Ionic Conduction in Composite Polymer Electrolytes: Case of PEO:Ga-LLZO Composites
By dispersing Li6.25Ga0.25La3Zr2O12 (Ga-LLZO) nanoparticles in poly(ethylene oxide) (PEO) matrix, PEO:Ga-LLZO composite polymer electrolytes are synthesized. The PEO: Ga-LLZO composite with 16 vol % Ga-LLZO nanoparticles shows a conductivity of 7.2 × 10–5 S cm–1 at 30 °C, about 4 orders of magnitud...
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| Published in | ACS applied materials & interfaces Vol. 11; no. 1; pp. 784 - 791 |
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| Main Authors | , , , , , , |
| Format | Journal Article |
| Language | English |
| Published |
United States
American Chemical Society
09.01.2019
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| Subjects | |
| Online Access | Get full text |
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| Abstract | By dispersing Li6.25Ga0.25La3Zr2O12 (Ga-LLZO) nanoparticles in poly(ethylene oxide) (PEO) matrix, PEO:Ga-LLZO composite polymer electrolytes are synthesized. The PEO: Ga-LLZO composite with 16 vol % Ga-LLZO nanoparticles shows a conductivity of 7.2 × 10–5 S cm–1 at 30 °C, about 4 orders of magnitude higher than the conductivity of PEO. The enhancement of the ionic conductivity is closely related to the space charge region (∼3 nm) formed at the interface between the PEO matrix and the Ga-LLZO nanoparticles. The space charge region is observed by transmission electron microscope (TEM) and corroborated by the phase-field simulation. Using the random resistor model, the lithium-ion transport in the composite polymer electrolyte is simulated by the Monte Carlo simulation, demonstrating that the enhanced ionic conductivity can be ascribed to the ionic conduction in the space charge regions and the percolation of the space charge regions. |
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| AbstractList | By dispersing Li₆.₂₅Ga₀.₂₅La₃Zr₂O₁₂ (Ga-LLZO) nanoparticles in poly(ethylene oxide) (PEO) matrix, PEO:Ga-LLZO composite polymer electrolytes are synthesized. The PEO: Ga-LLZO composite with 16 vol % Ga-LLZO nanoparticles shows a conductivity of 7.2 × 10–⁵ S cm–¹ at 30 °C, about 4 orders of magnitude higher than the conductivity of PEO. The enhancement of the ionic conductivity is closely related to the space charge region (∼3 nm) formed at the interface between the PEO matrix and the Ga-LLZO nanoparticles. The space charge region is observed by transmission electron microscope (TEM) and corroborated by the phase-field simulation. Using the random resistor model, the lithium-ion transport in the composite polymer electrolyte is simulated by the Monte Carlo simulation, demonstrating that the enhanced ionic conductivity can be ascribed to the ionic conduction in the space charge regions and the percolation of the space charge regions. By dispersing Li6.25Ga0.25La3Zr2O12 (Ga-LLZO) nanoparticles in poly(ethylene oxide) (PEO) matrix, PEO:Ga-LLZO composite polymer electrolytes are synthesized. The PEO: Ga-LLZO composite with 16 vol % Ga-LLZO nanoparticles shows a conductivity of 7.2 × 10-5 S cm-1 at 30 °C, about 4 orders of magnitude higher than the conductivity of PEO. The enhancement of the ionic conductivity is closely related to the space charge region (∼3 nm) formed at the interface between the PEO matrix and the Ga-LLZO nanoparticles. The space charge region is observed by transmission electron microscope (TEM) and corroborated by the phase-field simulation. Using the random resistor model, the lithium-ion transport in the composite polymer electrolyte is simulated by the Monte Carlo simulation, demonstrating that the enhanced ionic conductivity can be ascribed to the ionic conduction in the space charge regions and the percolation of the space charge regions.By dispersing Li6.25Ga0.25La3Zr2O12 (Ga-LLZO) nanoparticles in poly(ethylene oxide) (PEO) matrix, PEO:Ga-LLZO composite polymer electrolytes are synthesized. The PEO: Ga-LLZO composite with 16 vol % Ga-LLZO nanoparticles shows a conductivity of 7.2 × 10-5 S cm-1 at 30 °C, about 4 orders of magnitude higher than the conductivity of PEO. The enhancement of the ionic conductivity is closely related to the space charge region (∼3 nm) formed at the interface between the PEO matrix and the Ga-LLZO nanoparticles. The space charge region is observed by transmission