CuCl 2 ‐Catalyzed α ‐Chloroketonation of Aromatic Alkenes via Visible‐Light‐Induced LMCT

Here we report a copper‐catalyzed protocol for the synthesis of α ‐chloroketones from aromatic alkenes including electron‐deficient olefins under visible‐light irradiation. Preliminary mechanistic studies show that the peroxo Cu(II) species is the key intermediate and hydroperoxyl (HOO⋅) and chlorin...

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Published inChemistry, an Asian journal Vol. 18; no. 1; p. e202200954
Main Authors He, Xing‐Xian, Chang, Huan‐Huan, Zhao, Ying‐Xue, Li, Xiang‐Jie, Liu, Sheng‐An, Zang, Zhong‐Lin, Zhou, Cheng‐He, Cai, Gui‐Xin
Format Journal Article
LanguageEnglish
Published Germany 03.01.2023
Subjects
Alkenes
Catalysis
Copper
Light
CuCl2
LMCT
photocatalysis
aromatic alkenes
α-chloroketones
Online AccessGet full text
ISSN1861-4728
1861-471X
DOI10.1002/asia.202200954

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Abstract Here we report a copper‐catalyzed protocol for the synthesis of α ‐chloroketones from aromatic alkenes including electron‐deficient olefins under visible‐light irradiation. Preliminary mechanistic studies show that the peroxo Cu(II) species is the key intermediate and hydroperoxyl (HOO⋅) and chlorine (Cl⋅) radicals can be generated by ligand‐to‐metal charge transfer (LMCT).
AbstractList Here we report a copper‐catalyzed protocol for the synthesis of α ‐chloroketones from aromatic alkenes including electron‐deficient olefins under visible‐light irradiation. Preliminary mechanistic studies show that the peroxo Cu(II) species is the key intermediate and hydroperoxyl (HOO⋅) and chlorine (Cl⋅) radicals can be generated by ligand‐to‐metal charge transfer (LMCT).
Here we report a copper-catalyzed protocol for the synthesis of α-chloroketones from aromatic alkenes including electron-deficient olefins under visible-light irradiation. Preliminary mechanistic studies show that the peroxo Cu(II) species is the key intermediate and hydroperoxyl (HOO⋅) and chlorine (Cl⋅) radicals can be generated by ligand-to-metal charge transfer (LMCT).
Author Cai, Gui‐Xin
Zhao, Ying‐Xue
Zang, Zhong‐Lin
He, Xing‐Xian
Chang, Huan‐Huan
Li, Xiang‐Jie
Liu, Sheng‐An
Zhou, Cheng‐He
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Cites_doi 10.31635/ccschem.020.202000434
10.1126/science.aav9713
10.1002/ange.201907349
10.1002/adsc.202101016
10.1016/j.cclet.2013.09.001
10.1002/ange.201801678
10.1039/D0NP00018C
10.1038/s41557-021-00834-8
10.1002/anie.202100270
10.1002/adsc.201900626
10.1002/ange.201809984
10.1039/C9CC07655G
10.1039/C9CC00346K
10.1002/anie.201604898
10.1002/anie.201813090
10.1021/acs.orglett.7b00453
10.1002/anie.202112118
10.1021/ja4092648
10.1021/ja110668c
10.1038/s41570-022-00388-4
10.1039/c3gc40515j
10.1002/ange.200460462
10.1021/ja305665f
10.1021/acs.orglett.0c00052
10.1002/cjoc.201900372
10.1002/ange.202100270
10.1039/C7NJ00052A
10.1039/B315340A
10.1002/ange.202010801
10.1021/acs.joc.6b01465
10.1002/ange.201813090
10.1002/ange.201604898
10.1039/C7GC00283A
10.1002/anie.200460462
10.1016/j.tetlet.2011.09.106
10.1039/b707065a
10.1039/C6CC07272K
10.1021/acscatal.7b02892
10.1021/ja800443s
10.1002/anie.201809984
