High-Pressure Behavior of Nickel Sulfate Monohydrate: Isothermal Compressibility, Structural Polymorphism, and Transition Pathway
Single crystals of synthetic nickel sulfate monohydrate, α-NiSO4·H2O (space-group symmetry C2/c at ambient conditions), were subject to high-pressure behavior investigations in a diamond-anvil cell up to 10.8 GPa. By means of subtle spectral changes in Raman spectra recorded at 298 K on isothermal c...
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| Published in | Inorganic chemistry Vol. 59; no. 9; pp. 6255 - 6266 |
|---|---|
| Main Authors | , , , , , |
| Format | Journal Article |
| Language | English |
| Published |
United States
American Chemical Society
04.05.2020
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| Online Access | Get full text |
| ISSN | 0020-1669 1520-510X 1520-510X |
| DOI | 10.1021/acs.inorgchem.0c00370 |
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| Abstract | Single crystals of synthetic nickel sulfate monohydrate, α-NiSO4·H2O (space-group symmetry C2/c at ambient conditions), were subject to high-pressure behavior investigations in a diamond-anvil cell up to 10.8 GPa. By means of subtle spectral changes in Raman spectra recorded at 298 K on isothermal compression, two discontinuities were identified at 2.47(1) and 6.5(5) GPa. Both transitions turn out to be apparently second order in character, as deduced from the continuous evolution of unit-cell volumes determined from single-crystal X-ray diffraction. The first structural transition from α- to β-NiSO4·H2O is an obvious ferroelastic C2/c–P1̅ transition. It is purely displacive from a structural point of view, accompanied by symmetry changes in the hydrogen-bonding scheme. The second β- to γ-NiSO4·H2O transition, further splitting the O2 (hydrogen bridge acceptor) position and violating the P1̅ space-group symmetry, is also evident from the splitting of individual bands in the Raman spectra. It can be attributed to symmetry reduction through local violation of local centrosymmetry. Lattice elasticities were obtained by fitting second-order Birch–Murnaghan equations of state to the p-V data points yielding the following zero-pressure bulk moduli values: K 0 = 63.4 ± 1.0 GPa for α-NiSO4·H2O, K 0 = 61.3 ± 1.9 GPa for β-NiSO4·H2O, and K 0 = 68.8 ± 2.5 GPa for γ-NiSO4·H2O. |
|---|---|
| AbstractList | Single crystals of
synthetic nickel sulfate monohydrate, α-NiSO
4
·H
2
O (space-group symmetry
C
2/
c
at ambient conditions), were subject to high-pressure behavior investigations
in a diamond-anvil cell up to 10.8 GPa. By means of subtle spectral
changes in Raman spectra recorded at 298 K on isothermal compression,
two discontinuities were identified at 2.47(1) and 6.5(5) GPa. Both
transitions turn out to be apparently second order in character, as
deduced from the continuous evolution of unit-cell volumes determined
from single-crystal X-ray diffraction. The first structural transition
from α- to β-NiSO
4
·H
2
O is an
obvious ferroelastic
C
2/
c
–
P
1̅ transition. It is purely displacive from a structural
point of view, accompanied by symmetry changes in the hydrogen-bonding
scheme. The second β- to γ-NiSO
4
·H
2
O transition, further splitting the O2 (hydrogen bridge acceptor)
position and violating the
P
1̅ space-group
symmetry, is also evident from the splitting of individual bands in
the Raman spectra. It can be attributed to symmetry reduction through
local violation of local centrosymmetry. Lattice elasticities were
obtained by fitting second-order Birch–Murnaghan equations
of state to the
p
-
V
data points
yielding the following zero-pressure bulk moduli values:
K
0
= 63.4 ± 1.0 GPa for α-NiSO
4
·H
2
O,
K
0
= 61.3 ± 1.9 GPa for
β-NiSO
4
·H
2
O, and
K
0
= 68.8 ± 2.5 GPa for γ-NiSO
4
·H
2
O.
