Polyamorphism Mirrors Polymorphism in the Liquid–Liquid Transition of a Molecular Liquid
Liquid–liquid transitions between two amorphous phases in a single-component liquid have courted controversy. All known examples of liquid–liquid transitions in molecular liquids have been observed in the supercooled state, suggesting an intimate connection with vitrification and locally favored str...
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| Published in | Journal of the American Chemical Society Vol. 142; no. 16; pp. 7591 - 7597 |
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| Main Authors | , , , , , , , , , |
| Format | Journal Article |
| Language | English |
| Published |
United States
American Chemical Society
22.04.2020
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| Subjects | |
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| Abstract | Liquid–liquid transitions between two amorphous phases in a single-component liquid have courted controversy. All known examples of liquid–liquid transitions in molecular liquids have been observed in the supercooled state, suggesting an intimate connection with vitrification and locally favored structures inhibiting crystallization. However, there is precious little information about the local molecular packing in supercooled liquids, meaning that the order parameter of the transition is still unknown. Here, we investigate the liquid–liquid transition in triphenyl phosphite and show that it is caused by the competition between liquid structures that mirror two crystal polymorphs. The liquid–liquid transition is found to be between a geometrically frustrated liquid and a dynamically frustrated glass. These results indicate a general link between polymorphism and polyamorphism and will lead to a much greater understanding of the physical basis of liquid–liquid transitions and allow the systematic discovery of other examples. |
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| AbstractList | Liquid-liquid transitions between two amorphous phases in a single-component liquid have courted controversy. All known examples of liquid-liquid transitions in molecular liquids have been observed in the supercooled state, suggesting an intimate connection with vitrification and locally favored structures inhibiting crystallization. However, there is precious little information about the local molecular packing in supercooled liquids, meaning that the order parameter of the transition is still unknown. Here, we investigate the liquid-liquid transition in triphenyl phosphite and show that it is caused by the competition between liquid structures that mirror two crystal polymorphs. The liquid-liquid transition is found to be between a geometrically frustrated liquid and a dynamically frustrated glass. These results indicate a general link between polymorphism and polyamorphism and will lead to a much greater understanding of the physical basis of liquid-liquid transitions and allow the systematic discovery of other examples. Liquid-liquid transitions between two amorphous phases in a single-component liquid have courted controversy. All known examples of liquid-liquid transitions in molecular liquids have been observed in the supercooled state, suggesting an intimate connection with vitrification and locally favored structures inhibiting crystallization. However, there is precious little information about the local molecular packing in supercooled liquids, meaning that the order parameter of the transition is still unknown. Here, we investigate the liquid-liquid transition in triphenyl phosphite and show that it is caused by the competition between liquid structures that mirror two crystal polymorphs. The liquid-liquid transition is found to be between a geometrically frustrated liquid and a dynamically frustrated glass. These results indicate a general link between polymorphism and polyamorphism and will lead to a much greater understanding of the physical basis of liquid-liquid transitions and allow the systematic discovery of other examples.Liquid-liquid transitions between two amorphous phases in a single-component liquid have courted controversy. All known examples of liquid-liquid transitions in molecular liquids have been observed in the supercooled state, suggesting an intimate connection with vitrification and locally favored structures inhibiting crystallization. However, there is precious little information about the local molecular packing in supercooled liquids, meaning that the order parameter of the transition is still unknown. Here, we investigate the liquid-liquid transition in triphenyl phosphite and show that it is caused by the competition between liquid structures that mirror two crystal polymorphs. The liquid-liquid transition is found to be between a geometrically frustrated liquid and a dynamically frustrated glass. These results indicate a general