Structure-Tailored Surface Oxide on Cu-Ga Intermetallics Enhances CO 2 Reduction Selectivity to Methanol at Ultralow Potential
Electrochemical CO reduction reaction (eCO RR) is performed on two intermetallic compounds formed by copper and gallium metals (CuGa and Cu Ga ). Among them, CuGa selectively converts CO to methanol with remarkable Faradaic efficiency of 77.26% at an extremely low potential of -0.3 V vs RHE. The hig...
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| Published in | Advanced materials (Weinheim) Vol. 34; no. 19; p. e2109426 |
|---|---|
| Main Authors | , , , , , , , |
| Format | Journal Article |
| Language | English |
| Published |
Germany
01.05.2022
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| Subjects | |
| Online Access | Get full text |
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| Abstract | Electrochemical CO
reduction reaction (eCO
RR) is performed on two intermetallic compounds formed by copper and gallium metals (CuGa
and Cu
Ga
). Among them, CuGa
selectively converts CO
to methanol with remarkable Faradaic efficiency of 77.26% at an extremely low potential of -0.3 V vs RHE. The high performance of CuGa
compared to Cu
Ga
is driven by its unique 2D structure, which retains surface and subsurface oxide species (Ga
O
) even in the reduction atmosphere. The Ga
O
species is mapped by X-ray photoelectron spectroscopy (XPS) and X-ray absorption fine structure (XAFS) techniques and electrochemical measurements. The eCO
RR selectivity to methanol are decreased at higher potential due to the lattice expansion caused by the reduction of the Ga
O
, which is probed by in situ XAFS, quasi in situ powder X-ray diffraction, and ex situ XPS measurements. The mechanism of the formation of methanol is visualized by in situ infrared (IR) spectroscopy and the source of the carbon of methanol at the molecular level is confirmed from the isotope-labeling experiments in presence of
CO
. Finally, to minimize the mass transport limitations and improve the overall eCO
RR performance, a poly(tetrafluoroethylene)-based gas diffusion electrode is used in the flow cell configuration. |
|---|---|
| AbstractList | Electrochemical CO
reduction reaction (eCO
RR) is performed on two intermetallic compounds formed by copper and gallium metals (CuGa
and Cu
Ga
). Among them, CuGa
selectively converts CO
to methanol with remarkable Faradaic efficiency of 77.26% at an extremely low potential of -0.3 V vs RHE. The high performance of CuGa
compared to Cu
Ga
is driven by its unique 2D structure, which retains surface and subsurface oxide species (Ga
O
) even in the reduction atmosphere. The Ga
O
species is mapped by X-ray photoelectron spectroscopy (XPS) and X-ray absorption fine structure (XAFS) techniques and electrochemical measurements. The eCO
RR selectivity to methanol are decreased at higher potential due to the lattice expansion caused by the reduction of the Ga
O
, which is probed by in situ XAFS, quasi in situ powder X-ray diffraction, and ex situ XPS measurements. The mechanism of the formation of methanol is visualized by in situ infrared (IR) spectroscopy and the source of the carbon of methanol at the molecular level is confirmed from the isotope-labeling experiments in presence of
CO
. Finally, to minimize the mass transport limitations and improve the overall eCO