electron microscope (TEM) and corroborated by the phase-field simulation. Using the random resistor model, the lithium-ion transport in the composite polymer electrolyte is simulated by the Monte Carlo simulation, demonstrating that the enhanced ionic conductivity can be ascribed to the ionic conduction in the space charge regions and the percolation of the space charge regions. By dispersing Li6.25Ga0.25La3Zr2O12 (Ga-LLZO) nanoparticles in poly(ethylene oxide) (PEO) matrix, PEO:Ga-LLZO composite polymer electrolytes are synthesized. The PEO: Ga-LLZO composite with 16 vol % Ga-LLZO nanoparticles shows a conductivity of 7.2 × 10–5 S cm–1 at 30 °C, about 4 orders of magnitude higher than the conductivity of PEO. The enhancement of the ionic conductivity is closely related to the space charge region (∼3 nm) formed at the interface between the PEO matrix and the Ga-LLZO nanoparticles. The space charge region is observed by transmission electron microscope (TEM) and corroborated by the phase-field simulation. Using the random resistor model, the lithium-ion transport in the composite polymer electrolyte is simulated by the Monte Carlo simulation, demonstrating that the enhanced ionic conductivity can be ascribed to the ionic conduction in the space charge regions and the percolation of the space charge regions. By dispersing Li6.25Ga0.25La3Zr2O12 (Ga-LLZO) nanoparticles in polyethylene oxide (PEO) matrix, PEO:Ga-LLZO composite polymer electrolytes are synthesized. The PEO:Ga-LLZO composite with 16 vol.% Ga-LLZO nanoparticles shows a conductivity of 7.2×10-5 S cm-1 at 30 °C, about 4 orders of magnitude higher than the conductivity of PEO. The enhancement of the ionic conductivity is closely related to the space charge region (~3 nm) formed at the interface between the PEO matrix and the Ga-LLZO nanoparticles. The space charge region is observed by transmission electron microscope (TEM) and corroborated by the phase-field simulation. Using the random resistor model, the lithium-ion transport in the composite polymer electrolyte is simulated by the Monte Carlo simulation, demonstrating that the enhanced ionic conductivity can be ascribed to the ionic conduction in the space charge regions and the percolation of the space charge regions. |
| Author | Huang, He-Ming Zhu, Jia-Kun Li, Zhuo Wu, Jian-Fang Guo, Xin Wei, Lu Yang, Hui |
| AuthorAffiliation | Department of Mechanics School of Materials Science and Engineering |
| AuthorAffiliation_xml | – name: School of Materials Science and Engineering – name: Department of Mechanics |
| Author_xml | – sequence: 1 givenname: Zhuo surname: Li fullname: Li, Zhuo – sequence: 2 givenname: He-Ming surname: Huang fullname: Huang, He-Ming – sequence: 3 givenname: Jia-Kun surname: Zhu fullname: Zhu, Jia-Kun – sequence: 4 givenname: Jian-Fang surname: Wu fullname: Wu, Jian-Fang – sequence: 5 givenname: Hui orcidid: 0000-0002-2628-4676 surname: Yang fullname: Yang, Hui email: huiyang2017@hust.edu.cn – sequence: 6 givenname: Lu surname: Wei fullname: Wei, Lu email: lwei@hust.edu.cn – sequence: 7 givenname: Xin orcidid: 0000-0003-1546-8119 surname: Guo fullname: Guo, Xin email: xguo@hust.edu.cn |
| BackLink | https://www.ncbi.nlm.nih.gov/pubmed/30525410$$D View this record in MEDLINE/PubMed |
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| Snippet | By dispersing Li6.25Ga0.25La3Zr2O12 (Ga-LLZO) nanoparticles in poly(ethylene oxide) (PEO) matrix, PEO:Ga-LLZO composite polymer electrolytes are synthesized.... By dispersing Li6.25Ga0.25La3Zr2O12 (Ga-LLZO) nanoparticles in polyethylene oxide (PEO) matrix, PEO:Ga-LLZO composite polymer electrolytes are synthesized. The... By dispersing Li6.25Ga0.25La3Zr2O12 (Ga-LLZO) nanoparticles in poly(ethylene oxide) (PEO) matrix, PEO:Ga-LLZO composite polymer electrolytes are synthesized.... By dispersing Li₆.₂₅Ga₀.₂₅La₃Zr₂O₁₂ (Ga-LLZO) nanoparticles in poly(ethylene oxide) (PEO) matrix, PEO:Ga-LLZO composite polymer electrolytes are synthesized.... |
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| SubjectTerms | composite polymers electrolytes Monte Carlo method nanoparticles polyethylene glycol resistors transmission electron microscopes transmission electron microscopy |
| Title | Ionic Conduction in Composite Polymer Electrolytes: Case of PEO:Ga-LLZO Composites |
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