–ion batteries.
Author Subramaniyam, Chandrasekar M
VahidMohammadi, Armin
Kang, Min-A
Li, Jian
Hamedi, Mahiar Max
Author_xml – sequence: 1
  givenname: Chandrasekar M
  orcidid: 0000-0002-8909-8846
  surname: Subramaniyam
  fullname: Subramaniyam, Chandrasekar M
  organization: Department of Fibre and Polymer Technology, School of Engineering Sciences in Chemistry, Biotechnology and Health, KTH Royal Institute of Technology, 100 44 Stockholm, Sweden
– sequence: 2
  givenname: Min-A
  orcidid: 0000-0002-1661-3771
  surname: Kang
  fullname: Kang, Min-A
  organization: Department of Fibre and Polymer Technology, School of Engineering Sciences in Chemistry, Biotechnology and Health, KTH Royal Institute of Technology, 100 44 Stockholm, Sweden
– sequence: 3
  givenname: Jian
  surname: Li
  fullname: Li, Jian
  organization: Department of Fibre and Polymer Technology, School of Engineering Sciences in Chemistry, Biotechnology and Health, KTH Royal Institute of Technology, 100 44 Stockholm, Sweden
– sequence: 4
  givenname: Armin
  surname: VahidMohammadi
  fullname: VahidMohammadi, Armin
  organization: Department of Materials Science and Engineering, A.J. Drexel Nanomaterials Institute, Drexel University, Philadelphia, Pennsylvania, USA
– sequence: 5
  givenname: Mahiar Max
  orcidid: 0000-0001-9088-1064
  surname: Hamedi
  fullname: Hamedi, Mahiar Max
  organization: Department of Fibre and Polymer Technology, School of Engineering Sciences in Chemistry, Biotechnology and Health, KTH Royal Institute of Technology, 100 44 Stockholm, Sweden
BackLink https://urn.kb.se/resolve?urn=urn:nbn:se:kth:diva-330971$$DView record from Swedish Publication Index
BookMark eNpNUEtOwzAUtFCRKKUbTuA1UqifncTJMkr5SUVsCoINkR2_UEMbR3bKZ8cduCEnoagIWIxmRpqZxeyTQetaJOQQ2DEwkU-m_K5gDNKs3CFDLhMRQZzIwT-9R8YhPDLGuJQpkzAk94UxtrfPGDUekXo0tFu4sIFfh8ncUkFLyumcvtLLW2yRtqp1tVt1Ltge6cYYDLRxnq6wV8vP9w_rWqpV36O3GA7IbqOWAcc_PCLXpyfz8jyaXZ1dlMUsqgFiiGqWQ57xVGiVJCJhoBPNTZw0qNMMVBobFtdGcKlACBCY6VpxncXKKImAKEYk2u6GF-zWuuq8XSn_Vjllq6m9KSrnH6qnflEJwXIJm_zRNl97F4LH5rcBrPo-s_o7U3wBwXdo4Q
CitedBy_id crossref_primary_10_1002_smll_202307165
Cites_doi 10.1039/C9NR04790E
10.1021/acs.chemmater.0c00359
10.1016/j.mtener.2021.100840
10.1021/acs.nanolett.8b04957
10.1016/j.nantod.2012.08.004
10.1002/aenm.201801514
10.1002/smll.201802140
10.1021/acs.jpclett.9b02335
10.1038/srep25405
10.1002/adfm.201909486
10.1038/nnano.2007.411
10.1002/aenm.201702403
10.1039/C9TA07357D
10.1126/science.abf1581
10.1021/nn1006368
10.1016/j.nanoen.2019.104037
10.1039/C8EE01023D
10.1038/s41467-019-10631-0
10.1002/advs.201801354
10.1039/C6TA08432J
10.1002/cnma.201700232
10.1021/acsnano.0c00177
10.1149/1945-7111/ab856e
10.1038/nchem.2085
10.1039/D1NR00131K
10.1021/nl201470j
10.1016/j.cej.2019.123170
10.1021/acsami.9b13308
10.1016/j.nanoen.2016.07.023
ContentType Journal Article
DBID AAYXX
CITATION
ADTPV
AFDQA
AOWAS
D8T
D8V
ZZAVC
DOI 10.1039/D2YA00168C
DatabaseName CrossRef
SwePub
SWEPUB Kungliga Tekniska Högskolan full text
SwePub Articles
SWEPUB Freely available online
SWEPUB Kungliga Tekniska Högskolan
SwePub Articles full text
DatabaseTitle CrossRef
DatabaseTitleList
CrossRef
DeliveryMethod fulltext_linktorsrc
