Structurally Diverse Covalent Triazine-Based Framework Materials for Photocatalytic Hydrogen Evolution from Water

• Published in: Chemistry of materials Vol. 31; no. 21; pp. 8830 - 8838
• Main Authors: Meier, Christian B, Clowes, Rob, Berardo, Enrico, Jelfs, Kim E, Zwijnenburg, Martijn A, Sprick, Reiner Sebastian, Cooper, Andrew I
• Format: Journal Article
• Language: English
• Published: United States American Chemical Society 12.11.2019

A structurally diverse family of 39 covalent triazine-based framework materials (CTFs) are synthesized by Suzuki–Miyaura polycondensation and tested as hydrogen evolution photocatalysts using a high-throughput workflow. The two best-performing CTFs are based on benzonitrile and dibenzo­[b,d]­thiophe...