Chain-Length-Dependent Hydrogen-Bonded Self-Assembly of Terminally Functionalized Discrete Polyketones

• Published in: Precision Chemistry Vol. 1; no. 1; pp. 34 - 39
• Main Authors: Shivakumar, Kilingaru I., Manabe, Yumehiro, Yoneda, Tomoki, Ide, Yuki, Inokuma, Yasuhide
• Format: Journal Article
• Language: English
• Published: University of Science and Technology of China and American Chemical Society 27.03.2023; American Chemical Society
• Subjects: Letter; self-assembly; polyketone; helix; hydrogen bond; gel

Here, we report the synthesis and the chain-length-dependent self-assembling behaviors of discrete di-, tetra-, and hexaketones terminally functionalized with hydrogen-bonding carboxyl (C1, C2, and C3) and 3-acylaminopyridine groups (P1, P2, and P3). These polyketones were prepared by the coupling r...