EISSN 2753-1457
EndPage 1008
ExternalDocumentID oai_DiVA_org_kth_330971
10_1039_D2YA00168C
GroupedDBID AARTK
AAYXX
AKBGW
ALMA_UNASSIGNED_HOLDINGS
ANUXI
CITATION
EBS
GROUPED_DOAJ
H13
M~E
RRC
ADTPV
AFDQA
AOWAS
D8T
D8V
ZZAVC
ID FETCH-LOGICAL-c1141-c09198263ba553501b5b2d45feb681a64d04cd327a13313e8bca2b84ada7e1ee3
ISSN 2753-1457
IngestDate Sat Aug 24 00:04:31 EDT 2024
Fri Aug 23 01:09:24 EDT 2024
IsDoiOpenAccess false
IsOpenAccess true
IsPeerReviewed true
IsScholarly true
Issue 12
Language English
LinkModel OpenURL
MergedId FETCHMERGED-LOGICAL-c1141-c09198263ba553501b5b2d45feb681a64d04cd327a13313e8bca2b84ada7e1ee3
ORCID 0000-0002-8909-8846
0000-0002-1661-3771
0000-0001-9088-1064
OpenAccessLink http://dx.doi.org/10.1039/d2ya00168c
PageCount 10
ParticipantIDs swepub_primary_oai_DiVA_org_kth_330971
crossref_primary_10_1039_D2YA00168C
PublicationCentury 2000
PublicationDate 2022-12-08
PublicationDateYYYYMMDD 2022-12-08
PublicationDate_xml – month: 12
  year: 2022
  text: 2022-12-08
  day: 08
PublicationDecade 2020
PublicationTitle Energy advances
PublicationYear 2022
References Sarycheva (D2YA00168C/cit21/1) 2020; 32
Chan (D2YA00168C/cit16/1) 2008; 3
Wu (D2YA00168C/cit14/1) 2012; 7
Isaac (D2YA00168C/cit7/1) 2021; 21
Zhao (D2YA00168C/cit26/1) 2019; 65
VahidMohammadi (D2YA00168C/cit20/1) 2021; 372
Zhang (D2YA00168C/cit30/1) 2020; 387
Quartarone (D2YA00168C/cit1/1) 2020; 167
Subramaniyam (D2YA00168C/cit9/1) 2017; 5
Ekaterina Pomerantseva (D2YA00168C/cit29/1) 2019; 366
Rajagopalan (D2YA00168C/cit3/1) 2020; 30
Zhang (D2YA00168C/cit25/1) 2018; 4
Larcher (D2YA00168C/cit2/1) 2015; 7
Marcano (D2YA00168C/cit18/1) 2010; 4
Xu (D2YA00168C/cit4/1) 2018; 8
Zhang (D2YA00168C/cit12/1) 2019; 7
Su (D2YA00168C/cit8/1) 2021; 13
Tian (D2YA00168C/cit19/1) 2019; 10
Yao (D2YA00168C/cit15/1) 2011; 11
Casimir (D2YA00168C/cit13/1) 2016; 27
Guo (D2YA00168C/cit27/1) 2020; 14
Zhang (D2YA00168C/cit24/1) 2019; 10
Li (D2YA00168C/cit5/1) 2018; 11
Xiong (D2YA00168C/cit17/1) 2018; 14
Wu (D2YA00168C/cit10/1) 2019; 19
Zhang (D2YA00168C/cit11/1) 2019; 11
Meng (D2YA00168C/cit22/1) 2018; 8
Ansari (D2YA00168C/cit23/1) 2016; 6
Li (D2YA00168C/cit28/1) 2019; 11
Chang (D2YA00168C/cit6/1) 2019; 6
References_xml – volume: 11
  start-page: 19862
  year: 2019
  ident: D2YA00168C/cit28/1
  publication-title: Nanoscale
  doi: 10.1039/C9NR04790E
  contributor:
    fullname: Li
– volume: 32
  start-page: 3480
  year: 2020
  ident: D2YA00168C/cit21/1
  publication-title: Chem. Mater.
  doi: 10.1021/acs.chemmater.0c00359
  contributor:
    fullname: Sarycheva
– volume: 21
  start-page: 100840
  year: 2021
  ident: D2YA00168C/cit7/1
  publication-title: Mater. Today Energy
  doi: 10.1016/j.mtener.2021.100840
  contributor:
    fullname: Isaac
– volume: 19
  start-page: 1351
  year: 2019
  ident: D2YA00168C/cit10/1
  publication-title: Nano Lett.
  doi: 10.1021/acs.nanolett.8b04957
  contributor:
    fullname: Wu
– volume: 7
  start-page: 414
  year: 2012
  ident: D2YA00168C/cit14/1
  publication-title: Nano Today
  doi: 10.1016/j.nantod.2012.08.004
  contributor:
    fullname: Wu
– volume: 8
  start-page: 1801514
  year: 2018
  ident: D2YA00168C/cit22/1
  publication-title: Adv. Energy Mater.
