Self-Healing Polymers From Principles to Applications
This self-contained reference, written by a team of renowned international authors adopt a didactical approach to systematically cover all important aspects of designing self-healing polymers from concepts to applications - transferring lessons learnt from nature to materials science.It is the first...
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| Main Author | |
|---|---|
| Format | eBook Book |
| Language | English |
| Published |
Weinheim
Wiley-VCH
2013
John Wiley & Sons, Incorporated |
| Edition | 1. Aufl. |
| Subjects | |
| Online Access | Get full text |
| ISBN | 3527334394 9783527334391 |
| DOI | 10.1002/9783527670185 |
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| Abstract | This self-contained reference, written by a team of renowned international authors adopt a didactical approach to systematically cover all important aspects of designing self-healing polymers from concepts to applications - transferring lessons learnt from nature to materials science.It is the first to discuss the chemical and physical concepts for self-healing polymers, including aspects of biomimetic processes of healing in nature and tissue regeneration.Chapters will cover the design of self-healing polymers and explain the dynamics in these systems.Different self-healing concepts such as encapsulated systems and supramolecular systems are also included, with analysis and friction detection in self-healing polymers and on applications rounding off the whole. |
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| AbstractList | This self-contained reference, written by a team of renowned international authors adopt a didactical approach to systematically cover all important aspects of designing self-healing polymers from concepts to applications - transferring lessons learnt from nature to materials science.It is the first to discuss the chemical and physical concepts for self-healing polymers, including aspects of biomimetic processes of healing in nature and tissue regeneration.Chapters will cover the design of self-healing polymers and explain the dynamics in these systems.Different self-healing concepts such as encapsulated systems and supramolecular systems are also included, with analysis and friction detection in self-healing polymers and on applications rounding off the whole. Self-healing is a well-known phenomenon in nature: a broken bone merges after some time and if skin is damaged, the wound will stop bleeding and heals again. This concept can be mimicked in order to create polymeric materials with the ability to regenerate after they have suffered degradation or wear. Already realized applications are used in aerospace engineering, and current research in this fascinating field shows how different self-healing mechanisms proven successful by nature can be adapted to produce even more versatile materials. The book combines the knowledge of an international panel of experts in the field and provides the reader with chemical and physical concepts for self-healing polymers, including aspects of biomimetic processes of healing in nature. It shows how to design self-healing polymers and explains the dynamics in these systems. Different self-healing concepts such as encapsulated systems and supramolecular systems are detailed. Chapters on analysis and friction detection in self-healing polymers and on applications round off the book. |
| Author | Binder, Wolfgang H |
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| Keywords | Wissen Materialwissenschaften Technik |
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| Notes | Includes bibliographical references and index |
| OCLC | 836402320 |
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| PageCount | 447 |
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| PublicationPlace | Weinheim |
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| Snippet | This self-contained reference, written by a team of renowned international authors adopt a didactical approach to systematically cover all important aspects of... Self-healing is a well-known phenomenon in nature: a broken bone merges after some time and if skin is damaged, the wound will stop bleeding and heals again.... |
