White emission from Tm3＋/Tb3＋/Eu3＋ co-doped fluoride zirconate under ultraviolet excitation
We synthesize Tm3＋/Tb3＋/Eu3＋ triply-doped ZrF4-BaF2-LaF3-A1F3-NaF （ZBLAN） transparent glass by using a melt-quenching method. Under excitation of 365 nm, the white emission with Commission internationale deL＇Eclairage （CIE） coordinates of （0.33, 0.33） is achieved at the Eu3＋ concentration of 1.1 mol...
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| Published in | 中国物理B：英文版 no. 11; pp. 311 - 314 |
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| Main Author | |
| Format | Journal Article |
| Language | English |
| Published |
01.11.2014
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| Subjects | |
| Online Access | Get full text |
| ISSN | 1674-1056 2058-3834 |
| DOI | 10.1088/1674-1056/23/11/114103 |
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| Abstract | We synthesize Tm3＋/Tb3＋/Eu3＋ triply-doped ZrF4-BaF2-LaF3-A1F3-NaF （ZBLAN） transparent glass by using a melt-quenching method. Under excitation of 365 nm, the white emission with Commission internationale deL＇Eclairage （CIE） coordinates of （0.33, 0.33） is achieved at the Eu3＋ concentration of 1.1 mol%. The mechanisms for white emission and the energy transfer process of Tb3＋→ Eu3＋ are discussed in terms of the photoluminescence, photoluminescence excitation spectra, and the light emission decay curves. The nature for the Tb3＋ → Eu3＋ energy transfer is described with the aid of an energy level diagram. |
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| AbstractList | We synthesize Tm3＋/Tb3＋/Eu3＋ triply-doped ZrF4-BaF2-LaF3-A1F3-NaF （ZBLAN） transparent glass by using a melt-quenching method. Under excitation of 365 nm, the white emission with Commission internationale deL＇Eclairage （CIE） coordinates of （0.33, 0.33） is achieved at the Eu3＋ concentration of 1.1 mol%. The mechanisms for white emission and the energy transfer process of Tb3＋→ Eu3＋ are discussed in terms of the photoluminescence, photoluminescence excitation spectra, and the light emission decay curves. The nature for the Tb3＋ → Eu3＋ energy transfer is described with the aid of an energy level diagram. |
| Author | 孙健 张晓松 苑琳琳 冯志军 凌志 李岚 |
| AuthorAffiliation | College of Science, Tianjin University of Technology, Tianjin 300384, China Institute of Material Physics, Key Laboratory for Optoelectronic Materials and Devices of Tianjin, Key Laboratory of Display Materials and Photoelectric Devices of Ministry of Education, Tianjin University of Technology, Tianjin 300191, China |
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| Notes | Sun Jian, Zhang Xiao-Song, Ling Zhi, Yuan Lin-Lin, Feng Zhi-Jun, and LiLan（ a） College of Science, Tianjin University of Technology, Tianjin 300384, China b） Institute of Material Physics, Key Laboratory for Optoelectronic Materials and Devices of Tianjin, Key Laboratory of Display Materials and Photoelec~c Devices of Ministry of Education, Tianjin University of Technology, Tianjin 300191, China white light emitting glass, photoluminescence, energy transfer process 11-5639/O4 We synthesize Tm3＋/Tb3＋/Eu3＋ triply-doped ZrF4-BaF2-LaF3-A1F3-NaF （ZBLAN） transparent glass by using a melt-quenching method. Under excitation of 365 nm, the white emission with Commission internationale deL＇Eclairage （CIE） coordinates of （0.33, 0.33） is achieved at the Eu3＋ concentration of 1.1 mol%. The mechanisms for white emission and the energy transfer process of Tb3＋→ Eu3＋ are discussed in terms of the photoluminescence, photoluminescence excitation spectra, and the light emission decay curves. The nature for the Tb3＋ → Eu3＋ energy transfer is described with the aid of an energy level diagram. |
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| Snippet | We synthesize Tm3＋/Tb3＋/Eu3＋ triply-doped ZrF4-BaF2-LaF3-A1F3-NaF （ZBLAN） transparent glass by using a melt-quenching method. Under excitation of 365 nm, the... |
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| SubjectTerms | 光致发光激发光谱 共掺杂 氟化物 白色发光 紫外光 铕 铥 铽 |
| Title | White emission from Tm3＋/Tb3＋/Eu3＋ co-doped fluoride zirconate under ultraviolet excitation |
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