10.1002/anie.201002355
10.1016/j.cclet.2012.09.014
10.1021/ol501357w
10.1002/chem.202004810
10.1002/anie.202101033
10.1002/anie.202109072
10.1016/j.tetlet.2006.12.101
10.1002/ange.202007005
10.1002/anie.202010801
10.1021/jacs.2c01630
10.1038/ncomms15600
10.1246/cl.2012.432
10.1021/jacs.8b09251
10.1002/ange.201603914
10.1021/ja0016755
10.1039/C7CC03965D
10.1039/C9CC06746A
10.1002/adsc.201301012
10.1002/anie.201907349
10.1360/N032017-00104
10.1002/anie.201801678
10.1021/ja00870a025
10.1002/ejoc.202001238
10.1021/jacs.1c02490
10.1016/j.cclet.2020.02.022
10.1002/ange.202101033
10.3390/molecules27113583
10.1039/C4RA16130K
10.1002/anie.202007005
10.1002/anie.201603914
10.1021/acs.chemrev.1c00403
10.1002/anie.201101076
10.1021/jacs.1c00687
10.1021/jacs.0c06379
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Keywords CuCl2
LMCT
photocatalysis
aromatic alkenes
α-chloroketones
Language English
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References e_1_2_8_49_3
e_1_2_8_28_2
e_1_2_8_49_2
e_1_2_8_22_3
e_1_2_8_68_3
e_1_2_8_24_2
e_1_2_8_26_2
e_1_2_8_47_2
e_1_2_8_68_2
e_1_2_8_9_3
e_1_2_8_9_2
e_1_2_8_3_3
e_1_2_8_5_1
e_1_2_8_3_2
e_1_2_8_7_3
e_1_2_8_7_2
e_1_2_8_66_1
e_1_2_8_20_2
e_1_2_8_45_1
e_1_2_8_22_2
e_1_2_8_43_2
e_1_2_8_64_2
e_1_2_8_62_2
e_1_2_8_1_1
e_1_2_8_41_1
e_1_2_8_60_1
e_1_2_8_17_2
e_1_2_8_19_2
e_1_2_8_13_2
e_1_2_8_34_2
e_1_2_8_59_2
e_1_2_8_36_3
e_1_2_8_38_1
e_1_2_8_15_2
e_1_2_8_36_2
e_1_2_8_57_2
e_1_2_8_30_3
e_1_2_8_53_3
e_1_2_8_30_2
e_1_2_8_55_2
e_1_2_8_11_2
e_1_2_8_32_2
e_1_2_8_53_2
e_1_2_8_74_2
e_1_2_8_51_1
e_1_2_8_72_2
e_1_2_8_70_2
e_1_2_8_27_2
e_1_2_8_29_2
e_1_2_8_23_2
e_1_2_8_46_2
e_1_2_8_69_2
e_1_2_8_25_2
Koyama T. (e_1_2_8_39_2) 1993
e_1_2_8_46_3
e_1_2_8_48_1
e_1_2_8_2_2
e_1_2_8_4_2
e_1_2_8_6_2
e_1_2_8_8_2
e_1_2_8_65_2
e_1_2_8_21_1
e_1_2_8_42_1
e_1_2_8_67_1
e_1_2_8_44_2
e_1_2_8_63_2
e_1_2_8_61_2
e_1_2_8_40_2
e_1_2_8_16_2
e_1_2_8_18_1
e_1_2_8_12_2
e_1_2_8_35_2
e_1_2_8_58_2
e_1_2_8_33_3
e_1_2_8_14_2
e_1_2_8_56_2
e_1_2_8_37_1
e_1_2_8_54_2
e_1_2_8_31_1
e_1_2_8_10_2
e_1_2_8_33_2
e_1_2_8_52_2
e_1_2_8_52_3
e_1_2_8_73_3
e_1_2_8_50_2
e_1_2_8_73_2
e_1_2_8_71_2
References_xml – ident: e_1_2_8_47_2
  doi: 10.31635/ccschem.020.202000434
– ident: e_1_2_8_45_1
– ident: e_1_2_8_50_2
  doi: 10.1126/science.aav9713
– ident: e_1_2_8_31_1
– ident: e_1_2_8_36_3
  doi: 10.1002/ange.201907349
– ident: e_1_2_8_61_2
  doi: 10.1002/adsc.202101016
– ident: e_1_2_8_11_2
  doi: 10.1016/j.cclet.2013.09.001
– ident: e_1_2_8_52_3
  doi: 10.1002/ange.201801678
– ident: e_1_2_8_4_2
  doi: 10.1039/D0NP00018C
– ident: e_1_2_8_67_1
– ident: e_1_2_8_57_2
  doi: 10.1038/s41557-021-00834-8
– ident: e_1_2_8_49_2
  doi: 10.1002/anie.202100270
– ident: e_1_2_8_63_2
  doi: 10.1002/adsc.201900626
– ident: e_1_2_8_68_3
  doi: 10.1002/ange.201809984
– ident: e_1_2_8_25_2
  doi: 10.1039/C9CC07655G
– ident: e_1_2_8_28_2
  doi: 10.1039/C9CC00346K
– ident: e_1_2_8_33_2
  doi: 10.1002/anie.201604898
– ident: e_1_2_8_3_2
  doi: 10.1002/anie.201813090
– ident: e_1_2_8_24_2
  doi: 10.1021/acs.orglett.7b00453
– ident: e_1_2_8_22_2
  doi: 10.1002/anie.202112118
– ident: e_1_2_8_32_2
  doi: 10.1021/ja4092648
– year: 1993
  ident: e_1_2_8_39_2
  publication-title: Chem. Lett.
