Sequential Electrophilic Substitution Reactions of Tungsten-Coordinated Phosphenium Ions and Phosphine Triflates

Abstraction of chloride from [W­(CO)5{PPhCl2}] with AgOSO2CF3 leads to the phosphine triflate complex [W­(CO)5{PPhCl­(OSO2CF3)}] which undergoes electrophilic substitution reactions with N,N-diethylaniline, anisole, N,N-dimethyl-p-toluidine, toluene, biphenyl, naphthalene, 2,7,9,9-tetramethyl xanthe...

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Bibliographic Details
Published inACS omega Vol. 2; no. 11; pp. 7849 - 7861
Main Authors Jayaraman, Arumugam, Nilewar, Shrikant, Jacob, Tyler V, Sterenberg, Brian T
Format Journal Article
LanguageEnglish
Published United States American Chemical Society 30.11.2017
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