  doi: 10.1002/aenm.201801514
  contributor:
    fullname: Meng
– volume: 14
  start-page: 1802140
  year: 2018
  ident: D2YA00168C/cit17/1
  publication-title: Small
  doi: 10.1002/smll.201802140
  contributor:
    fullname: Xiong
– volume: 10
  start-page: 6446
  year: 2019
  ident: D2YA00168C/cit24/1
  publication-title: J. Phys. Chem. Lett.
  doi: 10.1021/acs.jpclett.9b02335
  contributor:
    fullname: Zhang
– volume: 6
  start-page: 25405
  year: 2016
  ident: D2YA00168C/cit23/1
  publication-title: Sci. Rep.
  doi: 10.1038/srep25405
  contributor:
    fullname: Ansari
– volume: 30
  start-page: 1909486
  year: 2020
  ident: D2YA00168C/cit3/1
  publication-title: Adv. Funct. Mater.
  doi: 10.1002/adfm.201909486
  contributor:
    fullname: Rajagopalan
– volume: 3
  start-page: 31
  year: 2008
  ident: D2YA00168C/cit16/1
  publication-title: Nat. Nanotechnol.
  doi: 10.1038/nnano.2007.411
  contributor:
    fullname: Chan
– volume: 8
  start-page: 1702403
  year: 2018
  ident: D2YA00168C/cit4/1
  publication-title: Adv. Energy Mater.
  doi: 10.1002/aenm.201702403
  contributor:
    fullname: Xu
– volume: 7
  start-page: 21766
  year: 2019
  ident: D2YA00168C/cit12/1
  publication-title: J. Mater. Chem. A
  doi: 10.1039/C9TA07357D
  contributor:
    fullname: Zhang
– volume: 372
  start-page: eabf1581
  year: 2021
  ident: D2YA00168C/cit20/1
  publication-title: Science
  doi: 10.1126/science.abf1581
  contributor:
    fullname: VahidMohammadi
– volume: 4
  start-page: 4806
  year: 2010
  ident: D2YA00168C/cit18/1
  publication-title: ACS Nano
  doi: 10.1021/nn1006368
  contributor:
    fullname: Marcano
– volume: 65
  start-page: 104037
  year: 2019
  ident: D2YA00168C/cit26/1
  publication-title: Nano Energy
  doi: 10.1016/j.nanoen.2019.104037
  contributor:
    fullname: Zhao
– volume: 11
  start-page: 2310
  year: 2018
  ident: D2YA00168C/cit5/1
  publication-title: Energy Environ. Sci.
  doi: 10.1039/C8EE01023D
  contributor:
    fullname: Li
– volume: 10
  start-page: 2558
  year: 2019
  ident: D2YA00168C/cit19/1
  publication-title: Nat. Commun.
  doi: 10.1038/s41467-019-10631-0
  contributor:
    fullname: Tian
– volume: 6
  start-page: 1801354
  year: 2019
  ident: D2YA00168C/cit6/1
  publication-title: Adv. Sci.
  doi: 10.1002/advs.201801354
  contributor:
    fullname: Chang
– volume: 5
  start-page: 1925
  year: 2017
  ident: D2YA00168C/cit9/1
  publication-title: J. Mater. Chem. A
  doi: 10.1039/C6TA08432J
  contributor:
    fullname: Subramaniyam
– volume: 4
  start-page: 56
  year: 2018
  ident: D2YA00168C/cit25/1
  publication-title: ChemNanoMat
  doi: 10.1002/cnma.201700232
  contributor:
    fullname: Zhang
– volume: 14
  start-page: 3651
  year: 2020
  ident: D2YA00168C/cit27/1
  publication-title: ACS Nano
  doi: 10.1021/acsnano.0c00177
  contributor:
    fullname: Guo
– volume: 167
  start-page: 080509
  year: 2020
  ident: D2YA00168C/cit1/1
  publication-title: J. Electrochem. Soc.
  doi: 10.1149/1945-7111/ab856e
  contributor:
    fullname: Quartarone
– volume: 7
  start-page: 19
  year: 2015
  ident: D2YA00168C/cit2/1
  publication-title: Nat. Chem.
  doi: 10.1038/nchem.2085
  contributor:
    fullname: Larcher
– volume: 13
  start-page: 6635
  year: 2021
  ident: D2YA00168C/cit8/1
  publication-title: Nanoscale
  doi: 10.1039/D1NR00131K
  contributor:
    fullname: Su
– volume: 11
  start-page: 2949
  year: 2011
  ident: D2YA00168C/cit15/1
  publication-title: Nano Lett.