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| SubjectTerms | Bioplastics and Polymers Bioplastics en polymeren genezing healing Matériaux autoréparants polymeren Polymers Polymers. (OCoLC)fst01070588 Polymères Self-healing materials Self-healing materials. (OCoLC)fst01762776 |
| Subtitle | From Principles to Applications |
| TableOfContents | Cover -- Related Titles -- Title page -- Copyright page -- Contents -- List of Contributors -- Introduction -- References -- Part One: Design of Self-Healing Materials -- 1: Principles of Self-Healing Polymers -- 1.1 Introductory Remarks -- 1.2 General Concept for the Design and Classification of Self-Healing Materials -- 1.3 Physical Principles of Self-Healing -- 1.4 Chemical Principles of Self-Healing -- 1.4.1 Covalent Network Formation -- 1.4.2 Supramolecular Network Formation -- 1.4.3 Mechanochemical Network Formation -- 1.4.4 "Switchable" Network Formation -- 1.5 Multiple versus One-Time Self-Healing -- 1.6 Resume and Outlook -- Acknowledgments -- References -- 2: Self-Healing in Plants as Bio-Inspiration for Self-Repairing Polymers -- 2.1 Self-Sealing and Self-Healing in Plants: A Short Overview -- 2.2 Selected Self-Sealing and Self-Healing Processes in Plants as Role Models for Bio-Inspired Materials with Self-Repairing Properties -- 2.2.1 Latex Plants as Concept Generators for Bio-Inspired Self-Healing Elastomers (Role Models: Ficus benjamina and Hevea brasiliensis) -- 2.2.2 Lianas as Concept Generators for Bio-Inspired Self-Sealing Membranes for Pneumatic Structures (Role Model: Aristolochia macrophylla) -- 2.2.3 Succulent Plants as Concept Generators for Bio-Inspired Self-Sealing Membranes for Pneumatic Structures (Role Model Delosperma cooperi) -- 2.3 Bio-Inspired Approaches for the Development of Self-Repairing Materials and Structures -- 2.3.1 Bio-Inspired Self-Healing Elastomers -- 2.3.2 Self-Sealing Foam Coatings for Membranes of Pneumatic Structures -- 2.4 Bio-Inspired Self-Healing Materials: Outlook -- Acknowledgments -- References -- 3: Modeling Self-Healing Processes in Polymers: From Nanogels to Nanoparticle-Filled Microcapsules -- 3.1 Introduction -- 3.2 Designing Self-Healing Dual Cross-Linked Nanogel Networks 8.4.2 Activation of Catalytic Species -- 8.4.3 Disruption of Equilibrium -- 8.5 Conclusions and Outlook -- References -- 9: Chemistry of Crosslinking Processes for Self-Healing Polymers -- 9.1 Introduction -- 9.2 Extrinsic Self-Healing Materials -- 9.2.1 Catalytic Systems -- 9.2.2 Non-Catalytic Systems -- 9.3 Intrinsic Self-Healing Materials -- 9.3.1 Molecular Interdiffusion -- 9.3.2 Reversible Bond Formation -- 9.3.3 Other Systems -- 9.4 Concluding Remarks and Future Outlook -- References -- 10: Preparation of Nanocapsules and Core-Shell Nanofibers for Extrinsic Self-Healing Materials -- 10.1 Selected Preparation Methods for the Encapsulation of Self-Healing Agents -- 10.1.1 Emulsion Droplets as Templates -- 10.1.2 Electrospinning -- 10.2 Mechanically Induced Self-Healing -- 10.2.1 Nanocapsules -- 10.2.2 Nanofibers and Nanotubes -- 10.3 Stimuli-Responsive Self-Healing Materials -- 10.3.1 Light-Responsive Capsules -- 10.3.2 pH-Responsive Systems -- 10.3.3 Temperature-Responsive Systems -- 10.3.4 Redox-Responsive Systems -- 10.4 Novel Approaches and Perspectives -- References -- Part Three: Supramolecular Systems -- 11: Self-Healing Polymers via Supramolecular, Hydrogen-Bonded Networks -- 11.1 Introduction -- 11.2 Dynamics of Hydrogen Bonds in Solution -- 11.3 Supramolecular Gels -- 11.4 Self-Healing Bulk Materials -- 11.5 Conclusions -- Acknowledgment -- References -- 12: Metal-Complex-Based Self-Healing Polymers -- 12.1 Stimuli-Responsive Metallopolymers -- 12.2 Self-Healing Metallopolymers -- 12.3 Summary and Outlook -- Acknowledgments -- References -- 13: Self-Healing Ionomers -- 13.1 Introduction -- 13.2 Basic Principles of Ionomers -- 13.2.1 Properties -- 13.2.2 Applications and Availability -- 13.3 Ionomers in Self-Healing Systems -- 