Organic pollution in surficial sediments of Tripoli harbour, Lebanon

• Published in: Marine pollution bulletin Vol. 93; no. 1-2; pp. 284 - 293
• Main Authors: Merhaby, Dima, Net, Sopheak, Halwani, Jalal, Ouddane, Baghdad
• Format: Journal Article
• Language: English
• Published: England Elsevier Ltd 15.04.2015; Elsevier
• Subjects: Analytical chemistry; Chemical Sciences; Coal; Continental interfaces, environment; Earth Sciences; Ecosystem; Environmental Monitoring; Geochemistry; Geologic Sediments - chemistry; Harbour; Lebanon; Marine; Me-PAHs; Mediterranean Sea; PAHs; PCBs; Polychlorinated Biphenyls - analysis; Polycyclic Aromatic Hydrocarbons - analysis; Sciences of the Universe; Sediments; SQGs; Water Pollutants, Chemical - analysis; MED, Western Mediterranean; MED; MED, Lebanon; MED, Eastern Mediterranean; Harbour; PCBs; PAHs; Me-PAHs; Sediments; SQGs
• ISSN: 0025-326X; 1879-3363
• DOI: 10.1016/j.marpolbul.2015.01.004

[Display omitted] •Three classes of POPs contaminant were monitored in Tripoli harbour sediments.•Pyrogenic process are predominant sources of PAHs and PCBs congeners.•PCBs contamination effect is expected for the biological compartment.•Evaluation of sediment ecotoxicological risk based on SQGs is applied. Tripoli harbour is among the most important ports on the Mediterranean Sea eastern basin. The persistent organic pollutants (POPs) were monitored (28 PCBs, 16 PAHs and 18 Me-PAHs) in 15 stations of Tripoli harbour basins, which are influenced by anthropogenic activities. Total PAHs concentrations ranged from 243 to 2965μgkg−1dw, total Me-PAH concentrations ranged from 54 to 1638μgkg−1dw, while total PCB levels ranged from 18 to 302μgkg−1dw. PCBs profiles were dominated by four and six-chlorinated congeners while the PAHs were dominated by four and five rings. For identifying pollution emission sources of PAHs, different ratios were used. The results show that the pollution origin was predominated by pyrogenic process related to the deposition of coal dust and the combustion of biomass and coal. Based on Sediments Quality Guidelines the biological adverse effects on aquatic ecosystems were expected rarely to occasionally for PAHs and PCBs contamination.