Synthetic nickel sulfate monohydrate
crystals (space group
C
2/
c
at ambient
conditions) were subject to in situ high-pressure solid-state investigations
(structure from single crystal X-ray diffraction, lattice parameter,
Raman spectra) in a diamond-anvil cell up to 10.8 GPa. Two discontinuities,
apparently phase transitions of second order, were identified at 2.47
± 0.01 (obvious ferroelastic
C
2/
c
−
P
1̅) and 6.5 ± 0.5 GPa (
P
1̅−
P
1̅). Birch−Murnaghan
equations of state were fitted to the
P
−
V
data, and the obtained parameters are given. Single crystals of synthetic nickel sulfate monohydrate, α-NiSO4·H2O (space-group symmetry C2/c at ambient conditions), were subject to high-pressure behavior investigations in a diamond-anvil cell up to 10.8 GPa. By means of subtle spectral changes in Raman spectra recorded at 298 K on isothermal compression, two discontinuities were identified at 2.47(1) and 6.5(5) GPa. Both transitions turn out to be apparently second order in character, as deduced from the continuous evolution of unit-cell volumes determined from single-crystal X-ray diffraction. The first structural transition from α- to β-NiSO4·H2O is an obvious ferroelastic C2/c-P1̅ transition. It is purely displacive from a structural point of view, accompanied by symmetry changes in the hydrogen-bonding scheme. The second β- to γ-NiSO4·H2O transition, further splitting the O2 (hydrogen bridge acceptor) position and violating the P1̅ space-group symmetry, is also evident from the splitting of individual bands in the Raman spectra. It can be attributed to symmetry reduction through local violation of local centrosymmetry. Lattice elasticities were obtained by fitting second-order Birch-Murnaghan equations of state to the p-V data points yielding the following zero-pressure bulk moduli values: K0 = 63.4 ± 1.0 GPa for α-NiSO4·H2O, K0 = 61.3 ± 1.9 GPa for β-NiSO4·H2O, and K0 = 68.8 ± 2.5 GPa for γ-NiSO4·H2O.Single crystals of synthetic nickel sulfate monohydrate, α-NiSO4·H2O (space-group symmetry C2/c at ambient conditions), were subject to high-pressure behavior investigations in a diamond-anvil cell up to 10.8 GPa. By means of subtle spectral changes in Raman spectra recorded at 298 K on isothermal compression, two discontinuities were identified at 2.47(1) and 6.5(5) GPa. Both transitions turn out to be apparently second order in character, as deduced from the continuous evolution of unit-cell volumes determined from single-crystal X-ray diffraction. The first structural transition from α- to β-NiSO4·H2O is an obvious ferroelastic C2/c-P1̅ transition. It is purely displacive from a structural point of view, accompanied by symmetry changes in the hydrogen-bonding scheme. The second β- to γ-NiSO4·H2O transition, further splitting the O2 (hydrogen bridge acceptor) position and violating the P1̅ space-group symmetry, is also evident from the splitting of individual bands in the Raman spectra. It can be attributed to symmetry reduction through local violation of local centrosymmetry. Lattice elasticities were obtained by fitting second-order Birch-Murnaghan equations of state to the p-V data points yielding the following zero-pressure bulk moduli values: K0 = 63.4 ± 1.0 GPa for α-NiSO4·H2O, K0 = 61.3 ± 1.9 GPa for β-NiSO4·H2O, and K0 = 68.8 ± 2.5 GPa for γ-NiSO4·H2O. Single