Effect of Perylene Photosensitizer Attachment to [Pd(triphosphine)L]2+ on CO2 Electrocatalysis

• Published in: Inorganic chemistry Vol. 55; no. 23; pp. 12281 - 12289
• Main Authors: Cook, Rita E, Phelan, Brian T, Shoer, Leah E, Majewski, Marek B, Wasielewski, Michael R
• Format: Journal Article
• Language: English
• Published: American Chemical Society 05.12.2016

Two new covalently linked chromophore–CO2 reduction catalyst systems were prepared using a perylene chromophore and a bis­[(dicyclohexylphosphino)­ethyl]­phenylphosphinopalladium­(II) catalyst. The primary goal of this study is to probe the influence of photosensitizer attachment on the electrocatal...