link between polymorphism and polyamorphism and will lead to a much greater understanding of the physical basis of liquid-liquid transitions and allow the systematic discovery of other examples. Liquid–liquid transitions between two amorphous phases in a single-component liquid have courted controversy. All known examples of liquid–liquid transitions in molecular liquids have been observed in the supercooled state, suggesting an intimate connection with vitrification and locally favored structures inhibiting crystallization. However, there is precious little information about the local molecular packing in supercooled liquids, meaning that the order parameter of the transition is still unknown. Here, we investigate the liquid–liquid transition in triphenyl phosphite and show that it is caused by the competition between liquid structures that mirror two crystal polymorphs. The liquid–liquid transition is found to be between a geometrically frustrated liquid and a dynamically frustrated glass. These results indicate a general link between polymorphism and polyamorphism and will lead to a much greater understanding of the physical basis of liquid–liquid transitions and allow the systematic discovery of other examples. |
| Author | MacEwen, Jamie Bolling, John Jiménez, Mario González Cinque, Gianfelice Syme, Christopher D Wilson, Claire Senn, Hans M Farrell, Andrew Wynne, Klaas Walton, Finlay |
| AuthorAffiliation | School of Chemistry Diamond Light Source, Harwell Science and Innovation Campus |
| AuthorAffiliation_xml | – name: Diamond Light Source, Harwell Science and Innovation Campus – name: School of Chemistry |
| Author_xml | – sequence: 1 givenname: Finlay orcidid: 0000-0002-4739-1649 surname: Walton fullname: Walton, Finlay organization: School of Chemistry – sequence: 2 givenname: John surname: Bolling fullname: Bolling, John organization: School of Chemistry – sequence: 3 givenname: Andrew surname: Farrell fullname: Farrell, Andrew organization: School of Chemistry – sequence: 4 givenname: Jamie surname: MacEwen fullname: MacEwen, Jamie organization: School of Chemistry – sequence: 5 givenname: Christopher D surname: Syme fullname: Syme, Christopher D organization: School of Chemistry – sequence: 6 givenname: Mario González orcidid: 0000-0002-8853-0588 surname: Jiménez fullname: Jiménez, Mario González organization: School of Chemistry – sequence: 7 givenname: Hans M orcidid: 0000-0001-8232-5957 surname: Senn fullname: Senn, Hans M organization: School of Chemistry – sequence: 8 givenname: Claire orcidid: 0000-0002-0090-5374 surname: Wilson fullname: Wilson, Claire organization: School of Chemistry – sequence: 9 givenname: Gianfelice orcidid: 0000-0001-6801-8010 surname: Cinque fullname: Cinque, Gianfelice organization: Diamond Light Source, Harwell Science and Innovation Campus – sequence: 10 givenname: Klaas orcidid: 0000-0002-5305-5940 surname: Wynne fullname: Wynne, Klaas email: klaas.wynne@glasgow.ac.uk organization: School of Chemistry |
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| Cites_doi | 10.1039/B401262C 10.1016/j.molstruc.2004.03.033 10.1016/0378-4371(95)00140-3 10.1016/j.pmatsci.2013.12.002 10.1126/science.aaf4382 10.1016/S0167-7322(96)90018-5 10.1103/PhysRevE.72.011605 10.1016/j.jnoncrysol.2005.09.010 10.1021/acs.chemrev.5b00750 10.1038/ncomms13438 10.1021/jp970848i 10.1021/acs.jpcb.5b05402 10.1038/s41557-019-0210-4 10.1038/24540 10.1098/rspa.1952.0194 10.1021/jp000765t 10.1021/acs.jpcc.7b05336 10.1021/acs.jpcb.8b04112 10.1021/jp983926q 10.1038/nature06044 10.1038/35003143 10.1021/jp046762o 10.1021/jacs.7b03036 10.1038/369633a0 10.1038/nmat1458 10.1039/b505052a 10.1021/jacs.8b13231 10.1021/jp953785h 10.1126/sciadv.1602209 10.1021/ja903315v 10.1088/0953-8984/22/19/195102 10.1038/srep42439 10.1063/1.5041757 10.1039/b401308p 10.1016/j.jnoncrysol.2006.02.155 10.1073/pnas.1909660116 10.1002/anie.201204824 10.1021/jacs.9b03083 10.1126/science.1103073 10.1073/pnas.1822016116 10.1021/ja046602q 10.1088/0953-8984/17/27/L01 10.1038/nmat2897 10.1063/1.4989961 10.1088/0953-8984/15/11/329 10.1021/jz5022763 |
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| Snippet | Liquid–liquid transitions between two amorphous phases in a single-component liquid have courted controversy. All known examples of liquid–liquid transitions... Liquid-liquid transitions between two amorphous phases in a single-component liquid have courted controversy. All known examples of liquid-liquid transitions... Liquid–liquid transitions between two amorphous phases in a single-component liquid have courted controversy. All known examples of liquid–liquid transitions... |
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| SubjectTerms | crystallization glass liquids vitrification |
| Title | Polyamorphism Mirrors Polymorphism in the Liquid–Liquid Transition of a Molecular Liquid |
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