Sequential Electrophilic Substitution Reactions of Tungsten-Coordinated Phosphenium Ions and Phosphine Triflates
Abstraction of chloride from [W(CO)5{PPhCl2}] with AgOSO2CF3 leads to the phosphine triflate complex [W(CO)5{PPhCl(OSO2CF3)}] which undergoes electrophilic substitution reactions with N,N-diethylaniline, anisole, N,N-dimethyl-p-toluidine, toluene, biphenyl, naphthalene, 2,7,9,9-tetramethyl xanthe...
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Published in | ACS omega Vol. 2; no. 11; pp. 7849 - 7861 |
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Main Authors | , , , |
Format | Journal Article |
Language | English |
Published |
United States
American Chemical Society
30.11.2017
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Online Access | Get full text |
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