Charge-Transfer-Promoted High Oxygen Evolution Activity of Co@Co 9 S 8 Core-Shell Nanochains
Co@Co S nanochains with core-shell structures are prepared by a direct-current arc-discharge technique and followed sulfurization at 200 °C. The nanochains, which consist of uniform nanospheres connecting each other, can range up to several micrometers. The thickness of Co S shell can be changed by...
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Published in | ACS applied materials & interfaces Vol. 10; no. 14; pp. 11565 - 11571 |
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Main Authors | , , , , , , , , , |
Format | Journal Article |
Language | English |
Published |
United States
11.04.2018
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Subjects | |
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Abstract | Co@Co
S
nanochains with core-shell structures are prepared by a direct-current arc-discharge technique and followed sulfurization at 200 °C. The nanochains, which consist of uniform nanospheres connecting each other, can range up to several micrometers. The thickness of Co
S
shell can be changed by regulating the sulfurization time. In this heterostructure of Co@Co
S
, Co nanochains function as a conductive network and can inject electrons into Co
S
, which manipulates the work function of Co
S
and makes it more apposite for catalysis. The density functional theory calculation also reveals that coupling with Co can significantly reduce the overpotential needed to drive the oxygen evolution process. On the basis of the exclusive structure, Co@Co
S
nanochains have shown high catalytic activity in the oxygen evolution reaction. Co@Co
S
reaches an overpotential of 285 mv at 10 mA cm
, which is much lower than that of Co nanochains (408 mV) and Co
S
(418 mV). Co@Co
S
also shows higher catalytic activity and robustness compared to state-of-the-art noble-metal catalyst RuO
. |
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AbstractList | Co@Co
S
nanochains with core-shell structures are prepared by a direct-current arc-discharge technique and followed sulfurization at 200 °C. The nanochains, which consist of uniform nanospheres connecting each other, can range up to several micrometers. The thickness of Co
S
shell can be changed by regulating the sulfurization time. In this heterostructure of Co@Co
S
, Co nanochains function as a conductive network and can inject electrons into Co
S
, which manipulates the work function of Co
S
and makes it more apposite for catalysis. The density functional theory calculation also reveals that coupling with Co can significantly reduce the overpotential needed to drive the oxygen evolution process. On the basis of the exclusive structure, Co@Co
S
nanochains have shown high catalytic activity in the oxygen evolution reaction. Co@Co
S
reaches an overpotential of 285 mv at 10 mA cm
, which is much lower than that of Co nanochains (408 mV) and Co
S
(418 mV). Co@Co
S
also shows higher catalytic activity and robustness compared to state-of-the-art noble-metal catalyst RuO
. |
Author | Yin, Junwen Dong, Chenlong Huang, Fuqiang Wang, Xin Dong, Wujie Riaz, Muhammad Sohail Chen, Ming-Yang Zhang, Zhe Liu, Zichao Yuan, Xiaotao |
Author_xml | – sequence: 1 givenname: Xiaotao surname: Yuan fullname: Yuan, Xiaotao organization: Beijing National Laboratory for Molecular Sciences and State Key Laboratory of Rare Earth Materials Chemistry and Applications, College of Chemistry and Molecular Engineering , Peking University , Beijing 100871 , P. R. China – sequence: 2 givenname: Junwen surname: Yin fullname: Yin, Junwen organization: Beijing Computational Science Research Center , Beijing 100084 , China – sequence: 3 givenname: Zichao surname: Liu fullname: Liu, Zichao organization: Beijing National Laboratory for Molecular Sciences and State Key Laboratory of Rare Earth Materials Chemistry and Applications, College of Chemistry and Molecular Engineering , Peking University , Beijing 100871 , P. R. China – sequence: 4 givenname: Xin surname: Wang fullname: Wang, Xin organization: Beijing National Laboratory for Molecular Sciences and State Key Laboratory of Rare Earth Materials Chemistry and Applications, College of Chemistry and Molecular Engineering , Peking University , Beijing 100871 , P. R. China – sequence: 5 givenname: Chenlong surname: Dong fullname: Dong, Chenlong organization: Beijing National Laboratory for Molecular Sciences and State Key Laboratory of Rare Earth Materials Chemistry and Applications, College of Chemistry and Molecular Engineering , Peking University , Beijing 100871 , P. R. China – sequence: 6 givenname: Wujie surname: Dong fullname: Dong, Wujie organization: Beijing National Laboratory for Molecular Sciences and State Key Laboratory of Rare Earth Materials Chemistry and Applications, College of Chemistry and Molecular Engineering , Peking University , Beijing 100871 , P. R. China – sequence: 7 givenname: Muhammad Sohail surname: Riaz fullname: Riaz, Muhammad Sohail organization: Beijing National Laboratory for Molecular Sciences and State Key Laboratory of Rare Earth Materials Chemistry and Applications, College of Chemistry and Molecular Engineering , Peking University , Beijing 100871 , P. R. China – sequence: 8 givenname: Zhe surname: Zhang fullname: Zhang, Zhe organization: Beijing National Laboratory for Molecular Sciences and State Key Laboratory of Rare Earth Materials Chemistry and Applications, College of Chemistry and Molecular Engineering , Peking University , Beijing 100871 , P. R. China – sequence: 9 givenname: Ming-Yang orcidid: 0000-0002-9866-8695 surname: Chen fullname: Chen, Ming-Yang organization: Beijing Computational Science Research Center , Beijing 100084 , China – sequence: 10 givenname: Fuqiang orcidid: 0000-0001-7727-0488 surname: Huang fullname: Huang, Fuqiang organization: State Key Laboratory of High Performance Ceramics and Superfine Microstructures, Shanghai Institute of Ceramics , Chinese Academy of Sciences , Shanghai 200050 , P. R. China |
BackLink | https://www.ncbi.nlm.nih.gov/pubmed/29521497$$D View this record in MEDLINE/PubMed |
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Keywords | oxygen evolution reaction Co@Co9S8 charge transfer nanochains core−shell structure |
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S
nanochains with core-shell structures are prepared by a direct-current arc-discharge technique and followed sulfurization at 200 °C. The nanochains,... |
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Title | Charge-Transfer-Promoted High Oxygen Evolution Activity of Co@Co 9 S 8 Core-Shell Nanochains |
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