Room Temperature Synthesis of Covalent–Organic Framework Films through Vapor-Assisted Conversion
We describe the facile synthesis of several two-dimensional covalent–organic frameworks (2D COFs) as films by vapor-assisted conversion at room temperature. High-quality films of benzodithiophene-containing BDT-COF and COF-5 with tunable thickness were synthesized under different conditions on vario...
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| Published in | Journal of the American Chemical Society Vol. 137; no. 3; pp. 1016 - 1019 |
|---|---|
| Main Authors | , , , , , , , , |
| Format | Journal Article |
| Language | English |
| Published |
United States
American Chemical Society
28.01.2015
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| Subjects | |
| Online Access | Get full text |
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| Abstract | We describe the facile synthesis of several two-dimensional covalent–organic frameworks (2D COFs) as films by vapor-assisted conversion at room temperature. High-quality films of benzodithiophene-containing BDT-COF and COF-5 with tunable thickness were synthesized under different conditions on various substrates. BDT-COF films of several micrometer thickness exhibit mesoporosity as well as textural porosity, whereas thinner BDT-COF films materialize as a cohesive dense layer. In addition, we studied the formation of COF-5 films with different solvent mixture compositions serving as vapor source. Room temperature vapor-assisted conversion is an excellent method to form COF films of fragile precursors and on sensitive substrates. |
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| AbstractList | We describe the facile synthesis of several two-dimensional covalent-organic frameworks (2D COFs) as films by vapor-assisted conversion at room temperature. High-quality films of benzodithiophene-containing BDT-COF and COF-5 with tunable thickness were synthesized under different conditions on various substrates. BDT-COF films of several micrometer thickness exhibit mesoporosity as well as textural porosity, whereas thinner BDT-COF films materialize as a cohesive dense layer. In addition, we studied the formation of COF-5 films with different solvent mixture compositions serving as vapor source. Room temperature vapor-assisted conversion is an excellent method to form COF films of fragile precursors and on sensitive substrates. We describe the facile synthesis of several two-dimensional covalent–organic frameworks (2D COFs) as films by vapor-assisted conversion at room temperature. High-quality films of benzodithiophene-containing BDT-COF and COF-5 with tunable thickness were synthesized under different conditions on various substrates. BDT-COF films of several micrometer thickness exhibit mesoporosity as well as textural porosity, whereas thinner BDT-COF films materialize as a cohesive dense layer. In addition, we studied the formation of COF-5 films with different solvent mixture compositions serving as vapor source. Room temperature vapor-assisted conversion is an excellent method to form COF films of fragile precursors and on sensitive substrates. We describe the facile synthesis of several two-dimensional covalent-organic frameworks (2D COFs) as films by vapor-assisted conversion at room temperature. High-quality films of benzodithiophene-containing BDT-COF and COF-5 with tunable thickness were synthesized under different conditions on various substrates. BDT-COF films of several micrometer thickness exhibit mesoporosity as well as textural porosity, whereas thinner BDT-COF films materialize as a cohesive dense layer. In addition, we studied the formation of COF-5 films with different solvent mixture compositions serving as vapor source. Room temperature vapor-assisted conversion is an excellent method to form COF films of fragile precursors and on sensitive substrates.We describe the facile synthesis of several two-dimensional covalent-organic frameworks (2D COFs) as films by vapor-assisted conversion at room temperature. High-quality films of benzodithiophene-containing BDT-COF and COF-5 with tunable thickness were synthesized under different conditions on various substrates. BDT-COF films of several micrometer thickness exhibit mesoporosity as well as textural porosity, whereas thinner BDT-COF films materialize as a cohesive dense layer. In addition, we studied the formation of COF-5 films with different solvent mixture compositions serving as vapor source. Room temperature vapor-assisted conversion is an excellent method to form COF films of fragile precursors and on sensitive substrates. |
| Author | Markiewicz, John T Dogru, Mirjam Auras, Florian Rotter, Julian M Werner, Veronika Hu, Yinghong Medina, Dana D Bein, Thomas Knochel, Paul |
| AuthorAffiliation | University of Munich (LMU) Department of Chemistry and Center for NanoScience (CeNS) |
| AuthorAffiliation_xml | – name: Department of Chemistry and Center for NanoScience (CeNS) – name: University of Munich (LMU) |
| Author_xml | – sequence: 1 givenname: Dana D surname: Medina fullname: Medina, Dana D – sequence: 2 givenname: Julian M surname: Rotter fullname: Rotter, Julian M – sequence: 3 givenname: Yinghong surname: Hu fullname: Hu, Yinghong – sequence: 4 givenname: Mirjam surname: Dogru fullname: Dogru, Mirjam – sequence: 5 givenname: Veronika surname: Werner fullname: Werner, Veronika – sequence: 6 givenname: Florian surname: Auras fullname: Auras, Florian – sequence: 7 givenname: John T surname: Markiewicz fullname: Markiewicz, John T – sequence: 8 givenname: Paul surname: Knochel fullname: Knochel, Paul email: paul.knochel@cup.uni-munchen.de – sequence: 9 givenname: Thomas surname: Bein fullname: Bein, Thomas email: bein@lmu.de |
| BackLink | https://www.ncbi.nlm.nih.gov/pubmed/25539131$$D View this record in MEDLINE/PubMed |
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| Snippet | We describe the facile synthesis of several two-dimensional covalent–organic frameworks (2D COFs) as films by vapor-assisted conversion at room temperature.... We describe the facile synthesis of several two-dimensional covalent-organic frameworks (2D COFs) as films by vapor-assisted conversion at room temperature.... We describe the facile synthesis of several two-dimensional covalent–organic frameworks (2D COFs) as films by vapor-assisted conversion at room temperature.... |
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| SubjectTerms | ambient temperature Communication Conversion Covalence Micrometers Porosity Precursors Solvents Synthesis Two dimensional vapors |
| Title | Room Temperature Synthesis of Covalent–Organic Framework Films through Vapor-Assisted Conversion |
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