– ident: e_1_2_8_8_2
  doi: 10.1021/ja110668c
– ident: e_1_2_8_66_1
  doi: 10.1038/s41570-022-00388-4
– ident: e_1_2_8_34_2
  doi: 10.1039/c3gc40515j
– ident: e_1_2_8_9_2
  doi: 10.1002/ange.200460462
– ident: e_1_2_8_2_2
  doi: 10.1021/ja305665f
– ident: e_1_2_8_26_2
  doi: 10.1021/acs.orglett.0c00052
– ident: e_1_2_8_43_2
  doi: 10.1002/cjoc.201900372
– ident: e_1_2_8_49_3
  doi: 10.1002/ange.202100270
– ident: e_1_2_8_18_1
– ident: e_1_2_8_19_2
  doi: 10.1039/C7NJ00052A
– ident: e_1_2_8_16_2
  doi: 10.1039/B315340A
– ident: e_1_2_8_53_3
  doi: 10.1002/ange.202010801
– ident: e_1_2_8_65_2
  doi: 10.1021/acs.joc.6b01465
– ident: e_1_2_8_3_3
  doi: 10.1002/ange.201813090
– ident: e_1_2_8_33_3
  doi: 10.1002/ange.201604898
– ident: e_1_2_8_29_2
  doi: 10.1039/C7GC00283A
– ident: e_1_2_8_9_3
  doi: 10.1002/anie.200460462
– ident: e_1_2_8_42_1
– ident: e_1_2_8_10_2
  doi: 10.1016/j.tetlet.2011.09.106
– ident: e_1_2_8_12_2
  doi: 10.1039/b707065a
– ident: e_1_2_8_48_1
– ident: e_1_2_8_27_2
  doi: 10.1039/C6CC07272K
– ident: e_1_2_8_74_2
  doi: 10.1021/acscatal.7b02892
– ident: e_1_2_8_70_2
  doi: 10.1021/ja800443s
– ident: e_1_2_8_68_2
  doi: 10.1002/anie.201809984
– ident: e_1_2_8_7_2
  doi: 10.1002/anie.201002355
– ident: e_1_2_8_17_2
  doi: 10.1016/j.cclet.2012.09.014
– ident: e_1_2_8_35_2
  doi: 10.1021/ol501357w
– ident: e_1_2_8_51_1
– ident: e_1_2_8_62_2
  doi: 10.1002/chem.202004810
– ident: e_1_2_8_73_2
  doi: 10.1002/anie.202101033
– ident: e_1_2_8_22_3
  doi: 10.1002/anie.202109072
– ident: e_1_2_8_6_2
  doi: 10.1016/j.tetlet.2006.12.101
– ident: e_1_2_8_46_3
  doi: 10.1002/ange.202007005
– ident: e_1_2_8_53_2
  doi: 10.1002/anie.202010801
– ident: e_1_2_8_56_2
  doi: 10.1021/jacs.2c01630
– ident: e_1_2_8_14_2
  doi: 10.1038/ncomms15600
– ident: e_1_2_8_15_2
  doi: 10.1246/cl.2012.432
– ident: e_1_2_8_1_1
– ident: e_1_2_8_21_1
– ident: e_1_2_8_58_2
  doi: 10.1021/jacs.8b09251
– ident: e_1_2_8_30_3
  doi: 10.1002/ange.201603914
– ident: e_1_2_8_69_2
  doi: 10.1021/ja0016755
– ident: e_1_2_8_5_1
– ident: e_1_2_8_71_2
  doi: 10.1039/C7CC03965D
– ident: e_1_2_8_40_2
  doi: 10.1039/C9CC06746A
– ident: e_1_2_8_13_2
  doi: 10.1002/adsc.201301012
– ident: e_1_2_8_36_2
  doi: 10.1002/anie.201907349
– ident: e_1_2_8_60_1
– ident: e_1_2_8_64_2
  doi: 10.1360/N032017-00104
– ident: e_1_2_8_52_2
  doi: 10.1002/anie.201801678
– ident: e_1_2_8_59_2
  doi: 10.1021/ja00870a025
– ident: e_1_2_8_23_2
  doi: 10.1002/ejoc.202001238
– ident: e_1_2_8_55_2
  doi: 10.1021/jacs.1c02490
– ident: e_1_2_8_44_2
  doi: 10.1016/j.cclet.2020.02.022
– ident: e_1_2_8_73_3
  doi: 10.1002/ange.202101033
– ident: e_1_2_8_38_1
– ident: e_1_2_8_37_1
  doi: 10.3390/molecules27113583
– ident: e_1_2_8_20_2
  doi: 10.1039/C4RA16130K
– ident: e_1_2_8_46_2
  doi: 10.1002/anie.202007005
– ident: e_1_2_8_30_2
  doi: 10.1002/anie.201603914
– ident: e_1_2_8_41_1
  doi: 10.1021/acs.chemrev.1c00403
– ident: e_1_2_8_7_3
  doi: 10.1002/anie.201101076
– ident: e_1_2_8_54_2
  doi: 10.1021/jacs.1c00687
– ident: e_1_2_8_72_2
  doi: 10.1021/jacs.0c06379
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Snippet Here we report a copper‐catalyzed protocol for the synthesis of α ‐chloroketones from aromatic alkenes including electron‐deficient olefins under visible‐light...
Here we report a copper-catalyzed protocol for the synthesis of α-chloroketones from aromatic alkenes including electron-deficient olefins under visible-light...
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StartPage e202200954
SubjectTerms Alkenes
Catalysis
Copper
Light
Title CuCl 2 ‐Catalyzed α ‐Chloroketonation of Aromatic Alkenes via Visible‐Light‐Induced LMCT
URI https://www.ncbi.nlm.nih.gov/pubmed/36378015
Volume 18
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