crystals of synthetic nickel sulfate monohydrate, α-NiSO4·H2O (space-group symmetry C2/c at ambient conditions), were subject to high-pressure behavior investigations in a diamond-anvil cell up to 10.8 GPa. By means of subtle spectral changes in Raman spectra recorded at 298 K on isothermal compression, two discontinuities were identified at 2.47(1) and 6.5(5) GPa. Both transitions turn out to be apparently second order in character, as deduced from the continuous evolution of unit-cell volumes determined from single-crystal X-ray diffraction. The first structural transition from α- to β-NiSO4·H2O is an obvious ferroelastic C2/c–P1̅ transition. It is purely displacive from a structural point of view, accompanied by symmetry changes in the hydrogen-bonding scheme. The second β- to γ-NiSO4·H2O transition, further splitting the O2 (hydrogen bridge acceptor) position and violating the P1̅ space-group symmetry, is also evident from the splitting of individual bands in the Raman spectra. It can be attributed to symmetry reduction through local violation of local centrosymmetry. Lattice elasticities were obtained by fitting second-order Birch–Murnaghan equations of state to the p-V data points yielding the following zero-pressure bulk moduli values: K 0 = 63.4 ± 1.0 GPa for α-NiSO4·H2O, K 0 = 61.3 ± 1.9 GPa for β-NiSO4·H2O, and K 0 = 68.8 ± 2.5 GPa for γ-NiSO4·H2O. Single crystals of synthetic nickel sulfate monohydrate, α-NiSO ·H O (space-group symmetry 2/ at ambient conditions), were subject to high-pressure behavior investigations in a diamond-anvil cell up to 10.8 GPa. By means of subtle spectral changes in Raman spectra recorded at 298 K on isothermal compression, two discontinuities were identified at 2.47(1) and 6.5(5) GPa. Both transitions turn out to be apparently second order in character, as deduced from the continuous evolution of unit-cell volumes determined from single-crystal X-ray diffraction. The first structural transition from α- to β-NiSO ·H O is an obvious ferroelastic 2/ - 1̅ transition. It is purely displacive from a structural point of view, accompanied by symmetry changes in the hydrogen-bonding scheme. The second β- to γ-NiSO ·H O transition, further splitting the O2 (hydrogen bridge acceptor) position and violating the 1̅ space-group symmetry, is also evident from the splitting of individual bands in the Raman spectra. It can be attributed to symmetry reduction through local violation of local centrosymmetry. Lattice elasticities were obtained by fitting second-order Birch-Murnaghan equations of state to the - data points yielding the following zero-pressure bulk moduli values: = 63.4 ± 1.0 GPa for α-NiSO ·H O, = 61.3 ± 1.9 GPa for β-NiSO ·H O, and = 68.8 ± 2.5 GPa for γ-NiSO ·H O. |
| Author | Wildner, Manfred Talla, Dominik Miletich, Ronald Ende, Martin Loitzenbauer, Michael Kirkkala, Terhi |
| AuthorAffiliation | Department of Chemistry Department of Mineralogy and Crystallography |
| AuthorAffiliation_xml | – name: Department of Chemistry – name: Department of Mineralogy and Crystallography |
