Graphene Gas Osmometers
Here it is shown that graphene membranes that separate 2 gases at identical pressure are deflected by osmotic pressure. The osmotic pressure is a consequence of differences in gas permeation rates into a graphene enclosed cavity. The deflection of the few layer graphene membranes is detected by an i...
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| Published in | arXiv.org |
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| Main Authors | , , , |
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Cornell University Library, arXiv.org
17.06.2016
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| Abstract | Here it is shown that graphene membranes that separate 2 gases at identical pressure are deflected by osmotic pressure. The osmotic pressure is a consequence of differences in gas permeation rates into a graphene enclosed cavity. The deflection of the few layer graphene membranes is detected by an interferometric technique for measuring their tension-induced resonance frequency. Using a calibration measurement of the relation between resonance frequency and pressure, the time dependent osmotic pressure on the graphene is extracted. The osmotic pressure for different combinations of gases shows large differences that can be accounted for by a model based on the different gas permeation rates. Thus a graphene membrane based gas osmometer with a responsitivity of ~60 kHz/mbar and nanoscale dimensions is demonstrated. |
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| AbstractList | Here it is shown that graphene membranes that separate 2 gases at identical pressure are deflected by osmotic pressure. The osmotic pressure is a consequence of differences in gas permeation rates into a graphene enclosed cavity. The deflection of the few layer graphene membranes is detected by an interferometric technique for measuring their tension-induced resonance frequency. Using a calibration measurement of the relation between resonance frequency and pressure, the time dependent osmotic pressure on the graphene is extracted. The osmotic pressure for different combinations of gases shows large differences that can be accounted for by a model based on the different gas permeation rates. Thus a graphene membrane based gas osmometer with a responsitivity of ~60 kHz/mbar and nanoscale dimensions is demonstrated. Here it is shown that graphene membranes that separate 2 gases at identical pressure are deflected by osmotic pressure. The osmotic pressure is a consequence of differences in gas permeation rates into a graphene enclosed cavity. The deflection of the few layer graphene membranes is detected by an interferometric technique for measuring their tension-induced resonance frequency. Using a calibration measurement of the relation between resonance frequency and pressure, the time dependent osmotic pressure on the graphene is extracted. The osmotic pressure for different combinations of gases shows large differences that can be accounted for by a model based on the different gas permeation rates. Thus a graphene membrane based gas osmometer with a responsitivity of ~60 kHz/mbar and nanoscale dimensions is demonstrated. |
| Author | Herre S J van der Zant Dolleman, Robin J Cartamil-Bueno, Santiago J Steeneken, Peter G |
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| BackLink | https://doi.org/10.1088/2053-1583/4/1/011002$$DView published paper (Access to full text may be restricted) https://doi.org/10.48550/arXiv.1606.05566$$DView paper in arXiv |
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| DOI | 10.48550/arxiv.1606.05566 |
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| Snippet | Here it is shown that graphene membranes that separate 2 gases at identical pressure are deflected by osmotic pressure. The osmotic pressure is a consequence... Here it is shown that graphene membranes that separate 2 gases at identical pressure are deflected by osmotic pressure. The osmotic pressure is a consequence... |
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| SubjectTerms | Deflection Gas permeation Gases Graphene Membranes Osmometers Osmosis Penetration Physics - Mesoscale and Nanoscale Physics Pressure dependence Time dependence |
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| Title | Graphene Gas Osmometers |
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