Theoretical Insights into the Dynamics of Gas-Phase Bimolecular Reactions with Submerged Barriers

• Published in: ACS Physical Chemistry Au Vol. 3; no. 5; pp. 406 - 418
• Main Authors: Song, Hongwei, Guo, Hua
• Format: Journal Article
• Language: English
• Published: United States American Chemical Society 27.09.2023
• Subjects: bimolecular reaction; product energy disposal; mode specificity; submerged barrier; non-Arrhenius behavior; rate coefficient; quantum effect

Much attention has been paid to the dynamics of both activated gas-phase bimolecular reactions, which feature monotonically increasing integral cross sections and Arrhenius kinetics, and their barrierless capture counterparts, which manifest monotonically decreasing integral cross sections and negat...