| Author_xml | – sequence: 1 givenname: Martin orcidid: 0000-0002-9509-8543 surname: Ende fullname: Ende, Martin email: martin.ende@univie.ac.at organization: Department of Mineralogy and Crystallography – sequence: 2 givenname: Terhi surname: Kirkkala fullname: Kirkkala, Terhi organization: Department of Chemistry – sequence: 3 givenname: Michael surname: Loitzenbauer fullname: Loitzenbauer, Michael organization: Department of Mineralogy and Crystallography – sequence: 4 givenname: Dominik surname: Talla fullname: Talla, Dominik organization: Department of Mineralogy and Crystallography – sequence: 5 givenname: Manfred surname: Wildner fullname: Wildner, Manfred organization: Department of Mineralogy and Crystallography – sequence: 6 givenname: Ronald surname: Miletich fullname: Miletich, Ronald organization: Department of Mineralogy and Crystallography |
| BackLink | https://www.ncbi.nlm.nih.gov/pubmed/32293173$$D View this record in MEDLINE/PubMed |
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| Cites_doi | 10.1107/S2053229614024218 10.1107/S1600576716008050 10.1107/S0021889879012723 10.1103/PhysRev.71.809 10.1107/S2052520616018254 10.1111/j.1945-5100.1988.tb00894.x 10.1107/S2052520617009295 10.1127/ejm/2015/0027-2489 10.1007/BF01167093 10.1127/0935-1221/2006/0018-0449 10.1107/S1600576716015351 10.1126/science.1122659 10.1029/1999JE900005 10.1126/science.1109087 10.1007/s00269-018-0956-z 10.1127/ejm/10/4/0621 10.1080/08957950412331323924 10.1029/2008JE003266 10.2138/rmg.2000.41.14 10.1126/science.1109091 10.1002/jrs.1623 10.1007/s00269-013-0567-7 10.1016/S0022-2860(98)90417-3 10.1016/0019-1035(91)90235-L 10.2138/am.2008.2988 10.1029/2009JE003342 10.2138/am-2000-5-627 10.1107/S0021889812048431 10.1107/S1600576718003977 10.2138/am-2019-6983 10.1063/1.2135877 10.1107/S0567739476001551 10.1107/S0021889811043202 10.1007/BF00630961 10.1016/0304-386X(93)90069-P 10.3406/bulmi.1970.6424 10.1016/j.jssc.2019.06.004 10.1016/j.jallcom.2006.12.064 10.1107/S0021889810042305 10.1016/j.icarus.2016.11.032 10.1016/j.icarus.2019.113459 10.1029/JB091iB05p04673 10.2138/am-2020-7287 10.1180/minmag.2016.080.015 10.1107/S2052520616018266 10.1126/science.1059916 10.1029/JB075i017p03494 |
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| References | ref9/cit9 Bregeault J. M. (ref26/cit26) 1970; 93 ref45/cit45 ref3/cit3 ref27/cit27 ref52/cit52 ref23/cit23 ref8/cit8 ref31/cit31 ref2/cit2 ref34/cit34 ref37/cit37 ref48/cit48 ref17/cit17 ref10/cit10 Hawthorne F. C. (ref24/cit24) 1987; 157 ref35/cit35 ref19/cit19 ref21/cit21 ref42/cit42 ref46/cit46 ref49/cit49 ref13/cit13 ref38/cit38 ref50/cit50 ref6/cit6 ref36/cit36 ref18/cit18 ref11/cit11 ref25/cit25 Giester G. (ref16/cit16) 1994; 32 ref29/cit29 ref32/cit32 ref39/cit39 ref14/cit14 Wildner M. (ref15/cit15) 1981; 7 ref5/cit5 ref51/cit51 ref43/cit43 ref28/cit28 ref40/cit40 Giester G. (ref20/cit20) 1992; 3 ref12/cit12 ref41/cit41 ref22/cit22 ref33/cit33 ref4/cit4 ref30/cit30 ref47/cit47 ref1/cit1 ref44/cit44 ref7/cit7 |
| References_xml | – ident: ref41/cit41 doi: 10.1107/S2053229614024218 – ident: ref38/cit38 doi: 10.1107/S1600576716008050 – ident: ref37/cit37 doi: 10.1107/S0021889879012723 – ident: ref47/cit47 doi: 10.1103/PhysRev.71.809 – ident: ref10/cit10 doi: 10.1107/S2052520616018254 – ident: ref13/cit13 doi: 10.1111/j.1945-5100.1988.tb00894.x – ident: ref49/cit49 doi: 10.1107/S2052520617009295 – ident: ref17/cit17 doi: 10.1127/ejm/2015/0027-2489 – ident: ref25/cit25 doi: 10.1007/BF01167093 – ident: ref11/cit11 doi: 10.1127/0935-1221/2006/0018-0449 – ident: ref32/cit32 doi: 