13.3.1 General Mechanism 13.4 Actual Developments and Future Trends in Ionomeric and Related Self-Healing Systems -- References -- Part Four: Analysis and Friction Detection in Self-Healing Polymers: Macroscopic, Microscopic and Nanoscopic Techniques -- 14: Methods to Monitor and Quantify (Self-) Healing in Polymers and Polymer Systems -- 14.1 Introduction -- 14.2 Visualization Techniques -- 14.2.1 Optical Microscopy -- 14.2.2 Scanning (SEM) and Environmental Scanning Electron (E-SEM) Microscopy -- 14.2.3 Acoustical Microscopy -- 14.2.4 Computed Tomography and Micro- (Computed) Tomography -- 14.3 Healing of Mechanical Properties -- 14.3.1 Healing after Static Damage -- 14.3.2 Healing after Fatigue Damage -- 14.3.3 Healing of Impact Damage -- 14.4 Healing of Functional Integrity -- 14.4.1 Healing of Esthetic Damage -- 14.4.2 Healing of Thermal and Electrical Conduction -- 14.4.3 Healing of Hydrophobicity and Surface Friction -- 14.4.4 Healing of Protection Against Corrosion -- 14.5 Summary -- References -- 15: Self-Healing Epoxies and Their Composites -- 15.1 Introduction -- 15.2 Capsule-Based Healing System -- 15.2.1 Self-Healing Epoxies -- 15.2.2 Self-Healing Fiber-Reinforced Epoxies -- 15.3 Vascular-Based Healing Systems -- 15.3.1 Recovery of Fracture Damage -- 15.3.2 Recovery of Impact Damage -- 15.3.3 Healing of Coatings -- 15.3.4 Self-Sensing, Self-Healing Vascularized Composites -- 15.4 Intrinsic Healing Systems -- 15.4.1 Resin Design for Reversibility -- 15.4.2 Dissolved Healing Agents -- 15.4.3 Phase Separated Healing Agents -- 15.4.4 Solid-Phase Healing Agents -- 15.5 Conclusions -- References -- 16: Self-Healing Coatings -- 16.1 Introduction into Self-Healing Coatings -- 16.2 Concept of Micro- and Nanocontainer-Based Self-Healing Coatings -- 16.3 Types of Nanocontainers -- 16.4 Characterization of Nanocontainer-Based Self-Healing Coatings 16.5 Conclusions and Current Trends -- References -- 17: Application of Self-Healing Materials in Aerospace Engineering -- 17.1 General Considerations -- 17.1.1 Stability and Reactivity of Catalysts for Self-Healing Formulations -- 17.1.2 Healing Efficiency at Low Temperatures -- 17.2 Conclusions -- References -- Index 3.2.1 Methodology -- 3.2.2 Results and Discussion -- 3.3 Designing "Artificial Leukocytes" That Help Heal Damaged Surfaces via the Targeted Delivery of Nanoparticles to Cracks -- 3.3.1 Methodology -- 3.3.2 Results and Discussion -- 3.4 Conclusions -- References -- Part Two: Polymer Dynamics -- 4: Structure and Dynamics of Polymer Chains -- 4.1 Foreword -- 4.2 Techniques -- 4.3 Structure -- 4.4 Dynamics -- 4.4.1 The Rouse Model -- 4.4.2 The Tube Model -- 4.5 Application to Self-Healing -- 4.6 Conclusions and Outlook -- References -- 5: Physical Chemistry of Cross-Linking Processes in Self-Healing Materials -- 5.1 Introduction -- 5.2 Thermodynamics of Gelation -- 5.3 Viscoelastic Properties of the Sol-Gel Transition -- 5.4 Phase Separation and Gelation -- 5.5 Conclusions -- References -- 6: Thermally Remendable Polymers -- 6.1 Principles of Thermal Healing -- 6.1.1 Physical Methods -- 6.1.2 Chemical Methods -- 6.2 Inorganic-Organic Systems -- 6.3 Efficiency, Assessment of Healing Performance -- 6.4 Conclusions -- Acknowledgments -- References -- 7: Photochemically Remendable Polymers -- 7.1 Background -- 7.2 Molecular Design -- 7.2.1 Polyurethane Containing Monohydroxy Coumarin Derivatives -- 7.2.2 Polyurethane Containing Dihydroxy Coumarin Derivatives -- 7.3 Reversible Photo-Crosslinking Behaviors -- 7.4 Evaluation of Photo-Remendability -- 7.5 Concluding Remarks -- Acknowledgments -- References -- 8: Mechanophores for Self-Healing Applications -- 8.1 Introduction -- 8.2 Mechanochemical Damage -- 8.2.1 Deformation -- 8.2.2 Homolytic Bond Cleavage -- 8.2.3 Heterolytic Bond Cleavage -- 8.3 Activation of Mechanophores -- 8.3.1 Ultrasound -- 8.3.2 Tensile Testing -- 8.3.3 Torsional Shear Testing -- 8.3.4 Compression -- 8.3.5 Others -- 8.4 Mechanochemical Self-Healing Strategies -- 8.4.1 Production of Reactive Species |
| Title | Self-Healing Polymers |
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