  doi: 10.1021/nl201470j
  contributor:
    fullname: Yao
– volume: 387
  start-page: 123170
  year: 2020
  ident: D2YA00168C/cit30/1
  publication-title: Chem. Eng. J.
  doi: 10.1016/j.cej.2019.123170
  contributor:
    fullname: Zhang
– volume: 366
  start-page: 969
  year: 2019
  ident: D2YA00168C/cit29/1
  publication-title: Science
  contributor:
    fullname: Ekaterina Pomerantseva
– volume: 11
  start-page: 42086
  year: 2019
  ident: D2YA00168C/cit11/1
  publication-title: ACS Appl. Mater. Interfaces
  doi: 10.1021/acsami.9b13308
  contributor:
    fullname: Zhang
– volume: 27
  start-page: 359
  year: 2016
  ident: D2YA00168C/cit13/1
  publication-title: Nano Energy
  doi: 10.1016/j.nanoen.2016.07.023
  contributor:
    fullname: Casimir
SSID ssj0002776071
Score 2.2530158
Snippet Herein, we report on scalable, environmentally benign, and additive-free, high-performance anodes for alkali–metal–ion batteries (MIBs, where M = Li + , Na + ,...
Herein, we report on scalable, environmentally benign, and additive-free, high-performance anodes for alkali-metal-ion batteries (MIBs, where M = Li+, Na+,...
SourceID swepub
crossref
SourceType Open Access Repository
Aggregation Database
StartPage 999
Title Additive-free red phosphorus/Ti 3 C 2 T x MXene nanocomposite anodes for metal–ion batteries
URI https://urn.kb.se/resolve?urn=urn:nbn:se:kth:diva-330971
Volume 1
hasFullText 1
inHoldings 1
isFullTextHit
isPrint
link http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwnV1ba9RAFB60vvgiior1UgYUX0K2yczk9rhslVKIT2lZQQhzW3epTUq6hdYHf7vnTG4brFB92LDMhmSZ8-XMmZPvfIeQDybOTIZ62iYNUl_oOPOzyCb-SsHyKXSSBAoT-vmX-PhUnCyj5VhC4KpLtmqmf95ZV_I_VoUxsCtWyf6DZYeLwgB8B_vCESwMx3vZeG6Mo_74q8Zi-xPjXa7rK_g011eoCrLxuLfwmFd4N16-BK_mVbKqkUWOVC18cVAb6wQZsJO0_OEjFpRT3Oy5hX3Svi0R7BgDQxwObqeRqKBx2-IKaxVMAwvjOcoDzQZv3iWl865Xt2MAORrByQ4683otLy6kcT8gACvvTK47xn2XmGCuR0qw40sZ7IT8ULT60zN7x1gHLbbjQLO2XdIfjj3gqItq2K3EIDXV4_I1Eco-2pzNy7r5Xp5v1yXnKJD1kDxi4ITQ--W_xvwbSxKU1sPeg_1_6tVreXY43mgSr0zUZF0EUjwlT7qtA523OHhGHtjqOfk2wQAFDNARA4fFhnK6oIwW9IY6BNAJAmiLAAoIoAMC6ICAF-T086dicex3HTN8Dfva0NcQ_WWwYeRKRhG-MlaRYkZEK6viNJSxMIHQhrNEhpyH3KZKS6ZSIY1MbGgtf0n2qrqyrwhVSjMbpFkKATs8wlJakQobay2YWgWp3Cfv-3kpL1thlNIRGnhWHrGvczd7i33ysZ2y4Zy_WOn1fU98Qx6PYHtL9rbNtX0HceFWHbh8yoEz829-xGav
link.rule.ids 230,315,783,787,867,888,27936,27937
linkProvider ISSN International Centre
openUrl ctx_ver=Z39.88-2004&ctx_enc=info%3Aofi%2Fenc%3AUTF-8&rfr_id=info%3Asid%2Fsummon.serialssolutions.com&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=article&rft.atitle=Additive-free+red+phosphorus%2FTi+3+C+2+T+x+MXene+nanocomposite+anodes+for+metal-ion+batteries&rft.jtitle=Energy+advances&rft.au=Subramaniyam%2C+Chandrasekar+M.&rft.au=Kang%2C+Mina&rft.au=Li%2C+Jian&rft.au=Mohammadi%2C+Armin+Vahid&rft.date=2022-12-08&rft.issn=2753-1457&rft.eissn=2753-1457&rft.issue=12&rft.spage=999&rft_id=info:doi/10.1039%2Fd2ya00168c&rft.externalDocID=oai_DiVA_org_kth_330971
thumbnail_l http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/lc.gif&issn=2753-1457&client=summon
thumbnail_m http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/mc.gif&issn=2753-1457&client=summon
thumbnail_s http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/sc.gif&issn=2753-1457&client=summon