10.1107/S1600576716015351 – ident: ref1/cit1 doi: 10.1126/science.1122659 – ident: ref6/cit6 doi: 10.1029/1999JE900005 – ident: ref2/cit2 doi: 10.1126/science.1109087 – ident: ref14/cit14 doi: 10.1007/s00269-018-0956-z – ident: ref46/cit46 doi: 10.1127/ejm/10/4/0621 – ident: ref31/cit31 doi: 10.1080/08957950412331323924 – ident: ref12/cit12 doi: 10.1029/2008JE003266 – volume: 157 start-page: 121 year: 1987 ident: ref24/cit24 publication-title: Neues Jb Miner. Abh. – ident: ref30/cit30 doi: 10.2138/rmg.2000.41.14 – ident: ref40/cit40 – ident: ref3/cit3 doi: 10.1126/science.1109091 – ident: ref43/cit43 doi: 10.1002/jrs.1623 – ident: ref7/cit7 doi: 10.1007/s00269-013-0567-7 – ident: ref19/cit19 doi: 10.1016/S0022-2860(98)90417-3 – ident: ref5/cit5 doi: 10.1016/0019-1035(91)90235-L – ident: ref33/cit33 doi: 10.2138/am.2008.2988 – ident: ref4/cit4 doi: 10.1029/2009JE003342 – ident: ref22/cit22 doi: 10.2138/am-2000-5-627 – ident: ref39/cit39 doi: 10.1107/S0021889812048431 – ident: ref8/cit8 doi: 10.1107/S1600576718003977 – ident: ref29/cit29 doi: 10.2138/am-2019-6983 – ident: ref35/cit35 doi: 10.1063/1.2135877 – ident: ref50/cit50 doi: 10.1107/S0567739476001551 – ident: ref42/cit42 doi: 10.1107/S0021889811043202 – ident: ref23/cit23 doi: 10.1007/BF00630961 – ident: ref18/cit18 doi: 10.1016/0304-386X(93)90069-P – volume: 93 start-page: 37 year: 1970 ident: ref26/cit26 publication-title: Bull. Soc. Franc. Minéral. Cristallogr. doi: 10.3406/bulmi.1970.6424 – ident: ref27/cit27 doi: 10.1016/j.jssc.2019.06.004 – volume: 32 start-page: 873 year: 1994 ident: ref16/cit16 publication-title: Can. Mineral. – volume: 7 start-page: 296 year: 1981 ident: ref15/cit15 publication-title: Neues Jb. Miner. Monat. – ident: ref21/cit21 doi: 10.1016/j.jallcom.2006.12.064 – ident: ref36/cit36 doi: 10.1107/S0021889810042305 – volume: 3 start-page: 135 year: 1992 ident: ref20/cit20 publication-title: Neues Jb. Miner. Monat. – ident: ref51/cit51 doi: 10.1016/j.icarus.2016.11.032 – ident: ref28/cit28 doi: 10.1016/j.icarus.2019.113459 – ident: ref34/cit34 doi: 10.1029/JB091iB05p04673 – ident: ref44/cit44 doi: 10.2138/am-2020-7287 – ident: ref45/cit45 doi: 10.1180/minmag.2016.080.015 – ident: ref9/cit9 doi: 10.1107/S2052520616018266 – ident: ref52/cit52 doi: 10.1126/science.1059916 – ident: ref48/cit48 doi: 10.1029/JB075i017p03494 |
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| Snippet | Single crystals of synthetic nickel sulfate monohydrate, α-NiSO4·H2O (space-group symmetry C2/c at ambient conditions), were subject to high-pressure behavior... Single crystals of synthetic nickel sulfate monohydrate, α-NiSO ·H O (space-group symmetry 2/ at ambient conditions), were subject to high-pressure behavior... Single crystals of synthetic nickel sulfate monohydrate, α-NiSO 4 ·H 2 O (space-group symmetry C 2/ c at ambient conditions), were subject to high-pressure... |
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| Title | High-Pressure Behavior of Nickel Sulfate Monohydrate: Isothermal Compressibility, Structural Polymorphism, and Transition Pathway |
| URI | http://dx.doi.org/10.1021/acs.inorgchem.0c00370 https://www.ncbi.nlm.nih.gov/pubmed/32293173 https://www.proquest.com/docview/2390161413 https://pubmed.ncbi.nlm.nih.gov/PMC7201398 |
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