RR performance, a poly(tetrafluoroethylene)-based gas diffusion electrode is used in the flow cell configuration. Abstract Electrochemical CO 2 reduction reaction (eCO 2 RR) is performed on two intermetallic compounds formed by copper and gallium metals (CuGa 2 and Cu 9 Ga 4 ). Among them, CuGa 2 selectively converts CO 2 to methanol with remarkable Faradaic efficiency of 77.26% at an extremely low potential of −0.3 V vs RHE. The high performance of CuGa 2 compared to Cu 9 Ga 4 is driven by its unique 2D structure, which retains surface and subsurface oxide species (Ga 2 O 3 ) even in the reduction atmosphere. The Ga 2 O 3 species is mapped by X‐ray photoelectron spectroscopy (XPS) and X‐ray absorption fine structure (XAFS) techniques and electrochemical measurements. The eCO 2 RR selectivity to methanol are decreased at higher potential due to the lattice expansion caused by the reduction of the Ga 2 O 3 , which is probed by in situ XAFS, quasi in situ powder X‐ray diffraction, and ex situ XPS measurements. The mechanism of the formation of methanol is visualized by in situ infrared (IR) spectroscopy and the source of the carbon of methanol at the molecular level is confirmed from the isotope‐labeling experiments in presence of 13 CO 2 . Finally, to minimize the mass transport limitations and improve the overall eCO 2 RR performance, a poly(tetrafluoroethylene)‐based gas diffusion electrode is used in the flow cell configuration. |
| Author | Raj, Jithu Roy, Soumyabrata Singh, Ashutosh Kumar Bagchi, Debabrata Manoj, Kaja Sai Vinod, C P Peter, Sebastian C Cherevotan, Arjun |
| Author_xml | – sequence: 1 givenname: Debabrata orcidid: 0000-0001-9922-2073 surname: Bagchi fullname: Bagchi, Debabrata organization: School of Advanced Materials, Jawaharlal Nehru Centre for Advanced Scientific Research, Jakkur, Bangalore, 560064, India – sequence: 2 givenname: Jithu surname: Raj fullname: Raj, Jithu organization: School of Advanced Materials, Jawaharlal Nehru Centre for Advanced Scientific Research, Jakkur, Bangalore, 560064, India – sequence: 3 givenname: Ashutosh Kumar orcidid: 0000-0002-2491-3678 surname: Singh fullname: Singh, Ashutosh Kumar organization: Chemistry and Physics of Materials Unit, Jawaharlal Nehru Centre for Advanced Scientific Research, Jakkur, Bangalore, 560064, India – sequence: 4 givenname: Arjun orcidid: 0000-0003-1649-0123 surname: Cherevotan fullname: Cherevotan, Arjun organization: School of Advanced Materials, Jawaharlal Nehru Centre for Advanced Scientific Research, Jakkur, Bangalore, 560064, India – sequence: 5 givenname: Soumyabrata orcidid: 0000-0003-3540-1341 surname: Roy fullname: Roy, Soumyabrata organization: School of Advanced Materials, Jawaharlal Nehru Centre for Advanced Scientific Research, Jakkur, Bangalore, 560064, India – sequence: 6 givenname: Kaja Sai surname: Manoj fullname: Manoj, Kaja Sai organization: School of Advanced Materials, Jawaharlal Nehru Centre for Advanced Scientific Research, Jakkur, Bangalore, 560064, India – sequence: 7 givenname: C P orcidid: 0000-0001-9857-4907 surname: Vinod fullname: Vinod, C P organization: Catalysis and Inorganic Chemistry Division, CSIR-National Chemical Laboratory, Dr. Homi Bhabha Road, Pune, 411008, India – sequence: 8 givenname: Sebastian C orcidid: 0000-0002-5211-446X surname: Peter fullname: Peter, Sebastian C organization: School of Advanced Materials, Jawaharlal Nehru Centre for Advanced Scientific Research, Jakkur, Bangalore, 560064, India |
