Self‐Pillared Ultramicroporous Carbon Nanoplates for Selective Separation of CH 4 /N 2
There is growing evidence that pillaring up a densely packed ultramicroporous two‐dimensional (2D) structure is an effective strategy to reduce their internal diffusion. Reliable pillaring paradigms, however, is rather challenging. Here we report a one‐pot multi‐component sequential assembly method...
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| Published in | Angewandte Chemie International Edition Vol. 60; no. 12; pp. 6339 - 6343 |
|---|---|
| Main Authors | , , , , , |
| Format | Journal Article |
| Language | English |
| Published |
Germany
15.03.2021
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| Subjects | |
| Online Access | Get full text |
| ISSN | 1433-7851 1521-3773 |
| DOI | 10.1002/anie.202014231 |
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| Abstract | There is growing evidence that pillaring up a densely packed ultramicroporous two‐dimensional (2D) structure is an effective strategy to reduce their internal diffusion. Reliable pillaring paradigms, however, is rather challenging. Here we report a one‐pot multi‐component sequential assembly method for the preparation of a new self‐pillared 2D polymer and ultramicroporous carbon with integrated surface protrusions. The molecular level pillaring process is surprisingly fast, that is, in 10 min. The thickness of nanoplate edge and the density (roughness), angle as well as height of protrusions can be precisely tuned. Exemplified in coal bed methane purification/separation, this unique pillared 2D carbons exhibit a CH
4
/N
2
selectivity up to 24 at a low CH
4
partial pressure and two orders of magnitude faster CH
4
diffusion kinetics than the commercial carbon molecular sieves. This solution synthesis methodology is generalizable for creation and fine tuning of pillared 2D heterostructures. |
|---|---|
| AbstractList | There is growing evidence that pillaring up a densely packed ultramicroporous two-dimensional (2D) structure is an effective strategy to reduce their internal diffusion. Reliable pillaring paradigms, however, is rather challenging. Here we report a one-pot multi-component sequential assembly method for the preparation of a new self-pillared 2D polymer and ultramicroporous carbon with integrated surface protrusions. The molecular level pillaring process is surprisingly fast, that is, in 10 min. The thickness of nanoplate edge and the density (roughness), angle as well as height of protrusions can be precisely tuned. Exemplified in coal bed methane purification/separation, this unique pillared 2D carbons exhibit a CH
/N
selectivity up to 24 at a low CH
partial pressure and two orders of magnitude faster CH
diffusion kinetics than the commercial carbon molecular sieves. This solution synthesis methodology is generalizable for creation and fine tuning of pillared 2D heterostructures. There is growing evidence that pillaring up a densely packed ultramicroporous two‐dimensional (2D) structure is an effective strategy to reduce their internal diffusion. Reliable pillaring paradigms, however, is rather challenging. Here we report a one‐pot multi‐component sequential assembly method for the preparation of a new self‐pillared 2D polymer and ultramicroporous carbon with integrated surface protrusions. The molecular level pillaring process is surprisingly fast, that is, in 10 min. The thickness of nanoplate edge and the density (roughness), angle as well as height of protrusions can be precisely tuned. Exemplified in coal bed methane purification/separation, this unique pillared 2D carbons exhibit a CH 4 /N 2 selectivity up to 24 at a low CH 4 partial pressure and two orders of magnitude faster CH 4 diffusion kinetics than the commercial carbon molecular sieves. This solution synthesis methodology is generalizable for creation and fine tuning of pillared 2D heterostructures. |
| Author | Xu, Shuang Li, Wen‐Cui Lu, An‐Hui Tang, Lei Wang, Cheng‐Tong Hao, Guang‐Ping |
| Author_xml | – sequence: 1 givenname: Shuang surname: Xu fullname: Xu, Shuang organization: State Key Laboratory of Fine Chemicals Liaoning Key Laboratory for Catalytic Conversion of Carbon Resources School of Chemical Engineering Dalian University of Technology Dalian 116024 P. R. China – sequence: 2 givenname: Wen‐Cui surname: Li fullname: Li, Wen‐Cui organization: State Key Laboratory of Fine Chemicals Liaoning Key Laboratory for Catalytic Conversion of Carbon Resources School of Chemical Engineering Dalian University of Technology Dalian 116024 P. R. China – sequence: 3 givenname: Cheng‐Tong surname: Wang fullname: Wang, Cheng‐Tong organization: State Key Laboratory of Fine Chemicals Liaoning Key Laboratory for Catalytic Conversion of Carbon Resources School of Chemical Engineering Dalian University of Technology Dalian 116024 P. R. China – sequence: 4 givenname: Lei surname: Tang fullname: Tang, Lei organization: State Key Laboratory of Fine Chemicals Liaoning Key Laboratory for Catalytic Conversion of Carbon Resources School of Chemical Engineering Dalian University of Technology Dalian 116024 P. R. China – sequence: 5 givenname: Guang‐Ping surname: Hao fullname: Hao, Guang‐Ping organization: State Key Laboratory of Fine Chemicals Liaoning Key Laboratory for Catalytic Conversion of Carbon Resources School of Chemical Engineering Dalian University of Technology Dalian 116024 P. R. China – sequence: 6 givenname: An‐Hui orcidid: 0000-0003-1294-5928 surname: Lu fullname: Lu, An‐Hui organization: State Key Laboratory of Fine Chemicals Liaoning Key Laboratory for Catalytic Conversion of Carbon Resources School of Chemical Engineering Dalian University of Technology Dalian 116024 P. R. China |
| BackLink | https://www.ncbi.nlm.nih.gov/pubmed/33331111$$D View this record in MEDLINE/PubMed |
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| Keywords | porous carbon nanomaterials self-assembly carbon nanoplates hierarchical structures CH4/N2 separation |
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| Title | Self‐Pillared Ultramicroporous Carbon Nanoplates for Selective Separation of CH 4 /N 2 |
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