Kinetic Studies of the Pt Carbonate-Mediated, Room-Temperature Oxidation of Carbon Monoxide by Oxygen over Pt/Al 2 O 3 Using Combined, Time-Resolved XAFS, DRIFTS, and Mass Spectrometry

• Published in: Journal of the American Chemical Society Vol. 138; no. 42; pp. 13930 - 13940
• Main Authors: Newton, Mark A., Ferri, Davide, Smolentsev, Grigory, Marchionni, Valentina, Nachtegaal, Maarten
• Format: Journal Article
• Language: English
• Published: United States 26.10.2016

The kinetics involved in a recently revealed ambient-temperature mechanism for the catalytic oxidation of carbon monoxide by oxygen over a 5 wt % Pt/Al O catalyst are evaluated within a periodic, plug flow, redox operation paradigm using combined mass spectrometry (MS), diffuse reflectance infrared...