Chemical reactivity under collective vibrational strong coupling

• Published in: arXiv.org
• Main Authors: Wang, Derek S, Flick, Johannes, Yelin, Susanne F
• Format: Paper Journal Article
• Language: English
• Published: Ithaca Cornell University Library, arXiv.org 17.06.2022
• Subjects: Chemical reactions; Coupling (molecular); Dipole moments; Holes; Physics - Chemical Physics; Physics - Computational Physics; Physics - Quantum Physics; Vibration mode

Recent experiments of chemical reactions in optical cavities have shown great promise to alter and steer chemical reactions but still remain poorly understood theoretically. In particular the origin of resonant effects between the cavity and certain vibrational modes in the collective limit is still...