| BackLink | https://www.ncbi.nlm.nih.gov/pubmed/35278256$$D View this record in MEDLINE/PubMed |
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| Cites_doi | 10.1038/s41929-018-0182-6 10.1021/acssuschemeng.8b03843 10.1016/j.rser.2013.11.045 10.1039/D0CC07318K 10.1016/j.joule.2019.07.021 10.1126/science.aas9100 10.1021/jacs.7b10462 10.1021/acscatal.7b01161 10.1039/D0EE03679J 10.1039/C9DT04749B 10.1039/C9EE03660A 10.1039/C6CY00971A 10.1039/C4GC02453B 10.1016/j.jpowsour.2013.12.002 10.1016/j.apcatb.2019.118369 10.1016/j.electacta.2020.137207 10.1021/acsenergylett.8b00740 10.1021/acsenergylett.8b00878 10.1016/0022-0728(91)85528-W 10.1016/j.jcat.2004.06.012 10.1039/C8EE00097B 10.1007/s00216-010-4219-1 10.1039/c3ee24040a 10.1021/ja202642y 10.1039/b800519b 10.1002/anie.201603034 10.1021/acscatal.6b02928 10.1021/acscatal.5b02543 10.1038/s41565-021-00974-5 10.1126/science.aav3506 10.1038/nchem.1873 10.1007/s10562-005-6507-5 10.1016/j.elecom.2020.106789 10.1149/1.3561636 10.1038/s41929-018-0169-3 10.1016/j.matt.2020.08.012 10.1021/jacs.9b11126 10.1088/0953-8984/27/17/175601 10.1039/D0SC01882A 10.1016/S0022-0728(96)04823-1 10.1002/anie.201810991 10.1039/c2ee21234j 10.1016/j.electacta.2004.11.061 10.1038/s41929-019-0269-8 10.1002/sia.6239 10.1021/acsenergylett.8b02525 10.1038/s41586-019-1760-8 10.1038/s41929-019-0397-1 10.1002/elan.201900665 10.1038/s41929-020-00547-0 10.1002/adfm.200701216 10.1016/j.jcou.2020.03.001 10.1016/0022-0728(94)03300-5 10.1016/j.jelechem.2017.09.046 10.1006/jcat.2000.2940 10.1038/s41929-020-00504-x 10.1103/PhysRevB.55.10786 10.1021/acs.chemrev.8b00705 10.1002/anie.201804142 10.1016/j.jcou.2019.05.025 10.1021/acs.jpcc.8b09598 10.1021/ja3010978 10.1021/acs.jpcc.6b03065 |
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| References | e_1_2_8_28_1 e_1_2_8_24_1 e_1_2_8_47_1 e_1_2_8_26_1 e_1_2_8_3_1 e_1_2_8_5_1 e_1_2_8_7_1 e_1_2_8_9_1 e_1_2_8_20_1 e_1_2_8_43_1 e_1_2_8_22_1 e_1_2_8_45_1 e_1_2_8_64_1 e_1_2_8_62_1 e_1_2_8_1_1 e_1_2_8_41_1 e_1_2_8_60_1 e_1_2_8_17_1 e_1_2_8_19_1 e_1_2_8_13_1 e_1_2_8_36_1 e_1_2_8_59_1 e_1_2_8_15_1 e_1_2_8_38_1 e_1_2_8_57_1 e_1_2_8_32_1 e_1_2_8_55_1 e_1_2_8_11_1 e_1_2_8_34_1 e_1_2_8_53_1 e_1_2_8_51_1 e_1_2_8_30_1 e_1_2_8_29_1 e_1_2_8_25_1 e_1_2_8_46_1 e_1_2_8_27_1 e_1_2_8_48_1 e_1_2_8_2_1 e_1_2_8_4_1 e_1_2_8_6_1 e_1_2_8_8_1 e_1_2_8_21_1 e_1_2_8_42_1 e_1_2_8_23_1 e_1_2_8_44_1 e_1_2_8_63_1 e_1_2_8_40_1 e_1_2_8_61_1 e_1_2_8_18_1 e_1_2_8_39_1 e_1_2_8_14_1 e_1_2_8_35_1 e_1_2_8_16_1 e_1_2_8_37_1 e_1_2_8_58_1 Shang L. (e_1_2_8_49_1) 2021 e_1_2_8_10_1 e_1_2_8_31_1 e_1_2_8_56_1 e_1_2_8_12_1 e_1_2_8_33_1 e_1_2_8_54_1 e_1_2_8_52_1 e_1_2_8_50_1 |
| References_xml | – ident: e_1_2_8_37_1 doi: 10.1038/s41929-018-0182-6 – ident: e_1_2_8_12_1 doi: 10.1021/acssuschemeng.8b03843 – ident: e_1_2_8_13_1 doi: 10.1016/j.rser.2013.11.045 – ident: e_1_2_8_40_1 doi: 10.1039/D0CC07318K – ident: e_1_2_8_64_1 doi: 10.1016/j.joule.2019.07.021 – ident: e_1_2_8_54_1 doi: 10.1126/science.aas9100 – ident: e_1_2_8_42_1 doi: 10.1021/jacs.7b10462 – ident: e_1_2_8_23_1 doi: 10.1021/acscatal.7b01161 – ident: e_1_2_8_55_1 doi: 10.1039/D0EE03679J – ident: e_1_2_8_35_1 doi: 10.1039/C9DT04749B – ident: e_1_2_8_6_1 doi: 10.1039/C9EE03660A – ident: e_1_2_8_18_1 doi: 10.1039/C6CY00971A – ident: e_1_2_8_11_1 doi: 10.1039/C4GC02453B – ident: e_1_2_8_16_1 doi: 10.1016/j.jpowsour.2013.12.002 – ident: e_1_2_8_28_1 doi: 10.1016/j.apcatb.2019.118369 – ident: e_1_2_8_56_1 doi: 10.1016/j.electacta.2020.137207 – ident: e_1_2_8_3_1 doi: 10.1021/acsenergylett.8b00740 – ident: e_1_2_8_2_1 doi: 10.1021/acsenergylett.8b00878 – ident: e_1_2_8_26_1 doi: 10.1016/0022-0728(91)85528-W – ident: e_1_2_8_52_1 doi: 10.1016/j.jcat.2004.06.012 – ident: e_1_2_8_7_1 doi: 10.1039/C8EE00097B – ident: e_1_2_8_48_1 doi: 10.1007/s00216-010-4219-1 – ident: e_1_2_8_4_1 doi: 10.1039/c3ee24040a – ident: e_1_2_8_1_1 doi: 10.1021/ja202642y – ident: e_1_2_8_47_1 doi: 10.1039/b800519b – ident: e_1_2_8_61_1 doi: 10.1002/anie.201603034 – ident: e_1_2_8_51_1 doi: 10.1021/acscatal.6b02928 – ident: e_1_2_8_41_1 doi: 10.1021/acscatal.5b02543 – ident: e_1_2_8_44_1 doi: 10.1038/s41565-021-00974-5 – ident: e_1_2_8_5_1 doi: 10.1126/science.aav3506 – ident: e_1_2_8_27_1 doi: 10.1038/nchem.1873 – ident: e_1_2_8_39_1 doi: 10.1007/s10562-005-6507-5 – ident: e_1_2_8_57_1 doi: 10.1016/j.elecom.2020.106789 – ident: e_1_2_8_15_1 doi: 10.1149/1.3561636 – ident: e_1_2_8_36_1 doi: 10.1038/s41929-018-0169-3 – ident: e_1_2_8_34_1 doi: 10.1016/j.matt.2020.08.012 – ident: e_1_2_8_43_1 doi: 10.1021/jacs.9b11126 – ident: e_1_2_8_31_1 doi: 10.1088/0953-8984/27/17/175601 – ident: e_1_2_8_22_1 doi: 10.1039/D0SC01882A – ident: e_1_2_8_59_1 doi: 10.1016/S0022-0728(96)04823-1 – ident: e_1_2_8_62_1 doi: 10.1002/anie.201810991 – ident: e_1_2_8_8_1 doi: 10.1039/c2ee21234j – start-page: 2101334 year: 2021 ident: e_1_2_8_49_1 publication-title: Small Methods contributor: fullname: Shang L. – ident: e_1_2_8_21_1 doi: 10.1016/j.electacta.2004.11.061 – ident: e_1_2_8_30_1 doi: 10.1038/s41929-019-0269-8 – ident: e_1_2_8_50_1 doi: 10.1002/sia.6239 – ident: e_1_2_8_38_1 doi: 10.1021/acsenergylett.8b02525 – ident: e_1_2_8_58_1 doi: 10.1038/s41586-019-1760-8 – ident: e_1_2_8_53_1 doi: 10.1038/s41929-019-0397-1 – ident: e_1_2_8_63_1 doi: 10.1002/elan.201900665 – ident: e_1_2_8_10_1 doi: 10.1038/s41929-020-00547-0 – ident: e_1_2_8_33_1 doi: 10.1002/adfm.200701216 – ident: e_1_2_8_29_1 doi: 10.1016/j.jcou.2020.03.001 – ident: e_1_2_8_60_1 doi: 10.1016/0022-0728(94)03300-5 – ident: e_1_2_8_19_1 doi: 10.1016/j.jelechem.2017.09.046 – ident: e_1_2_8_14_1 doi: 10.1006/jcat.2000.2940 – ident: e_1_2_8_9_1 doi: 10.1038/s41929-020-00504-x – ident: e_1_2_8_32_1 doi: 10.1103/PhysRevB.55.10786 – ident: e_1_2_8_25_1 doi: 10.1021/acs.chemrev.8b00705 – ident: e_1_2_8_20_1 doi: 10.1002/anie.201804142 – ident: e_1_2_8_17_1 doi: 10.1016/j.jcou.2019.05.025 – ident: e_1_2_8_45_1 doi: 10.1021/acs.jpcc.8b09598 – ident: e_1_2_8_24_1 doi: 10.1021/ja3010978 – ident: e_1_2_8_46_1 doi: 10.1021/acs.jpcc.6b03065 |
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| Snippet | Electrochemical CO
reduction reaction (eCO
RR) is performed on two intermetallic compounds formed by copper and gallium metals (CuGa
and Cu
Ga
). Among them,... Abstract Electrochemical CO 2 reduction reaction (eCO 2 RR) is performed on two intermetallic compounds formed by copper and gallium metals (CuGa 2 and Cu 9 Ga... |
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| StartPage | e2109426 |
| Title | Structure-Tailored Surface Oxide on Cu-Ga Intermetallics Enhances CO 2 Reduction Selectivity to Methanol at Ultralow Potential |
| URI | https://www.ncbi.nlm.nih.gov/pubmed/35278256 |
| Volume | 34 |
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