Porous Organic Cages for Sulfur Hexafluoride Separation

A series of porous organic cages is examined for the selective adsorption of sulfur hexafluoride (SF6) over nitrogen. Despite lacking any metal sites, a porous cage, CC3, shows the highest SF6/N2 selectivity reported for any material at ambient temperature and pressure, which translates to real sepa...

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Published inJournal of the American Chemical Society Vol. 138; no. 5; pp. 1653 - 1659
Main Authors Hasell, Tom, Miklitz, Marcin, Stephenson, Andrew, Little, Marc A, Chong, Samantha Y, Clowes, Rob, Chen, Linjiang, Holden, Daniel, Tribello, Gareth A, Jelfs, Kim E, Cooper, Andrew I
Format Journal Article
LanguageEnglish
Published United States American Chemical Society 10.02.2016
Subjects
adsorption
ambient temperature
crystals
nitrogen
sulfur hexafluoride
X-ray diffraction
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Abstract A series of porous organic cages is examined for the selective adsorption of sulfur hexafluoride (SF6) over nitrogen. Despite lacking any metal sites, a porous cage, CC3, shows the highest SF6/N2 selectivity reported for any material at ambient temperature and pressure, which translates to real separations in a gas breakthrough column. The SF6 uptake of these materials is considerably higher than would be expected from the static pore structures. The location of SF6 within these materials is elucidated by X-ray crystallography, and it is shown that cooperative diffusion and structural rearrangements in these molecular crystals can rationalize their superior SF6/N2 selectivity.
AbstractList A series of porous organic cages is examined for the selective adsorption of sulfur hexafluoride (SF6) over nitrogen. Despite lacking any metal sites, a porous cage, CC3, shows the highest SF6/N2 selectivity reported for any material at ambient temperature and pressure, which translates to real separations in a gas breakthrough column. The SF6 uptake of these materials is considerably higher than would be expected from the static pore structures. The location of SF6 within these materials is elucidated by X-ray crystallography, and it is shown that cooperative diffusion and structural rearrangements in these molecular crystals can rationalize their superior SF6/N2 selectivity.A series of porous organic cages is examined for the selective adsorption of sulfur hexafluoride (SF6) over nitrogen. Despite lacking any metal sites, a porous cage, CC3, shows the highest SF6/N2 selectivity reported for any material at ambient temperature and pressure, which translates to real separations in a gas breakthrough column. The SF6 uptake of these materials is considerably higher than would be expected from the static pore structures. The location of SF6 within these materials is elucidated by X-ray crystallography, and it is shown that cooperative diffusion and structural rearrangements in these molecular crystals can rationalize their superior SF6/N2 selectivity.
A series of porous organic cages is examined for the selective adsorption of sulfur hexafluoride (SF6) over nitrogen. Despite lacking any metal sites, a porous cage, CC3, shows the highest SF6/N2 selectivity reported for any material at ambient temperature and pressure, which translates to real separations in a gas breakthrough column. The SF6 uptake of these materials is considerably higher than would be expected from the static pore structures. The location of SF6 within these materials is elucidated by X-ray crystallography, and it is shown that cooperative diffusion and structural rearrangements in these molecular crystals can rationalize their superior SF6/N2 selectivity.
A series of porous organic cages is examined for the selective adsorption of sulfur hexafluoride (SF 6 ) over nitrogen. Despite lacking any metal sites, a porous cage, CC3 , shows the highest SF 6 /N 2 selectivity reported for any material at ambient temperature and pressure, which translates to real separations in a gas breakthrough column. The SF 6 uptake of these materials is considerably higher than would be expected from the static pore structures. The location of SF 6 within these materials is elucidated by X-ray crystallography, and it is shown that cooperative diffusion and structural rearrangements in these molecular crystals can rationalize their superior SF 6 /N 2 selectivity.
A series of porous organic cages is examined for the selective adsorption of sulfur hexafluoride (SF₆) over nitrogen. Despite lacking any metal sites, a porous cage, CC3, shows the highest SF₆/N₂ selectivity reported for any material at ambient temperature and pressure, which translates to real separations in a gas breakthrough column. The SF₆ uptake of these materials is considerably higher than would be expected from the static pore structures. The location of SF₆ within these materials is elucidated by X-ray crystallography, and it is shown that cooperative diffusion and structural rearrangements in these molecular crystals can rationalize their superior SF₆/N₂ selectivity.
Author Hasell, Tom
Stephenson, Andrew
Chong, Samantha Y
Holden, Daniel
Tribello, Gareth A
Jelfs, Kim E
Cooper, Andrew I
Miklitz, Marcin
Little, Marc A
Chen, Linjiang
Clowes, Rob
AuthorAffiliation University of Liverpool
Department of Chemistry
Queen’s University Belfast
Atomistic Simulation Centre, Department of Physics and Astronomy
Imperial College London
Department of Chemistry and Centre for Materials Discovery
AuthorAffiliation_xml – name: Department of Chemistry and Centre for Materials Discovery
– name: University of Liverpool
– name: Department of Chemistry
– name: Imperial College London
– name: Queen’s University Belfast
– name: Atomistic Simulation Centre, Department of Physics and Astronomy
Author_xml – sequence: 1
  givenname: Tom
  surname: Hasell
  fullname: Hasell, Tom
– sequence: 2
  givenname: Marcin
  surname: Miklitz
  fullname: Miklitz, Marcin
– sequence: 3
  givenname: Andrew
  surname: Stephenson
  fullname: Stephenson, Andrew
– sequence: 4
  givenname: Marc A
  surname: Little
  fullname: Little, Marc A
– sequence: 5
  givenname: Samantha Y
  surname: Chong
  fullname: Chong, Samantha Y
– sequence: 6
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  surname: Clowes
  fullname: Clowes, Rob
– sequence: 7
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  surname: Chen
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  fullname: Jelfs, Kim E
– sequence: 11
  givenname: Andrew I
  surname: Cooper
  fullname: Cooper, Andrew I
  email: aicooper@liv.ac.uk
BackLink https://www.ncbi.nlm.nih.gov/pubmed/26757885$$D View this record in MEDLINE/PubMed
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Snippet A series of porous organic cages is examined for the selective adsorption of sulfur hexafluoride (SF6) over nitrogen. Despite lacking any metal sites, a porous...
A series of porous organic cages is examined for the selective adsorption of sulfur hexafluoride (SF₆) over nitrogen. Despite lacking any metal sites, a porous...
A series of porous organic cages is examined for the selective adsorption of sulfur hexafluoride (SF 6 ) over nitrogen. Despite lacking any metal sites, a...
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SubjectTerms adsorption
ambient temperature
crystals
nitrogen
sulfur hexafluoride
X-ray diffraction
Title Porous Organic Cages for Sulfur Hexafluoride Separation
URI http://dx.doi.org/10.1021/jacs.5b11797
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